Papermaking additive compositions and methods and uses thereof

• US 10,557,234 B2
• Filed: 08/22/2016
• Issued: 02/11/2020
• Est. Priority Date: 05/29/2012
• Status: Active Grant

• Current Assignee: Neozyme International, Inc. (International Daleco Corp.)
• Original Assignee: Neozyme International, Inc. (International Daleco Corp.)
• Inventors: Dale, Parker, Dale, Parker David
• Primary Examiner(s): Claytor, Renee
• Assistant Examiner(s): Fernandez, Susan E.
• Application Number:
  US15/243,958
• Publication Number:
  US 20160362834A1
• Time in Patent Office: 1,268 Days
• CPC Class Codes: D21C 5/005 Treatment of cellulose-containing material with microorganisms or enzymes
• CPC Class Codes: D21C 5/025 De-inking
• CPC Class Codes: D21H 17/005 Microorganisms or enzymes
• CPC Class Codes: D21H 21/24 Surfactants
• CPC Class Codes: D21H 21/36 Biocidal agents, e.g. fungicidal, bactericidal, insecticidal agents
• CPC Class Codes: Y02W 30/64 Paper recycling

Abstract

The present specification discloses papermaking additive compositions, articles of manufacture, containers or kits comprising such compositions, and methods and uses to increase separation of cellulose fibers from a pulp, to remove one or more impurities and/or one or more contaminates from a pulp and/or a paper material and to remove an ink from a pulp and/or a paper material.

Claims

1. A papermaking additive composition comprising a treated, fermented yeast supernatant including bio-nutrients, minerals and amino acids, and about 1% to about 15% by weight of one or more nonionic surfactants, wherein the composition lacks any active enzymes due to the treatment, and wherein the composition has a pH of about 2.5 to about 5.0.

2. The papermaking additive composition according to claim 1, wherein the papermaking additive composition comprises at least 35% by weight of the treated, fermented yeast supernatant.

3. The papermaking additive composition according to claim 1, wherein the papermaking additive composition comprises at most 95% by weight of the treated, fermented yeast supernatant.

4. The papermaking additive composition according to claim 1, wherein the one or more nonionic surfactants comprises a polyether nonionic surfactant, a polyhydroxyl nonionic surfactant, and/or a biosurfactant.

5. The papermaking additive composition according to claim 4, wherein the polyhydroxyl nonionic surfactant comprises a sucrose ester, an ethoxylated sucrose ester, a sorbital ester, an ethoxylated sorbital ester, an alkyl glucoside, an ethoxylated alkyl glucoside, a polyglycerol ester, or an ethoxylated polyglycerol ester.

6. The papermaking additive composition according to claim 1, wherein the one or more nonionic surfactants comprise an amine oxide, an ethoxylated alcohol, an ethoxylated aliphatic alcohol, an alkylamine, an ethoxylated alkylamine, an ethoxylated alkyl phenol, an alkyl polysaccharide, an ethoxylated alkyl polysaccharide, an ethoxylated fatty acid, an ethoxylated fatty alcohol, or an ethoxylated fatty amine, or a nonionic surfactant having the general formula of H(OCH₂CH₂)_xOC₆H₄R¹, H(OCH₂CH₂)_xOR², or H(OCH₂CH₂)_xOC(O)R², wherein x represents the number of moles of ethylene oxide added to an alkyl phenol and/or a fatty alcohol or a fatty acid, R¹ represents a long chain alkyl group and, R² represents a long chain aliphatic group.

7. The papermaking additive composition according to claim 1, wherein the one or more nonionic surfactants is an ethoxylated nonyl phenol, an ethoxylated octyl phenol, an ethoxylated ceto-oleyl alcohol, an ethoxylated ceto-stearyl alcohol, an ethoxylated decyl alcohol, an ethoxylated dodecyl alcohol, an ethoxylated tridecyl alcohol, or an ethoxylated castor oil.

8. The papermaking additive composition according to claim 1, wherein the papermaking additive composition comprises from about 5% to about 13% by weight of the one or more nonionic surfactants.

9. The papermaking additive composition according to claim 8, wherein the papermaking additive composition comprises from about 7% to about 11% by weight of the one or more nonionic surfactants.

10. The papermaking additive composition according to claim 1, wherein the papermaking additive composition further comprises one or more anionic surfactants.

11. The papermaking additive composition according to claim 10, wherein the papermaking additive composition comprises from about 0.5% to about 10% by weight of the one or more anionic surfactants.

12. The papermaking additive composition according to claim 11, wherein the papermaking additive composition comprises from about 1% to about 8% by weight of the one or more anionic surfactants.

13. The papermaking additive composition according to claim 12, wherein the papermaking additive composition comprises from about 2% to about 6% by weight of the one or more anionic surfactants.

14. The papermaking additive composition according to claim 1, wherein the pH is at most 4.5.

15. The papermaking additive composition according to claim 1, wherein the papermaking additive composition further comprises an antimicrobial.

16. The papermaking additive composition according to claim 1, wherein the treated, fermented yeast supernatant is from the genus Brettanomyces, Candida, Cyberlindnera, Cystofilobasidium, Debaryomyces, Dekkera, Fusarium, Geotrichum, Issatchenkia, Kazachstania, Kloeckera, Kluyveromyces, Lecanicillium, Mucor, Neurospora, Penicillium, Pichia, Rhizopus, Rhodosporidium, Rhodotorula, Saccharomyces, Schizosaccharomyces, Thrichosporon, Torulaspora, Torulopsis, Verticillium, Yarrowia, Zygosaccharomyces, or Zygotorulaspora.

17. A method of separating fibers from a pulp, the method comprising applying an effective amount of a papermaking additive composition as defined in claim 1 to the pulp during a pulping and/or a paper production phase, wherein the application results in increased separation of cellulose fibers from raw materials present in the pulp.

18. A method of removing one or more impurities and/or one or more contaminates from a pulp and/or a paper material, the method comprising applying an effective amount of a papermaking additive composition as defined in claim 1 to the pulp during a pulping and/or a paper production phase, wherein the application results in removal of the one or more impurities and/or the one or more contaminates from the pulp and/or paper material.

19. A method of removing an ink from a pulp and/or a paper material, the method comprising applying an effective amount of a papermaking additive composition as defined in claim 1 to the pulp during a pulping and/or a paper production phase, wherein the application results in removal of the ink from the pulp and/or paper material.