Accommodating imperfectly aligned memory holes

• US 10,529,737 B2
• Filed: 06/10/2019
• Issued: 01/07/2020
• Est. Priority Date: 02/08/2017
• Status: Active Grant

• Current Assignee: Applied Materials Incorporated
• Original Assignee: Applied Materials Incorporated
• Inventors: Purayath, Vinod R.
• Primary Examiner(s): Dulka, John P.
• Application Number:
  US16/435,887
• Publication Number:
  US 20190296045A1
• Time in Patent Office: 211 Days
• CPC Class Codes: H01L 21/3065 Plasma etching; Reactive-ion etching
• CPC Class Codes: H01L 21/3081 characterised by their composition, e.g. multilayer masks, materials
• CPC Class Codes: H01L 21/31116 by dry-etching
• CPC Class Codes: H01L 21/31144 using masks
• CPC Class Codes: H01L 21/67069 for drying etching
• CPC Class Codes: H01L 29/1037 and non-planar channel resulting from the gate electrode disposition, e.g. within a trench, H01L29/42356
• CPC Class Codes: H01L 29/40117 the electrodes comprising a charge-trapping insulator
• CPC Class Codes: H10B 43/27 the channels comprising vertical portions, e.g. U-shaped channels

Abstract

Methods of forming 3-d flash memory cells are described. The methods allow the cells to be produced despite a misalignment in at least two sections (top and bottom), each having multiple charge storage locations. The methods include selectively gas-phase etching dielectric from the bottom memory hole portion by delivering the etchants through the top memory hole. Two options for completing the methods include (1) forming a ledge spacer to allow reactive ion etching of the bottom polysilicon portion without damaging polysilicon or charge-trap/ONO layer on the ledge, and (2) placing sacrificial silicon oxide gapfill in the bottom memory hole, selectively forming protective conformal silicon nitride elsewhere, then removing the sacrificial silicon oxide gapfill before performing the reactive ion etching of the bottom polysilicon portion as before.

Claims

1. A method of forming a memory cell, the method comprising:

forming a silicon nitride spacer on a ledge of a patterned substrate positioned in a substrate processing chamber, wherein the patterned substrate comprises a vertical stack of alternating oxide and nitride layers defining a vertical memory hole there through, wherein sidewalls of the vertical memory hole include a conformal coating and a first polysilicon layer overlying the conformal coating, and wherein the vertical stack comprises a bottom portion and a top portion laterally misaligned to form the ledge;

removing a bottom portion of the first polysilicon layer by reactive ion etching the bottom portion of the first polysilicon layer while retaining sidewall portions of the first polysilicon layer;

removing a bottom portion of the conformal coating using a gas-phase etch;

removing the silicon nitride spacer from the ledge using a gas-phase etch; and

forming a second polysilicon layer on the first polysilicon layer.

2. The method of claim 1, wherein the conformal coating comprises a first silicon oxide layer, a silicon nitride layer, and a second silicon oxide layer.

3. The method of claim 1, wherein the silicon nitride spacer completely covers the ledge while maintaining a line-of-sight path from top to bottom of the vertical memory hole.

4. The method of claim 1, wherein forming the second polysilicon layer comprises making electrical contact between the first polysilicon layer, the second polysilicon layer and underlying silicon.

5. The method of claim 1, wherein removing the silicon nitride spacer comprises exciting both a fluorine precursor and an oxygen precursor in a remote plasma to produce plasma effluents, and flowing the plasma effluents into a substrate processing region housing the patterned substrate.

6. The method of claim 1, wherein the bottom portion and the top portion are laterally misaligned by more than 5 nm.

7. The method of claim 1, wherein removing the bottom portion of the conformal coating is performed by exciting a hydrogen-containing precursor and a fluorine-containing precursor in a remote plasma to form plasma effluents.

8. The method of claim 7, wherein the plasma effluents are flowed into a substrate processing region through a showerhead, wherein the patterned substrate is positioned in the substrate processing region, and wherein a temperature of the patterned substrate is greater than 95°

C.

9. A method of forming a memory cell, the method comprising:

forming sacrificial silicon oxide in a bottom portion of a vertical memory hole through a patterned substrate in a substrate processing chamber, wherein the patterned substrate comprises a vertical stack of alternating oxide and nitride layers defining the vertical memory hole, wherein sidewalls of the vertical memory hole include an inner layer coating, wherein the patterned substrate further comprises a first polysilicon layer formed on the inner layer coating;

wherein the vertical stack comprises the bottom portion and a top portion laterally misaligned to form a ledge;

forming conformal silicon nitride on exposed portions of the first polysilicon layer exposed by the sacrificial silicon oxide;

removing the sacrificial silicon oxide;

removing a bottom portion of the first polysilicon layer by reactive ion etching the bottom portion of the first polysilicon layer while retaining sidewall portions of the first polysilicon layer;

removing a bottom portion of the inner layer coating using a gas-phase etch;

removing the conformal silicon nitride; and

forming a second polysilicon layer on the first polysilicon layer producing electrical contact between the second polysilicon layer and underlying silicon.

10. The method of claim 9, wherein the inner layer coating comprises a conformal coating.

11. The method of claim 10, wherein the conformal coating comprises a first silicon oxide layer, a silicon nitride layer, and a second silicon oxide layer.

12. The method of claim 9, wherein the bottom portion and the top portion are laterally misaligned by more than 5 nm.

13. The method of claim 9, wherein removing the conformal silicon nitride comprises exciting both a fluorine precursor and an oxygen precursor in a remote plasma to produce plasma effluents, and flowing the plasma effluents into a substrate processing region housing the patterned substrate.

14. The method of claim 13, wherein the fluorine precursor comprises nitrogen trifluoride and the oxygen precursor comprises molecular oxygen (02).

15. A method of forming a memory cell, the method comprising:

forming a bottom portion of a compound stack of alternating silicon oxide and silicon nitride slabs;

forming a bottom portion of a memory hole through the bottom portion of the compound stack by patterning the bottom portion of the compound stack;

filling the bottom portion of the compound stack with doped silicon oxide;

forming a top portion of the compound stack of alternating silicon oxide and silicon nitride slabs;

forming a top portion of a memory hole through the top portion of the compound stack by patterning the top portion of the compound stack and exposing the doped silicon oxide; and

selectively removing the doped silicon oxide with a gas-phase etch which retains material in the alternating silicon oxide and silicon nitride slabs in each of the top portion and the bottom portion, wherein the bottom portion and the top portion of the compound stack are fluidly coupled and the top portion is laterally displaced from the bottom portion.

16. The method of claim 15, wherein the top portion is displaced from the bottom portion by at least 5 nm.

17. The method of claim 15, wherein the bottom portion comprises at least twenty pairs of slabs.

18. The method of claim 15, wherein the top portion comprises at least twenty pairs of slabs.

19. The method of claim 15, wherein the doped silicon oxide is doped with boron and/or phosphorus.