Method for improving propylene recovery from fluid catalytic cracker unit

• US 10,513,477 B2
• Filed: 12/29/2015
• Issued: 12/24/2019
• Est. Priority Date: 12/30/2014
• Status: Active Grant

• Current Assignee: Technip France (Technip)
• Original Assignee: Technip France (Technip)
• Inventors: Taraphdar, Tanmay, Sharath, Babu N.
• Primary Examiner(s): Louie, Philip Y
• Assistant Examiner(s): Cepluch, Alyssa L
• Application Number:
  US15/540,431
• Publication Number:
  US 20180002255A1
• Time in Patent Office: 1,456 Days
• CPC Class Codes: B01D 5/0075 with heat exchanging B01D5/0039 takes precedence
• CPC Class Codes: B01D 53/145 Pretreatment by separation of solid or liquid material
• CPC Class Codes: C07C 7/005 Processes comprising at least two steps in series
• CPC Class Codes: C07C 7/04 by distillation
• CPC Class Codes: C07C 7/09 by fractional condensation
• CPC Class Codes: C07C 7/11 by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids
• CPC Class Codes: C10G 2400/20 C2-C4 olefins
• CPC Class Codes: C10G 2400/26 Fuel gas
• CPC Class Codes: C10G 2400/28 Propane and butane
• CPC Class Codes: C10G 7/02 Stabilising gasoline by removing gases by fractioning
• CPC Class Codes: C10G 70/043 by fractional condensation
• CPC Class Codes: C10G 70/06 by gas-liquid contact

Abstract

The present invention relates to a method for treating a cracked stream stemming from a fluid catalytic cracker unit (FCCU) in order to improve propylene recovery. The present invention also relates to the corresponding installation to implement the method.

Claims

1. A method for treating a cracked stream from a fluid catalytic cracker unit (FCCU) comprising the following steps:

compressing and partly condensing a gas stream from a main fractionator column overhead receiver of the FCCU to produce a compressed and partially condensed gas stream;

separating the compressed and partially condensed gas stream to produce an upstream liquid and an upstream gas;

heating the upstream liquid;

introducing the heated liquid into an upstream stripper to produce a first top stream rich in C2 compounds and a first bottom liquid stream rich in C3+ hydrocarbons;

introducing the first bottom liquid stream into a first heat exchanger and then into a second heat exchanger to produce a heated first side liquid stream;

introducing the heated first side liquid stream into a stabilizer column to produce a second top stream rich in C3 and C4 hydrocarbons, a side liquid stream rich in C5 and C6 hydrocarbons, and a stabilizer bottom liquid stream rich in C5, C6 and C7+ hydrocarbons;

introducing the side liquid stream into the first heat exchanger to produce a cooled side liquid stream;

further cooling the cooled side liquid stream to produce a further cooled side liquid stream;

introducing the upstream gas and at least a portion of the stabilizer bottom liquid stream into a primary absorber to produce a third top gas stream and a second bottom liquid stream;

cooling the third top gas stream;

introducing the cooled third top gas stream and the further cooled side liquid stream into a propylene absorber,

recovering a third bottom stream liquid rich in C3 hydrocarbons and a fourth top gas stream poor in C3 hydrocarbons from the propylene absorber; and

introducing lean oil from the FCCU main fractionator column and the fourth top gas stream into a sponge absorber to recover a fuel gas and a rich oil.

2. The method according to claim 1, further comprising mixing the third bottom liquid stream from the propylene absorber with the compressed and partially condensed stream from the main fractionator column before separating the compressed and partially condensed stream into the upstream liquid and the upstream gas.

3. The method according to claim 1, further comprising introducing the cooled side liquid stream recovered from the first heat exchanger into a third heat exchanger before further cooling the cooled side liquid stream.

4. The method according to claim 3, further comprising introducing the further cooled side liquid stream recovered from the third heat exchanger into fourth heat exchanger before cooling the further cooled side liquid stream.

5. The method according to claim 1, further comprising:

introducing the second top stream into a condenser;

retrieving a condensed stream from the condenser;

cooling the condensed stream to produce a cooled condensed stream; and

separating the cooled condensed stream into a fourth liquid stream which is introduced into the stabilizer column and a fifth liquid stream which is sent to a LPG treating unit to recover LPG.

6. The method according to claim 1, wherein the first top stream is mixed with the compressed and partially condensed stream from the main fractionator column overhead receiver before the separation of the resulting stream into the upstream liquid and the upstream gas.

7. The method according to claim 1, wherein the second bottom liquid stream is mixed with the compressed and partially condensed stream from the main fractionator column overhead receiver before the separation of the resulting stream into the upstream liquid and the upstream gas.

8. The method according to claim 1, wherein the third bottom liquid stream from the propylene absorber is mixed with the compressed and partially condensed stream from the main fractionator column overhead receiver before the separation of the resulting stream into the upstream liquid and the upstream gas.

9. The method according to claim 1, wherein a gas stream from a propylene recovery unit which is rich in propylene is mixed with the compressed and partially condensed stream from the main fractionator column overhead receiver before the separation of the resulting stream into the upstream liquid and the upstream gas.