Multilayer thin film encapsulation structure for a organic electroluminescent device

• US 10,516,136 B2
• Filed: 06/13/2017
• Issued: 12/24/2019
• Est. Priority Date: 06/13/2017
• Status: Active Grant

• Current Assignee: Sakai Display Products Corporation (Hon Hai Precision Industry Co., Ltd.)
• Original Assignee: Sakai Display Products Corporation (Hon Hai Precision Industry Co., Ltd.)
• Inventors: Narutaki, Yozo, Kishimoto, Katsuhiko
• Primary Examiner(s): Chambliss, Alonzo
• Application Number:
  US15/763,288
• Publication Number:
  US 20190363288A1
• Time in Patent Office: 924 Days
• CPC Class Codes: G09F 9/30 in which the desired character or characters are formed by combining individual elements panels comprising a number of electrodes in a single cell controlling light arriving from an independent light source, e.g. electro-optical or magneto-optical cell, G02F1/00
• CPC Class Codes: H05B 33/02 Details
• CPC Class Codes: H05B 33/04 Sealing arrangements , e.g. against humidity
• CPC Class Codes: H05B 33/06 Electrode terminals
• CPC Class Codes: H05B 33/10 Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
• CPC Class Codes: H05B 33/22 characterised by the chemical or physical composition or the arrangement of auxiliary dielectric or reflective layers
• CPC Class Codes: H10K 2102/00 Constructional details relating to the organic devices covered by this subclass
• CPC Class Codes: H10K 2102/351 Thickness
• CPC Class Codes: H10K 50/84 Passivation; Containers; Encapsulations
• CPC Class Codes: H10K 50/844 Encapsulations
• CPC Class Codes: H10K 50/8445 multilayered coatings having a repetitive structure, e.g. having multiple organic-inorganic bilayers
• CPC Class Codes: H10K 59/1213 the pixel elements being TFTs
• CPC Class Codes: H10K 59/131 Interconnections, e.g. wiring lines or terminals
• CPC Class Codes: H10K 71/00 Manufacture or treatment specially adapted for the organic devices covered by this subclass
• CPC Class Codes: H10K 85/10 Organic polymers or oligomers
• CPC Class Codes: H10K 85/111 comprising aromatic, heteroaromatic, or aryl chains, e.g. polyaniline, polyphenylene or polyphenylene vinylene
• CPC Class Codes: H10K 85/141 comprising aliphatic or olefinic chains, e.g. poly N-vinylcarbazol, PVC or PTFE

Abstract

An organic electroluminescent device (100) includes a substrate (1), a driving circuit layer (2), an inorganic protective layer (Pa), an organic flattening layer (Pb), an organic electroluminescent element layer (3), and a TFE structure (10). The TFE structure includes a first inorganic barrier layer (12), an organic barrier layer (14), and a second inorganic barrier layer (16). As seen in a direction of normal to the substrate, the organic flattening layer (Pb) is formed in a region where the inorganic protective layer (Pa) is formed, organic electroluminescent elements are located in a region where the organic flattening layer (Pb) is formed, and an outer perimeter of the TFE structure (10) crosses lead wires (32) and is present between an outer perimeter of the organic flattening layer (Pb) and an outer perimeter of the inorganic protective layer (Pa). In a region where the inorganic protective layer (Pb) and the first inorganic barrier layer (12) are in direct contact with each other on the lead wires (32), a tapering angle θ(12) of a side surface of a cross-section of the first inorganic barrier layer (12) taken along a plane parallel to a width direction of the lead wires (32) is smaller than 90 degrees.

Claims

1. An organic electroluminescent device, comprising:

a substrate;

a driving circuit layer including a plurality of TFTs formed on the substrate, a plurality of gate bus lines and a plurality of source bus lines each connected with any of the plurality of TFTs, a plurality of terminals, and a plurality of lead wires connecting each of the plurality of terminals with either one of the plurality of gate bus lines or either one of the plurality of source bus lines;

an inorganic protective layer formed on the driving circuit layer and exposing at least the plurality of terminals;

an organic flattening layer formed on the inorganic protective layer;

an organic electroluminescent element layer formed on the organic flattening layer and including a plurality of organic electroluminescent elements each connected with either one of the plurality of TFTs; and

a thin film encapsulation structure formed to cover the organic electroluminescent element layer, the thin film encapsulation structure including a first inorganic barrier layer, an organic barrier layer in contact with a top surface of the first inorganic barrier layer, and a second inorganic barrier layer in contact with a top surface of the organic barrier layer, the organic barrier layer being formed in a region enclosed by an inorganic barrier layer joint portion where the first inorganic barrier layer and the second inorganic barrier layer are in direct contact with each other;

wherein;

as seen in a direction of normal to the substrate, the organic flattening layer is formed in a region where the inorganic protective layer is formed, the plurality of organic electroluminescent elements are located in a region where the organic flattening layer is formed, and an outer perimeter of the thin film encapsulation structure crosses the plurality of lead wires and is present between an outer perimeter of the organic flattening layer and an outer perimeter of the inorganic protective layer; and

in a region where the inorganic protective layer and the first inorganic barrier layer are in direct contact with each other on the plurality of lead wires, a tapering angle of a side surface of a cross-section of the first inorganic barrier layer taken along a plane parallel to a width direction of the plurality of lead wires is smaller than 90 degrees.

2. The organic electroluminescent device according to claim 1, wherein the tapering angle of the side surface of the first inorganic barrier layer is smaller than 70 degrees.

3. The organic electroluminescent device according to claim 1, wherein the organic flattening layer is formed of a photosensitive resin.

4. The organic electroluminescent device according to claim 1, wherein the organic flattening layer is formed of polyimide.

5. A method for producing the organic electroluminescent device according to claim 1, the method comprising:

step A of forming the driving circuit layer on the substrate;

step B of forming the inorganic protective layer on the driving circuit layer;

step C of forming the organic flattening layer on the inorganic protective layer;

step D of heating the organic flattening layer to a temperature higher than, or equal to, 200°

C.; and

step E of forming the organic electroluminescent element layer on the organic flattening layer after the step of heating.

6. The method according to claim 5, further comprising step C1 of forming a positive photoresist film covering the organic flattening layer and step C2 of exposing and then developing the entirety of the photoresist film to remove the photoresist film, the step C1 and the step C2 being performed after the step C but before the step D.

7. The method according to claim 6, further comprising the step of storing or transporting the substrate having the photoresist film formed thereon between the step C1 and the step C2.

8. The method according to claim 5, further comprising:

step F of, after the step E, forming the first inorganic barrier layer selectively in an active region where the plurality of organic electroluminescent elements are formed;

step G of, after the step F, locating the substrate in a chamber and supplying a vapor-like or mist-like photocurable resin into the chamber;

step H of condensing the photocurable resin on the first inorganic barrier layer such that the photocurable resin is not present on a part of the first inorganic barrier layer, the part having the tapering angle smaller than 90 degrees; and

step I of, after the step H, irradiating the condensed photocurable resin with light to form the organic barrier layer of the photocurable resin.

9. The method according to claim 5, further comprising:

step F, after the step E, forming the first inorganic barrier layer selectively in an active region where the plurality of organic electroluminescent elements are formed;

step G of, after the step F, locating the substrate in a chamber and supplying a vapor-like or mist-like photocurable resin into the chamber;

step H of condensing the photocurable resin on the first inorganic barrier layer to form a liquid film;

step I of irradiating the liquid film of the photocurable resin with light to form a photocurable resin layer; and

step J of partially ashing the photocurable resin layer to form the organic barrier layer.