Solar cell comprising an oxide-nanoparticle buffer layer and method of fabrication

• US 10,522,774 B2
• Filed: 10/21/2016
• Issued: 12/31/2019
• Est. Priority Date: 10/22/2015
• Status: Active Grant

• Current Assignee: Board of Trustees of the Leland Stanford Junior University (Stanford University)
• Original Assignee: Board of Trustees of the Leland Stanford Junior University (Stanford University)
• Inventors: Bush, Kevin Alexander, Bailie, Colin David, McGehee, Michael David, Leijtens, Tomas
• Primary Examiner(s): Nguyen, Thinh T
• Application Number:
  US15/769,287
• Publication Number:
  US 20180309077A1
• Time in Patent Office: 1,166 Days
• Field of Search: 257 40, 257467, 438 82, 438 64, 438 99
• CPC Class Codes: H01L 2031/0344 Organic materials
• CPC Class Codes: H01L 31/02167 for solar cells
• CPC Class Codes: H01L 31/0725 Multiple junction or tandem solar cells
• CPC Class Codes: H10K 2102/00 Constructional details relating to the organic devices covered by this subclass
• CPC Class Codes: H10K 30/152 the wide bandgap semiconductor comprising zinc oxide, e.g. ZnO
• CPC Class Codes: H10K 30/20 comprising organic-organic junctions, e.g. donor-acceptor junctions
• CPC Class Codes: H10K 30/57 comprising multiple junctions, e.g. tandem PV cells
• CPC Class Codes: H10K 30/81 Electrodes
• CPC Class Codes: H10K 30/82 Transparent electrodes, e.g. indium tin oxide [ITO] electrodes
• CPC Class Codes: H10K 85/215 comprising substituents, e.g. PCBM
• CPC Class Codes: H10K 85/50 Organic perovskites; Hybrid organic-inorganic perovskites [HOIP], e.g. CH3NH3PbI3
• CPC Class Codes: Y02E 10/549 Organic PV cells

Abstract

A buffer layer for protecting an organic layer during high-energy deposition of an electrically conductive layer is disclosed. Buffer layers in accordance with the present invention are particularly well suited for use in perovskite-based single-junction solar cells and double-junction solar cell structures that include at least one perovskite-based absorbing layer. In some embodiments, the buffer layer comprises a layer of oxide-based nanoparticles that is formed using solution-state processing, in which a solution comprising the nanoparticles and a volatile solvent is spin coated onto a structure that includes the organic layer. The solvent is subsequently removed in a low-temperature process that does not degrade the organic layer.

Claims

1. An optoelectronic device comprising:

a substrate;

a first contact disposed on and in physical contact with the substrate;

a first layer comprising an organic material, the first layer being disposed on the first contact;

a second layer that is configured to protect the first layer during a sputter-deposition process, the second layer comprising a plurality of oxide nanoparticles, the oxide nanoparticles of the plurality thereof being characterized by a wide bandgap, the second layer being disposed on the first layer such that the first layer is between the second layer and the first contact; and

a first transparent conductive electrode disposed on the second layer, the first transparent conductive electrode comprising a sputter-deposited material;

wherein the second layer is between the first layer and the first transparent conductive electrode.

2. The optoelectronic device of claim 1 wherein the organic material is a perovskite material.

3. The optoelectronic device of claim 1 wherein the oxide nanoparticles of the plurality thereof comprise an oxide selected from the group consisting of zinc oxide (ZnO), tin oxide (SnO₂), titanium oxide (TiO₂), tungsten oxide (W₂O₃), aluminum oxide (Al₂O₃), silicon dioxide (SiO₂), nickel oxide (NiO), and molybdenum oxide (MoO_x).

4. The optoelectronic device of claim 3 wherein the oxide nanoparticles of the plurality thereof are doped with a first dopant that is selected from the group consisting of aluminum, hydrogen, indium, and gallium.

5. The optoelectronic device of claim 1 wherein the optoelectronic device is selected from the group consisting of a solar cell, a light emitting diode, and an electrochromic.

6. The optoelectronic device of claim 1 wherein the first layer comprises a first perovskite having a first energy bandgap (EG), and wherein the optoelectronic device further comprises:

a third layer comprising a first material having a second EG that is lower than the first EG; and

a second transparent conductive electrode that is between the first layer and the third layer, the second transparent conductive electrode being in electrical communication with each of the first layer and the third layer.

7. The optoelectronic device of claim 6 wherein the optoelectronic device is a monolithically integrated tandem solar cell.

8. The optoelectronic device of claim 7 wherein the first material comprises a second perovskite.

15. The optoelectronic device of claim 1 wherein the sputter-deposited material is selected from the group consisting of indium tin oxide (ITO), aluminum-doped zinc oxide (AZO), indium zinc oxide (IZO), and hafnium zinc oxide (HZO).

16. The optoelectronic device of claim 1 wherein the sputter-deposited material includes indium tin oxide.

17. The optoelectronic device of claim 1 wherein the first transparent conductive electrode is in physical contact with the second layer.

9. An optoelectronic device comprising:

a first layer comprising a first material, the first material comprising a first perovskite and having a first energy bandgap (EG), the first layer being disposed on a substrate;

a first electrical contact disposed on the substrate, the first electrical contact being between the substrate and the first layer;

a second electrical contact that is disposed on and in electrical communication with the first layer, the electrical contact being substantially transparent for a first light signal characterized by a first wavelength range, and the second electrical contact comprising a sputter-deposited material;

a first carrier-transport layer that is disposed on and in physical contact with the first layer; and

a buffer layer that is configured to protect the first layer during a sputter-deposition process, the buffer layer between the second electrical contact and the first carrier-transport layer, the buffer layer comprising plurality of oxide nanoparticles.

10. The optoelectronic device of claim 9 wherein the oxide nanoparticles comprise a wide-bandgap oxide that is selected from the group consisting of tin oxide, zinc oxide, aluminum-doped zinc oxide (AZO), titanium oxide, nickel oxide, platinum oxide, tungsten oxide, and vanadium oxide.

11. The optoelectronic device of claim 9 wherein the first carrier-transport layer is a hole-selective layer, and wherein the optoelectronic device further comprises:

a first electron-selective layer, the first layer being between the first carrier-transport layer and the first electron-selective layer; and

a second electrical contact that is in electrical communication with the first layer;

wherein the first layer, the first carrier-transport layer, the first electron-selective layer, and the first and second electrical contacts are collectively operative for generating electrical energy based on light characterized by the first wavelength range.

12. The optoelectronic device of claim 11 further comprising:

a second layer comprising a second material having a second EG that is lower than the first EG;

a second hole-selective layer;

a second electron-selective layer, the second layer being between the second hole-selective layer and the second electron-selective layer; and

a third electrical contact that is in electrical communication with the second layer;

wherein the second electrical contact substantially transparent for the first signal;

wherein the first light signal includes light characterized by a second wavelength range;

wherein the second layer, the second hole-selective layer, the second electron-selective layer, and the second and third electrical contacts are collectively operative for generating electrical energy based on light characterized by the second wavelength range; and

wherein the first layer, second layer, and second electrical contact are arranged such that the second layer receives at least a portion of the first light signal through the first layer and the second electrical contact.

13. The optoelectronic device of claim 12 wherein the first layer and the second layer are monolithically integrated.

14. The optoelectronic device of claim 12 wherein the second material is selected from the group consisting of silicon, copper indium gallium selenide (CIGS), and a second perovskite.

18. The optoelectronic device of claim 9 wherein the first carrier-transport layer is an electron-selective layer, and wherein the optoelectronic device further comprises:

a first hole-selective layer, the first layer being between the first carrier-transport layer and the first electron-selective layer; and

a second electrical contact that is in electrical communication with the first layer;

wherein the first layer, the first carrier-transport layer, the first hole-selective layer, and the first and second electrical contacts are collectively operative for generating electrical energy based on light characterized by the first wavelength range.

19. The optoelectronic device of claim 9 wherein the sputter-deposited material is selected from the group consisting of indium tin oxide (ITO), aluminum-doped zinc oxide (AZO), indium zinc oxide (IZO), and hafnium zinc oxide (HZO).

20. The optoelectronic device of claim 9 wherein the sputter-deposited material includes indium tin oxide.