Impedance spectrometer with metamaterial radiative filter

• US 10,551,334 B1
• Filed: 08/09/2018
• Issued: 02/04/2020
• Est. Priority Date: 08/09/2018
• Status: Active Grant

• Current Assignee: William N. Carr
• Original Assignee: William N. Carr
• Inventors: Carr, William N.
• Primary Examiner(s): McAndrew, Christopher P
• Application Number:
  US16/059,237
• Publication Number:
  US 20200049640A1
• Time in Patent Office: 544 Days
• CPC Class Codes: G01N 2033/245 for agricultural purposes
• CPC Class Codes: G01N 27/021 before and after chemical transformation of the material
• CPC Class Codes: G01N 27/025 a current being generated within the material by induction
• CPC Class Codes: G01N 27/026 Dielectric impedance spectroscopy electrochemical impedance spectroscopy for measuring corrosion G01N17/02
• CPC Class Codes: G01N 33/02 Food
• CPC Class Codes: G01N 33/24 Earth materials G01N33/42 takes precedence
• CPC Class Codes: G01N 33/383 Concrete, cement

Abstract

A system and method for sensing the wave impedance of a material using an RF power source with a sensor structure comprised of a metamaterial radiative filter (MRF). The wave impedance is specified or monitored by processing a differential RF signal level with an impedance calculator. The differential RF signal level is obtained from a reference source signal and a response signal. RF field-coupling of the RF source with the material effects the response signal level. In embodiments, the spectrometer is physically configured for noninvasive and invasive measurements. In embodiments, the material is sensed when shielded by RF-opaque media. In embodiments, wherein the MRF has a fixed response characteristic, the dielectric constant may be obtained with a sensing structure comprised of two transponders and a single RF frequency. In embodiments wherein the MRF has a fixed response characteristic, both the dielectric constant and the loss tangent may be obtained using three transponders and a single RF frequency. In embodiments wherein the MRF is tuned with programmed control, both the dielectric constant and the loss tangent may be obtained using two transponders and a single RF frequency.

Claims

1. An impedance spectrometer for sensing a wave impedance of a material, the impedance spectrometer comprising an interrogator adapted for controlling and processing RF signals communicating with a sensing structure, the sensing structure further comprising:

a first transponder, wherein the first transponder generates a source analog signal responding to an RF control signal communicated from the interrogator by wired or wireless operative coupling;

a metamaterial resonant filter (MRF) receiving the source analog signal from the first transponder and generating a response analog signal affected by MRF coupling into the material, wherein the MRF coupling comprises at least one of an electric, electromagnetic, or magnetic field, and the MRF is operational with at least one of negative permittivity or negative permeability within the MRF;

a second transponder, receiving the response analog signal from the MRF, wherein the level of the response analog signal is communicated to the interrogator via RF signals through a wired or wireless operative coupling, and

the interrogator is further comprised of;

an impedance calculator, wherein the impedance calculator determines the real part and/or the imaginary part of the wave impedance of the material based on one or more sensing operations, wherein each sensing operation provides a measure of the difference in signal levels between the source analog signal and the response signal level at a controlled frequency.

2. The impedance spectrometer of claim 1 wherein the MRF comprises one or more of a split ring resonator (SRR), coupled spiral resonator, fractile metamaterial and variations thereof.

3. The impedance spectrometer of claim 1 wherein at least a portion of the operative coupling between the interrogator and one or more transponders is a wired connection provided by a digital bus.

4. The impedance spectrometer of claim 1 wherein at least a portion of the operative coupling between the interrogator and one or more transponders comprises wireless RFID technology, wherein the transponders are active or semi-passive transponders.

5. The spectrometer of claim 1 wherein at least a portion of the operative coupling is comprised of a wired coupling through RF-blocking material between the controller and the transponders.

6. The impedance spectrometer of claim 1 wherein the operative coupling is implemented at an RF signal frequency different from that of the RF signal providing field coupling within the MRF.

7. The impedance spectrometer of claim 1 wherein the operative coupling between the interrogator and one or more of the transponders is based on wireless RFID technology wherein the transponders comprise passive RFID tags.

8. The impedance spectrometer of claim 1 wherein one or more of the transponders is powered by an RF energy harvester receiving RF energy by wireless means from the interrogator or other external RF power source.

9. The impedance spectrometer of claim 1 wherein the integrator and the transponders are disposed on the same physical circuit platform.

10. The impedance spectrometer of claim 1 wherein the interrogator is carried as payload on an unmanned aerial vehicle (drone).

11. The impedance spectrometer of claim 1 wherein the interrogator is disposed within a wand stick structure.

12. The impedance spectrometer of claim 1 wherein the interrogator is connected with or disposed within a mobile phone.

13. The spectrometer of claim 1 wherein the material is earth soil having the wave impedance affected by moisture and ionic conduction.

14. The spectrometer of claim 1 wherein the material comprises an agricultural product, in raw or processed form, further comprised of one or more materials selected from a group comprised of maize, cocoa, coffee, wheat, barley, tea, nuts, peanuts, tree oils, timber, bales of hay, and silage.

15. The spectrometer of claim 1 wherein the material comprises a processed food product further comprising a water or alcohol component.

16. The spectrometer of claim 1 wherein the material is comprised of an alcohol or water component, further comprising one or more of beer, wine, rum, and industrial chemicals.

17. The spectrometer of claim 1 wherein the material comprises curing cement, wherein the wave impedance of the cement changes with time as the cement cures.

18. The spectrometer of claim 1 wherein the material is a material in a frozen or unfrozen state, and the wave impedance of the material is different for its frozen and unfrozen states.

19. A method for sensing a wave impedance of a material, the method comprising:

performing one or more sensing operations controlled by a controller, wherein each sensing operation comprises transmitting a first analog signal from a first transponder into a metamaterial resonant filter (MRF) and the MRF transmitting a second analog signal into a second transponder in response to the first analog signal, wherein each sensing operation determines a signal level for the first and second analog signals and the signals within each sensing operation have the same frequency;

generation of a coupling by the MRF into the material, the coupling comprising at least one of an electric, electromagnetic, or magnetic field, wherein said coupling into the material affects the electrical impedance of the MRF;

calculating, by the controller, a difference level for the first and second analog signals for each sensing operation;

calculating the real part of the wave impedance of the material based on the difference level obtained for the one or more sensing operations wherein the real part of the wave impedance of the material is uniquely related to the resonant frequency of the MRF;

calculating the imaginary part of the wave impedance of the material based on multiple sensing operations obtained over a frequency range that encompasses the resonance frequency of the affected MRF, wherein the imaginary part of the wave impedance is uniquely related to the difference level at the MRF resonance frequency.

20. The method of claim 19 wherein the impedance calculator is calibrated by operating the impedance spectrometer in specific environments with material of known wave impedance.