Method for the free form fabrication of articles out of electrically conductive filaments using localized heating

• US 10,513,080 B2
• Filed: 11/07/2016
• Issued: 12/24/2019
• Est. Priority Date: 11/06/2015
• Status: Active Grant

• Current Assignee: United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration
• Original Assignee: United States of America as represented by the Administrator of NASA
• Inventors: Kim, Jae-Woo, Sauti, Godfrey, Gardner, John M., Siochi, Emilie J.
• Primary Examiner(s): Yi, Stella K
• Application Number:
  US15/345,064
• Publication Number:
  US 20170129170A1
• Time in Patent Office: 1,142 Days
• CPC Class Codes: B29C 64/106 using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
• CPC Class Codes: B29C 64/118 using filamentary material being melted, e.g. fused deposition modelling [FDM]
• CPC Class Codes: B29C 64/393 for controlling or regulating additive manufacturing processes
• CPC Class Codes: B29K 2105/16 Fillers
• CPC Class Codes: B29K 2995/0005 Conductive
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 50/02 for controlling or regulating additive manufacturing processes

Abstract

A method of fabricating composite articles includes supplying electrical current to an electrically conductive filament. The electrically conductive filament may include a first material that is electrically conductive and a polymer second material. The polymer second material comprises at least one of a thermoplastic polymer and a partially cured thermosetting polymer. The heated filament is deposited according to a predefined pattern in successive layers to adhere the polymer material of the layers together and build up a three dimensional article. The article includes strands of the first material embedded in a substantially continuous polymer matrix of the second material.

Claims

1. A method of fabricating composite articles, comprising:

providing an electrically conductive filament comprising a first material that is electrically conductive and a polymer second material; and

wherein the polymer second material comprises at least one of a thermoplastic polymer and a partially cured thermosetting polymer;

supplying electrical current to the electrically conductive filament to heat the filament wherein the electrical current ranges from about 1 μ

A to about 1 MA,

depositing the heated filament on a substrate in successive layers to adhere the polymer material of the layers together and build up a three dimensional article having strands of the first material embedded in a substantially continuous polymer matrix of the second material.

2. The method of claim 1, including:

providing first material comprising carbon.

3. The method of claim 2, wherein:

the filament is provided in a form comprising carbon selected from a group consisting of carbon fiber, carbon nanotube, graphite, activated carbon powder, and graphene.

4. The method of claim 1, wherein:

the filament is provided in a form comprising a polymer matrix and conductive filler, wherein a loading of the conductive filler is at or above an electrical percolation threshold, and wherein the conductive filler is selected from the group consisting of chopped carbon fiber, carbon nanotube, graphite, activated carbon powder, and graphene.

5. The method of claim 1, wherein:

the second material comprises a thermoplastic polymer that forms a molten portion on a partially-formed article, and including;

allowing the molten portion to solidify.

6. The method of claim 1, wherein;

the polymer second material comprises a partially cured thermosetting polymer that cures after heating and including;

adhering the polymer second material to previously-deposited thermosetting polymer material.

7. The method of claim 1, wherein:

the filament is provided in a form comprising a plurality of electrically conductive filaments.

8. The method of claim 1, including:

providing filament comprising a polymer matrix and conductive filler, wherein the loading of the conductive filler is at or above the electrical percolation threshold.

9. The method of claim 8, wherein:

the conductive filler is provided in a form comprising at least one of a chopped carbon fiber, carbon nanotubes, graphite, activated carbon powder, graphene and/or metal particles.

10. The method of claim 1, wherein:

the filament is provided in a form comprising a continuous electrically conductive fiber as the first material and a matrix loaded with dispersed electrically conductive filler as the second material.

11. The method of claim 1, including:

causing at least one of the layers to undergo chemical crosslinking due to electrical current being applied to the filament.

12. The method of claim 1, wherein:

at least one of the layers is provided in a form comprising a partially cured thermosetting resin.

13. The method of claim 1, wherein:

at least one of the layers of the electrically conductive filaments is provided in a form comprising carbon nanotubes, conductive polymer, metal wire, metal alloy, metal/carbon hybrid or a combination thereof.

14. The method of claim 1, including:

providing an electrically conductive nozzle;

providing an electrically conductive guide member;

operably connecting the electrically conductive nozzle and the conductive guide member to opposite poles of an electrical power source;

causing the electrically conductive filament to contact the electrically conductive nozzle and the electrically conductive guide member; and

causing electrical current to flow through the filament and heat the filament.

15. The method of claim 14, wherein:

the electrically conductive guide member includes an opening; and

including;

feeding the filament through the opening.

16. A method of printing an article, comprising:

providing data describing a geometry of an article to be printed;

providing electrically conductive filament that is bondable when heated to a bonding temperature electrically coupling the electrically conductive filament to first and second electrodes of a printing device;

causing the printing device to print the article utilizing the data, wherein printing the article includes passing electrical current through the electrically conductive filament to heat the electrically conductive filament wherein the electrical current ranges from about 1 μ

A to about 1 MA, and depositing the heated filament onto a substrate.

17. The method of claim 16, wherein:

the electrically conductive filament is provided in a form that includes carbon and polymer materials.

18. A method of printing an article, comprising:

passing electrical current through an electrically-conductive filament to heat the electrically-conductive filament wherein the electrical current ranges from about 1 μ

A to about 1 MA; and

depositing the heated electrically conductive filament onto a substrate.

19. The method of claim 18, including:

providing an electrically conductive filament comprising a carbon material and a polymer material.