Crack-resistant cement composition

• US 10,494,897 B2
• Filed: 07/23/2018
• Issued: 12/03/2019
• Est. Priority Date: 09/09/2014
• Status: Active Grant

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Pandey, Vandana Neeraj, Senapati, Dibyadarshani, Deshpande, Abhimanyu P., Patil, Rahul Chandrakant
• Primary Examiner(s): Green, Anthony J
• Application Number:
  US16/042,762
• Publication Number:
  US 20180328138A1
• Time in Patent Office: 498 Days
• CPC Class Codes: C04B 14/306 Zirconium oxide zircon C04B14/046
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 2111/2038 Resistance against physical degradation
• CPC Class Codes: C04B 22/0093 Aluminates
• CPC Class Codes: C04B 22/06 Oxides, Hydroxides C04B22/0013 takes precedence
• CPC Class Codes: C04B 22/124 Chlorides of ammonium or of the alkali or alkaline earth metals, e.g. calcium chloride
• CPC Class Codes: C04B 22/128 Bromine compounds
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C09K 8/46 containing inorganic binders, e.g. Portland cement
• CPC Class Codes: C09K 8/467 containing additives for specific purposes
• CPC Class Codes: C09K 8/493 Additives for reducing or preventing gas migration
• CPC Class Codes: E21B 33/14 for cementing casings into boreholes
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete

Abstract

A cement composition for use in a well that penetrates a subterranean formation comprising: cement; water; and an additive comprising zirconium dioxide, wherein at least a portion of the zirconium dioxide is in a metastable tetragonal phase, and wherein some or all of the zirconium dioxide that is in the metastable tetragonal phase transforms to a stable monoclinic phase after a stress is applied to the cement composition. The additive also reduces the dimensions of a crack located within the set cement composition. A method of cementing in a subterranean formation comprising: introducing a cement composition into the subterranean formation.

Claims

1. A cement composition comprising:

cement;

water; and

an additive comprising zirconium dioxide, wherein at least a portion of the zirconium dioxide is in a metastable tetragonal phase, and wherein some or all of the zirconium dioxide that is in the metastable tetragonal phase transforms to a stable monoclinic phase after a stress is applied to the cement composition.

2. The cement composition according to claim 1, wherein the cement is selected from the group consisting of Portland cements, gypsum cements, high alumina content cements, slag cements, high magnesia content cements, and any combination thereof.

3. The cement composition according to claim 1, wherein the water is selected from the group consisting of freshwater, brackish water, saltwater, and any combination thereof in any proportion.

4. The cement composition according to claim 1, wherein the cement composition further comprises a water-soluble salt.

5. The cement composition according to claim 4, wherein the salt is selected from sodium chloride, calcium chloride, calcium bromide, potassium chloride, potassium bromide, magnesium chloride, and any combination thereof in any proportion.

6. The cement composition according to claim 1, wherein all of the zirconium dioxide is in the metastable tetragonal phase.

7. The cement composition according to claim 1, wherein the additive further comprises an additional metal oxide.

8. The cement composition according to claim 7, wherein the additional metal oxide is selected from the group consisting of aluminum oxide and transition metal oxides.

9. The cement composition according to claim 7, wherein the ratio of zirconium dioxide to additional metal oxide is in the range of about 9:

1 to about 1;

1.

10. The cement composition according to claim 1, wherein the additive is in a concentration in the range of about 1% to about 10% by weight of the cement.

11. The cement composition according to claim 1, wherein the zirconium dioxide is in a concentration in the range of about 10% to about 50% by weight of the additive.

12. The cement composition according to claim 1, wherein the zirconium dioxide is in a concentration in the range of about 0.1% to about 25% by weight of the cement.

13. The cement composition according to claim 1, wherein the cement composition is a set cement composition.

14. The cement composition according to claim 13, wherein the set cement composition comprises one crack formed within the set cement composition during or after the application of the stress to the cement composition.

15. The cement composition according to claim 13, wherein the transformation of the zirconium dioxide from the metastable tetragonal phase to the stable monoclinic phase occurs after the cement composition has set.

16. The cement composition according to claim 14, wherein the transformation of the zirconium dioxide from the metastable tetragonal phase to the stable monoclinic phase occurs after the crack has formed within the set cement composition.

17. The cement composition according to claim 16, wherein the additive has reduced the size of at least one dimension of the crack within the set cement composition.

18. The cement composition according to claim 16, wherein the additive has completely filled the crack within the set cement composition.

19. The cement composition according to claim 1, wherein the cement composition is placed in a subterranean formation penetrated by a well.

20. The cement composition according to claim 19, wherein the well is an oil well, a gas well, a water production well, an injection well, a geothermal well, or a high-temperature and high-pressure well.