Synthetic material for detecting ultraviolet radiation and/or X-radiation

• US 10,533,131 B2
• Filed: 05/08/2017
• Issued: 01/14/2020
• Est. Priority Date: 05/09/2016
• Status: Active Grant

• Current Assignee: Turun yliopisto
• Original Assignee: Turun yliopisto
• Inventors: Lastusaari, Mika, Norrbo, Isabella
• Primary Examiner(s): Gaworecki, Mark R
• Application Number:
  US16/099,807
• Publication Number:
  US 20190106620A1
• Time in Patent Office: 981 Days
• CPC Class Codes: C09K 11/646 Silicates
• CPC Class Codes: C09K 11/676 Aluminates; Silicates
• CPC Class Codes: C09K 11/77344 Aluminosilicates
• CPC Class Codes: C09K 9/00 Tenebrescent materials, i.e. materials for which the range of wavelengths for energy absorption is changed as a result of excitation by some form of energy
• CPC Class Codes: G01T 1/06 Glass dosimeters using colour change; including plastic dosimeters
• CPC Class Codes: G01T 1/1606 with other specified detectors not provided for in the other sub-groups of G01T1/16 see provisionally also G01T1/16
• CPC Class Codes: H01L 33/502 Wavelength conversion materials
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps

Abstract

The invention relates to a material represented by the following formula (I)
(M′)₈M″₆M′″₆O₂₄(X,S)₂:M″″  formula (I).
Further, the invention relates to an ultraviolet radiation sensing material, to an X-radiation sensing material, to different uses, to a device and to a method for determining the intensity of ultraviolet radiation.

Claims

1. A material represented by the following formula (I)

(M′

)₈M″

₆M′

″

₆O₂₄(X,S)₂;

M″

″

 

 

formula (I)

wherein

M′

represents a combination of at least two monoatomic cations of different alkali metals selected from a group consisting of Li, Na, K, and Rb;

M″

represents a trivalent monoatomic cation of a metal selected from a group consisting of Al and Ga, or a trivalent monoatomic cation of B, or a trivalent monoatomic cation of a transition element selected from any of Groups 3-12 of the IUPAC periodic table of the elements, or any combination of such cations;

M′

″

represents a monoatomic cation of an element selected from a group consisting of Si and Ge, or any combination of such cations;

X represents an anion of an element selected from a group consisting of O, S, Se, and Te, or any combination of such anions, or X represents an anion of an element selected from a group consisting of F, Cl, Br, and I, or any combination of such anions; and

M″

″

represents a dopant cation of an element selected from rare earth metals of the IUPAC periodic table of the elements, or transition metals of the IUPAC periodic table of the elements, or any combination of such cations, or wherein M″

″

is absent.

2. The material of claim 1, wherein M′

represents a combination of at least two monoatomic cations of different alkali metals selected from a group consisting of Li, Na, K, and Rb, wherein the combination comprises 0-98 mol-%, or 0-95 mol-%, or 0-90 mol-%, or 0-85 mol-%, or 0-80 mol-%, or 0-70 mol-%, of the monoatomic cation of Na.

3. The material of claim 1, wherein M′

represents a combination of at least two monoatomic cations of different alkali metals selected from a group consisting of Li, Na, K, and Rb, and wherein the combination comprises at most 66 mol-% of the monoatomic cation of Na.

4. The material of claim 1, wherein M′

represents a combination of a monoatomic cation of Na with a monoatomic cation of Li, a monoatomic cation of K and/or a monoatomic cation of Rb.

5. The material of claim 1, wherein M″

″

represents a cation of an element selected from a group consisting of Eu and Tb, or a combination of such cations.

6. The material of claim 1, wherein M″

″

represents a cation of an element selected from a group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu, and Zn, or any combination of such cations.

7. The material of claim 1, wherein M′

represents a combination of at least two monoatomic cations of different alkali metals selected from a group consisting of Na, K, and Rb, and wherein the combination is selected in order to provide a predetermined absorption edge for the material.

8. The material of claim 1, wherein the material is configured to change color on exposure to ultraviolet radiation, wherein the correlation between the intensity of the color of the material and the intensity of the ultraviolet radiation is calculated based on the following formula 1:

y=A1*e^(x/t1)+y0 

 

formula 1

wherein the parameters have the following meanings;

y=color intensity [percent of black]

A1=amplitude for color

x=UV index value for sunlight or UV lamp power [%] for UVA, UVB, and/or UVC

t1=growth constant for color

y0=initial offset for color.

9. The material of claim 1, wherein the material is selected from a group consisting of (Na,K)₈Al₆Si₆O₂₄(Cl,S)₂, (Na,Rb)₈Al₆Si₆O₂₄ (Cl,S)₂, (Na,K,Rb)₈Al₆Si₆O₂₄ (Cl,S)₂, (Na,K)₈Al₆Si₆O₂₄ (Cl,S)₂:

Eu, (Na,K)₈Al₆Si₆O₂₄ (Cl,S)₂;

Tb, (Li,K)₈Al₆Si₆O₂₄ (Cl,S)₂, (Li, Rb)₈Al₆Si₆O₂₄ (Cl,S)₂, (Li,K,Rb)₈Al₆Si₆O₂₄ (Cl,S)₂, and (Li,Na,K,Rb)₈Al₆Si₆O₂₄(Cl,S)₂.

10. An ultraviolet radiation sensing material, characterized in that the material is a material as defined in claim 1.

11. An X-radiation sensing material, characterized in that the material is a material as defined in claim 1.

12. A device, characterized in that the device comprises a material as defined in claim 1.

13. The device of claim 12, wherein the device is an ultraviolet radiation sensor, an ultraviolet radiation detector, or an ultraviolet radiation indicator.

14. The device of claim 12, wherein the device comprises a device for indicating the presence of ultraviolet radiation.

15. The device of claim 14, wherein the ultraviolet radiation is ultraviolet A radiation, ultraviolet B radiation and/or ultraviolet C radiation.

16. The device of claim 12, wherein the device comprises a device for indicating the presence of X-radiation.

17. The device of claim 12, wherein the device comprises a security device.

18. A method for determining the intensity of ultraviolet radiation and/or X-radiation, wherein the method comprises:

a) providing a material as defined in claim 1;

b) subjecting the material provided in step a) to ultraviolet radiation and/or X-radiation;

c) determining a change in the color of the material caused by the ultraviolet radiation and/or the X-radiation; and

d) comparing the color of the material with a reference indicating the correlation of the intensity of the ultraviolet radiation and/or X-radiation with the color of the material.

19. The method of claim 18, wherein step c) comprises visually determining the change in the color of the material.