Crude oil recovery chemical fluids

• US 10,563,117 B2
• Filed: 09/12/2018
• Issued: 02/18/2020
• Est. Priority Date: 09/13/2017
• Status: Active Grant

• Current Assignee: Nissan Chemical America Corporation (Nissan Chemical Corporation)
• Original Assignee: Nissan Chemical America Corporation (Nissan Chemical Corporation)
• Inventors: Southwell, John Edmond, Murakami, Satoru, Oota, Isao
• Primary Examiner(s): Bhushan, Kumar R
• Application Number:
  US16/129,688
• Publication Number:
  US 20190078015A1
• Time in Patent Office: 524 Days
• CPC Class Codes: C09K 2208/10 Nanoparticle-containing well treatment fluids
• CPC Class Codes: C09K 8/584 characterised by the use of specific surfactants
• CPC Class Codes: C09K 8/588 characterised by the use of specific polymers polymeric surfactants C09K8/584
• CPC Class Codes: E21B 43/16 Enhanced recovery methods for obtaining hydrocarbons

Abstract

A crude oil recovery chemical fluid is described and claimed. This fluid has been shown to exhibit excellent resistance to salt and high temperatures. This crude oil recovery chemical fluid includes a silane compound, an aqueous silica sol having an average particle diameter of from about 3 nm to about 200 nm, two or more anionic surfactants, and one or more nonionic surfactants.

Claims

1. A crude oil recovery chemical fluid which is excellent in resistance to high temperature and salt, comprising a silane compound, an aqueous silica sol comprising colloidal silica particles dispersed in an aqueous solvent having an average particle diameter of from about 3 nm to about 200 nm, two or more anionic surfactants, and one or more nonionic surfactants, wherein the aqueous silica sol has a silica concentration of about 5% to about 55% by mass;

and wherein the aqueous silica sol is present in an amount of from about 3% by mass to about 30% by mass, based on the total mass of the crude oil recovery chemical solution, in terms of silica solid content, wherein the aqueous silica sol comprises silica particles in which at least a part of the silane compound is bonded on the surface of at least a part of the silica particles in the sol.

2. The crude oil recovery chemical fluid of claim 1, wherein the silane compound comprises a silane coupling agent having at least one organic functional group, wherein the organic functional group is selected from the group consisting of a vinyl group, an ether group, an epoxy group, a styryl group, a methacryl group, an acryl group, an amino group, an isocyanurate group, an alkoxysilane, a silazane and a siloxane.

3. The crude oil recovery chemical fluid of claim 1 wherein the aqueous silica sol is present in an amount of from about 10% by mass to about 25% by mass, based on the total mass of the crude oil recovery chemical fluid, in terms of silica solid content.

4. The crude oil recovery chemical fluid of claim 1, wherein the silane compound is present in a ratio of from about 0.1 to about 10.0 of silane compound based on the mass of silica solid content of the aqueous silica sol.

5. The crude oil recovery chemical fluid of claim 1, wherein the anionic surfactants are selected from the group consisting of a sodium salt or a potassium salt of a fatty acid, an alkylbenzene sulfonate, a higher alcohol sulfate ester salt, a polyoxyethylene alkyl ether sulfate, an α

-sulfo fatty acid ester, an α

-olefin sulfonate, a monoalkyl phosphate ester salt, and an alkane sulfone acid salt.

6. The crude oil recovery chemical fluid of claim 1, wherein the anionic surfactants are present in an amount of from about 0.001% by mass to about 20% by mass, based on the total mass of the crude oil recovery chemical fluid.

7. The crude oil recovery chemical fluid of claim 1, wherein the anionic surfactants are present in a mass ratio of from about 0.4 to about 5.0 based on the silica solid content of the crude oil recovery chemical fluid, and the crude oil recovery chemical fluid has a pH of from about 7 about 12.

8. The crude oil recovery chemical fluid of claim 1, wherein the anionic surfactants are present in a mass ratio of from about 0.001 to about 0.4 based on the silica solid content of the crude oil recovery chemical fluid, and the crude oil recovery chemical fluid has a pH of from about 2 to about 7.

9. The crude oil recovery chemical fluid of claim 1, wherein the nonionic surfactants have an HLB of from about 3.0 to about 20.0 or less, and wherein the nonionic surfactants are selected from the group consisting of polyoxyethylene alkyl ether, polyoxyethylene alkylphenol ether, alkyl glucoside, polyoxyethylene fatty acid ester, sucrose fatty acid ester, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester and fatty acid alkanolamide.

10. The crude oil recovery chemical fluid of claim 1, wherein the nonionic surfactants are present in an amount of from about 0.001% by mass to about 30% by mass, based on the total mass of the crude oil recovery chemical fluid.

11. The crude oil recovery chemical fluid according to claim 1, wherein at least a part of the silane compound is not bonded on the surface of the silica particles in the sol.

12. The crude oil recovery chemical fluid according to claim 1, produced by a process comprising combining the silane compound, the aqueous silica sol, two or more anionic surfactants, and one or more nonionic surfactants.

13. The crude oil recovery chemical fluid according to claim 12, wherein the aqueous silica sol comprises silica particles in which at least a part of the silane compound is bonded on the surface of at least a part of the silica particles in the sol.

14. The crude oil recovery chemical fluid according to claim 12, wherein the aqueous silica sol comprises silica particles obtained by (a) adding the silane compound to the aqueous silica sol in a ratio of from about 0.1 to about 3.0, based on the mass of the silane compound in terms of the silica particles (silica solid content) in the aqueous silica sol, and (b) heating from about 50°

C. to about 100°

C. for from about 1 hour to about 20 hours.