Bleaching using peroxyformic acid and an oxygen catalyst

• US 10,494,591 B2
• Filed: 06/22/2018
• Issued: 12/03/2019
• Est. Priority Date: 06/22/2017
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Lang, Jason, Crew, Benjamin, Fast, Jonathan P., Becker, Angela, Lundberg, Steven
• Primary Examiner(s): Elhilo, Eisa B
• Application Number:
  US16/015,443
• Publication Number:
  US 20180371373A1
• Time in Patent Office: 529 Days
• CPC Class Codes: A61L 2/186 Peroxide solutions
• CPC Class Codes: A61L 2202/26 Textiles, e.g. towels, beds, cloths
• CPC Class Codes: C11D 2111/12 Soft surfaces, e.g. textile
• CPC Class Codes: C11D 2111/44 Multi-step processes
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/3905 Bleach activators or bleach catalysts
• CPC Class Codes: C11D 3/48 Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
• CPC Class Codes: C11D 7/06 Hydroxides

Abstract

A method for enhancing bleaching efficacy for treatment of articles, including for example laundry is disclosed. Methods for sanitizing and/or disinfecting and bleaching laundry and other articles is provided by washing the articles with a peroxyformic acid composition at a first pH for effective antimicrobial efficacy, thereafter applying an alkaline source to increase the pH for addition of a bleaching activator and/or catalyst for the bleaching agent at a second pH, and lastly draining the remaining components of the peroxyformic acid composition, and the bleaching agent and bleach activator/catalyst from the articles. The methods can be provided as part of a laundry cleaning operation and can be utilized in industrial and commercial applications.

Claims

1. A method of antimicrobial sanitizing and/or disinfecting treatment and bleaching of laundry, the method comprising:

a. washing the laundry with a peroxyformic acid composition at a pH range from about 4 to about 7 in a laundry washing machine for antimicrobial efficacy on the laundry, wherein the peroxyformic acid composition comprises peroxyformic acid, formic acid and hydrogen peroxide;

thereafter

b. adding an alkalinity source to the washing machine to increase the pH range to at least above 9 in the laundry washing machine;

thereafter

c. adding a bleach activator and/or catalyst composition to boost the bleaching efficacy of the peroxyformic acid composition on the laundry in the laundry washing machine; and

d. optionally applying a detergent use solution to remove soil from the laundry at any point in the method of sanitizing and/or disinfecting and bleaching of the laundry;

e. draining the peroxyformic acid composition, the detergent use solution and the bleach activator and/or catalyst composition from the laundry,

wherein (i) the peroxyformic acid composition has a ratio (w/w) of peroxyformic acid to hydrogen peroxide of 1;

1 or greater hydrogen peroxide, and/or (ii) the method comprises an additional step of adding additional hydrogen peroxide to the wash of the laundry washing machine at any time during the method before the draining of the peroxyformic acid composition, the detergent use solution and the bleach activator and/or catalyst composition from the laundry, to increase the bleaching efficacy of the peroxyformic acid composition.

2. The method of claim 1, wherein the laundry washing machine is an industrial machine or a consumer machine.

3. The method of claim 1, peroxyformic acid composition is applied to the laundry in the laundry washing machine at a pH from about 5 to about 8.

4. The method of claim 1, wherein the peroxyformic acid composition is applied to the laundry in the laundry washing machine for about 3 to about 15 minutes.

5. The method of claim 1, wherein the peroxyformic acid composition is generated in situ or at a point of use.

6. The method of claim 1, wherein the peroxyformic acid composition is provided to the laundry washing machine at an actives level from about 5 ppm to about 200 ppm.

7. The method of claim 1, wherein the alkalinity source increases the pH range to at least above 10.

8. The method of claim 1, wherein the detergent use solution and the bleach activator and/or catalyst composition is applied to the laundry in the laundry washing machine for about 3 to about 15 minutes.

9. The method of claim 1, wherein the detergent use solution comprises an alkalinity agent.

10. The method of claim 9, wherein the alkalinity agent comprises at least one of alkali metal hydroxide, alkali metal silicate, alkali metal carbonate or other base component.

11. The method of claim 1, wherein the detergent use solution further comprises any one or more of surfactants, chelants, polymers, enzymes, or other functional ingredients.

12. The method of claim 1, wherein the bleach activator is tetraacetylethylene diamine, sodium nonanonyloxydenzene sulfonate (NOBS), acetyl caprolactone, N-methyl morpholinium acetonitrile or combinations thereof.

13. The method of claim 1, wherein the bleach catalyst is a transition metal catalyst.

14. The method of claim 13, wherein the transition metal catalyst is a manganese containing compound.

15. The method of claim 1, further comprising a step of adding additional hydrogen peroxide to the wash of the laundry washing machine before or after the addition of the peroxyformic acid composition, before or after the addition of the detergent use solution, before or after the addition of the alkalinity source, and/or before or after the addition of the bleach activator and/or catalyst to increase the bleaching efficacy of the peroxyformic acid composition.

16. The method of claim 1, further comprising a step of rinsing the peroxyformic acid composition, the detergent use solution and the bleach activator and/or catalyst composition from the laundry.

17. The method of claim 16, wherein the laundry is rinsed with water in the laundry washing machine for at least about 1 minute.

18. The method of claim 1, wherein the method further comprises an adjuvant use solution comprising at least one of souring agents, fabric softening agents, starch, anti-wrinkle agents, sizing agents, color-fastness agents, oil and water repellant agents, water conditioning agents, iron controlling agents, water threshold agents, soil releasing agents, soil shielding agents, optical brightening agents, fragrances, and mixtures thereof, and wherein the adjuvant use solution is applied to the laundry in the laundry washing machine at a pH from about 5 to about 8 for about 1 to about 6 minutes and at any time during the method before the draining of the peroxyformic acid composition, the detergent use solution and the bleach activator and/or catalyst composition from the laundry.

19. The method of claim 1, wherein the method of sanitizing and/or disinfecting and bleaching laundry follows an initial washing step for the laundry.