Process for improving propylene recovery from FCC recovery unit

• US 10,487,271 B2
• Filed: 05/31/2018
• Issued: 11/26/2019
• Est. Priority Date: 12/16/2015
• Status: Active Grant

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Qafisheh, Jibreel A., Cabanaw, Boyd E.
• Primary Examiner(s): Singh, Prem C
• Assistant Examiner(s): Doyle, Brandi M
• Application Number:
  US15/994,906
• Publication Number:
  US 20180273853A1
• Time in Patent Office: 544 Days
• CPC Class Codes: B01D 1/20 Sprayers in general B05B
• CPC Class Codes: B01D 3/06 Flash distillation
• CPC Class Codes: B01D 5/00 Condensation of vapours; Recovering volatile solvents by condensation B01D8/00 takes precedence; condensers F28B
• CPC Class Codes: B01D 53/002 by condensation
• CPC Class Codes: C10G 11/00 Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils cracking in direct contact with molten metals or salts C10G9/34
• CPC Class Codes: C10G 11/18 according to the "fluidised-bed" technique
• CPC Class Codes: C10G 2300/104 Light gasoline having a boiling range of about 20 - 100 °C
• CPC Class Codes: C10G 2300/1044 Heavy gasoline or naphtha having a boiling range of about 100 - 180 °C
• CPC Class Codes: C10G 2300/1088 Olefins
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10G 70/041 by distillation
• CPC Class Codes: C10G 70/043 by fractional condensation
• CPC Class Codes: C10L 2290/06 Heat exchange, direct or indirect
• CPC Class Codes: C10L 2290/30 Pressing, compressing or compacting
• CPC Class Codes: C10L 2290/543 Distillation, fractionation or rectification for separating fractions, components or impurities during preparation or upgrading of a fuel
• CPC Class Codes: C10L 3/12 Liquefied petroleum gas liquefying by pressure and cold treatment F25J

Abstract

The present subject matter relates generally to processes for propylene recovery. More specifically, the present subject matter relates to processes for enhanced recovery of propylene and liquid petroleum gas (LPG) from the fuel gas produced in fluid catalytic cracking (FCC) units by minimizing the light ends and propylene in the unstabilized gasoline which is used as lean oil for the primary absorber of the FCC gas concentration unit.

Claims

1. A process for the recovery of propylene comprising:

(i) contacting a hydrocarbon feed with a catalyst in a fluid catalytic cracking process to produce a product stream;

(ii) distilling the product stream in a fractionator to obtain heavier liquid products as side/bottom draws and a gaseous top product;

(iii) cooling and condensing the gaseous top product and thereafter, separating the obtained gas-liquid mixture in a receiver to obtain a liquid fraction and a lighter gaseous fraction;

(iv) sequentially sending the gaseous fraction obtained from step (iii) to a wet gas compressor train;

(v) feeding a first portion of the liquid fraction obtained in step (iii) back to the fractionator;

(vi) feeding a second portion of the liquid fraction obtained in step (iii) to at least one heat exchanger to produce a heated stream; and

(vii) feeding the heated stream to a flash drum to produce a flashed light ends stream to be sent back to the wet gas compressor in step (iv) and a bottoms liquid stream wherein the bottoms stream is sent to one or more heat exchangers in step (vi) before routing the liquid stream to FCC gas concentration absorber.

2. The process of claim 1 wherein the one or more heat exchangers heats the liquid fraction from about 38°

C. to about 80°

C.

3. The process of claim 1 wherein the flashed light ends stream contains nearly 70% of the propylene in the flash drum feed.

4. The process of claim 1 wherein one or more of the heat exchanges uses a waste heat process stream.

5. The process of claim 1 wherein two heat exchangers are used to heat the liquid fraction.

6. A process for the recovery of propylene comprising:

(i) contacting a hydrocarbon feed with a catalyst in a fluid catalytic cracking process to produce a product stream;

(ii) distilling the product stream in a fractionator to obtain heavier liquid products as side/bottom draws and a gaseous top product;

(iii) cooling and condensing the gaseous top product and thereafter, separating the obtained gas-liquid mixture in a receiver to obtain a liquid fraction and a lighter gaseous fraction;

(iv) sequentially sending the gaseous fraction obtained from step (iii) to a wet gas compressor;

(v) feeding a first portion of the liquid fraction obtained in step (iii) back to the fractionator;

(vi) feeding a second portion of the liquid fraction obtained in step (iii) to at least one heat exchanger to produce a heated stream; and

(vii) feeding the heated stream to a split shell flash drum having a first side and a second side wherein the heated stream is sent to the first side of the split shell to produce a first flashed light ends stream to be sent back to the wet gas compressor in step (iv) and a first bottoms stream wherein the bottoms stream is heated and sent to the second side of the split shell flash drum to produce a second flashed light ends stream to be sent back to the wet gas compressor in step (iv) and a second bottoms stream wherein the second bottoms stream is sent to one or more heat exchangers in step (vi) before routing liquid stream to FCC gas concentration absorber.

7. The process of claim 6 wherein the one or more heat exchangers heats the liquid fraction from about 38°

C. to about 80°

C.

8. The process of claim 6 wherein the flashed light ends stream contains nearly 70% of the propylene in the flash drum feed.

9. The process of claim 6 wherein one or more of the heat exchanges uses a waste heat process stream.

10. The process of claim 6 wherein two heat exchangers are used to heat the liquid fraction.