Converter for lighting devices

• US 10,550,320 B2
• Filed: 10/28/2016
• Issued: 02/04/2020
• Est. Priority Date: 11/11/2015
• Status: Expired due to Fees

• Current Assignee: ZKW Group GmbH (LG Corporation)
• Original Assignee: ZKW Group GmbH (LG Corporation)
• Inventors: Hartmann, Peter
• Primary Examiner(s): Mulvaney, Elizabeth E
• Application Number:
  US15/770,566
• Publication Number:
  US 20190316033A1
• Time in Patent Office: 1,194 Days
• CPC Class Codes: C01B 32/26 Preparation by using ultra-high pressure B01J3/06; by crystal growth C30B29/04
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: C23C 16/27 Diamond only
• CPC Class Codes: C23C 16/274 using microwave discharges
• CPC Class Codes: F21S 41/16 Laser light sources
• CPC Class Codes: F21S 41/176 Light sources where the light is generated by photoluminescent material spaced from a primary light generating element
• CPC Class Codes: F21S 43/16 Light sources where the light is generated by photoluminescent material spaced from a primary light generating element
• CPC Class Codes: F21S 45/47 Passive cooling, e.g. using fins, thermal conductive elements or openings

Abstract

The invention relates to a converter (25, 35, 45, 55, 65, 75, 85, 95, 115, 125) for a lighting device, in particular for a lighting device for a motor vehicle headlight, wherein the converter comprises a converter material (24, 34, 44, 54, 64, 74, 84, 94, 114, 124) for at least partly converting a primary light, which is emitted from a primary light source, into a secondary light, wherein the secondary light has a different wavelength than the primary light, wherein the converter comprises a flat diamond support structure (20, 30, 40, 50, 60, 70, 80, 90, 110, 120) made of polycrystalline diamond with a plurality of column-shaped diamond crystals (23, 33, 43, 53, 63, 73, 83, 93, 113, 123), which form a column-shaped diamond texture, wherein regions (22, 32, 42, 52, 62, 72, 82, 92, 112, 122) of the diamond support structure comprise the converter material (24, 34, 44, 54, 64, 74, 84, 94, 114, 124), and free spaces remain between said regions, the free spaces allow the primary light to pass through the diamond support structure without being converted.

Claims

1. A converter (25, 35, 45, 55, 65, 75, 85, 95, 115, 125) for a lighting device for a motor vehicle headlight, wherein the converter comprises a converter material (24, 34, 44, 54, 64, 74, 84, 94, 114, 124) for at least partly converting a primary light, which is emitted from a primary light source, into a secondary light, wherein the secondary light has a different wavelength than the primary light, the converter comprising:

a flat diamond support structure (20, 30, 40, 50, 60, 70, 80, 90, 110, 120) made of polycrystalline diamond with a plurality of column-shaped diamond crystals (23, 33, 43, 53, 63, 73, 83, 93, 113, 123), which form a column-shaped diamond texture, wherein regions (22, 32, 42, 52, 62, 72, 82, 92, 112, 122) of the diamond support structure comprise the converter material (24, 34, 44, 54, 64, 74, 84, 94, 114, 124), and free spaces remain between said regions, the free spaces allow the primary light to pass through the diamond support structure without being converted.

2. The converter according to claim 1, wherein the regions (22, 32, 42, 52, 62, 72, 82, 92, 112, 122) of the flat diamond support structure (20, 30, 40, 50, 60, 70, 80, 90, 110, 120) comprising the converter material follow the topography of the flat diamond support structure.

3. The converter according to claim 1, wherein the column-shaped diamond crystals (23, 33, 43, 53, 63, 73, 83, 93, 113, 123) in the flat diamond support structure (20, 30, 40, 50, 60, 70, 80, 90, 110, 120) are oriented substantially in the direction of light propagation.

4. The converter according to claim 1, wherein the diamond support structure (20, 30, 40, 50, 60, 70, 80, 90, 110, 120) is produced by chemical vapour deposition (CVD).

5. The converter according to claim 1, wherein the column-shaped diamond crystals (23, 33, 43, 53, 63, 73, 83, 93, 113, 123) have a mean width of from 1 to 500 μ

m.

6. The converter according to claim 1, wherein gaps (22, 32, 42, 52, 62, 72, 92, 112) in the diamond support structure (20, 30, 40, 50, 60, 70, 90, 110) are filled at least in part with the converter material (24, 34, 44, 54, 64, 74, 94, 114).

7. The converter according to claim 6, wherein the gaps (22, 32, 42, 52, 62, 72, 92, 112) filled with converter material (24, 34, 44, 54, 64, 74, 94, 114) have a thickness of from 10 μ

m to 2 mm.

8. The converter according to claim 6, wherein the flat diamond support structure (20, 30, 40, 50, 60, 70, 90, 110) has an inner face (20a, 30a, 40a, 50a, 60a, 70a, 90a, 110a) and an outer face (20b, 30b, 40b, 50b, 60b, 70b, 90b, 110b), wherein gaps on at least one of the faces of the diamond support structure are filled at least in part with converter material (22, 32, 42, 52, 62, 72, 92, 112).

9. The converter according to claim 8, wherein the gaps (22, 32) on the inner face (20a, 30a) of the diamond support structure (20, 30) are filled at least in part with converter material (22, 32).

10. The converter according to claim 8, wherein the gaps on both faces (30a) of the flat diamond support structure (30) are filled at least in part with converter material (32).

11. The converter according to claim 1, wherein the flat diamond support structure (80, 120) has an inner face (80a, 120a) and an outer face (80b, 120b), wherein the converter material (84, 124) is applied at least in part to elevations (82, 122) on at least one of the faces of the diamond support structure.

12. The converter according to claim 11, wherein the converter material (84, 124) is applied at least in part to elevations (82, 122) on the outer face (80b, 120b) of the diamond support structure (80, 120).

13. The converter according to claim 1, wherein the converter material (24, 34, 44, 54, 64, 74, 84, 94, 114, 124) is selected from the group consisting of doped yttrium aluminium garnet (YAG-Ce), lanthanum-doped yttrium oxide (Y₂O₃—

La₂O₃), magnesium aluminium spinel (MgAl₂O₄) and europium-doped M₂Si₅N₈ with M=Ca, Sr or Ba.

14. A lighting device for a motor vehicle headlight comprising:

a primary light source; and

a converter (25, 35, 45, 55, 65, 75, 85, 95, 115, 125) according to claim 1.

15. The lighting device according to claim 14, wherein the primary light source is a laser light source.

16. A motor vehicle headlight comprising:

a lighting device according to claim 14.

17. A signal light comprising:

a lighting device according to claim 14.

18. A method for producing a converter for a lighting device according to claim 1, the method comprising the following steps:

a) producing a flat polycrystalline diamond support structure on a flat substrate by means of chemical vapour deposition (CVD),

b) at least partially applying converter material in regions of the diamond support structure, wherein free spaces remain between the regions having the converter material, and the free spaces allow the primary light to pass through the diamond support structure without being converted, and

optionally detaching the flat substrate from the polycrystalline diamond support structure after step a) or after step b).

19. The method according to claim 18, wherein the regions having the converter material are selected from the group consisting of gaps and elevations of the diamond support structure.

20. The method according to claim 18, wherein the diamond support structure is processed prior to the application of the converter material by a focussed ion beam (FIB) method, by laser drilling, by oxidative etching, by applying a hot metal powder, by polishing, or by stamping.

21. The method according to claim 18, wherein an adhesive layer is applied to the diamond support structure, at least in regions prior to the application of the converter material, in order to improve the adhesion of the converter material to the diamond support structure.

22. The method according to claim 18, wherein the converter material is applied by chemical deposition of gaseous reactants or by material deposition.

23. The method according to claim 18, wherein the converter material is applied in a solid, liquid or gel-like preform and is then converted into a solid phase connected to the diamond support structure.

24. A method for producing a converter for a lighting device according to of claim 1, the method comprising the following steps:

a) producing a structured converter material layer on a flat substrate,

b) depositing a flat polycrystalline diamond support structure on the substrate having the structured converter material layer by means of chemical vapour deposition (CVD), and

optionally detaching the flat substrate from the polycrystalline diamond support structure having the converter material after step b).

25. The method according to claim 24, wherein the converter material is applied to the substrate by chemical vapour deposition (CVD) in conjunction with photolithographic methods, physical material deposition, such as physical vapour deposition (PVD) in conjunction with photolithographic methods, or by structured printing.

26. The method according to claim 18, wherein the chemical vapour deposition of the diamond support structure is based on a selective seeding of the diamond crystals on the substrate, wherein the substrate or the substrate surface is produced from a foreign material.

27. The method according to claim 26, wherein the substrate is selected from the group consisting of silicon, an element from the group of refractory metals (Ti, Zr, Hf, Va, Nb, Ta, Cr, Mo and W), in particular molybdenum, silicon carbides, carbides of an element from the group of refractory metals (Ti, Zr, Hf, Va, Nb, Ta, Cr, Mo and W), silicon with carbidised surface, and an element from the group of refractory metals (Ti, Zr, Hf, Va, Nb, Ta, Cr, Mo and W) with carbidised surface.

28. The method according to claim 18, wherein the diamond support structure is deposited by chemical vapour deposition on the basis of a homoepitaxial process.

29. The method according to claim 28, wherein the substrate is selected from HPHT diamond or preferably polished natural or CVD diamond substrates.

30. The method according to claim 18, wherein the converter material is selected from the group consisting of Cer-doped YAG (yttrium aluminium garnet, lanthanum-doped yttrium oxide (Y₂O₃—

La₂O₃), magnesium aluminium spinel (MgAl₂O₄) and europium-doped M₂Si₅N₈ with M=Ca, Sr or Ba.

31. The converter according to claim 5, wherein the column-shaped diamond crystals (23, 33, 43, 53, 63, 73, 83, 93, 113, 123) have a width of from 20 to 100 μ

m.

32. The converter according to claim 7, wherein the gaps (22, 32, 42, 52, 62, 72, 92, 112) filled with converter material (24, 34, 44, 54, 64, 74, 94, 114) have a thickness of from 100 to 500 μ

m.

33. The lighting device according to claim 15, wherein the laser light source is configured to emit blue light.

34. The method according to claim 22, wherein the converter material is applied by sputtering or spray-coating.

35. The method according to claim 29, wherein the substrate is a polished natural or CVD diamond substrate.