Methods of inkjet printing

• US 10,569,587 B1
• Filed: 10/26/2018
• Issued: 02/25/2020
• Est. Priority Date: 10/26/2018
• Status: Active Grant

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Sowinski, Allan Francis, Cook, Wayne Lee, Bugner, Douglas Eugene
• Primary Examiner(s): Jackson, Juanita D
• Application Number:
  US16/171,455
• Time in Patent Office: 487 Days
• CPC Class Codes: B41J 2/02 generating a continuous ink jet
• CPC Class Codes: B41M 5/0023 Digital printing methods characterised by the inks used inks per se C09D11/00
• CPC Class Codes: C09D 11/033 characterised by the solvent
• CPC Class Codes: C09D 11/037 characterised by the pigment
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/38 characterised by non-macromolecular additives other than solvents, pigments or dyes
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing

Abstract

Substrates can be inkjet printed using an aqueous inkjet ink composition having a dynamic viscosity of 5 centipoise (5 mPa-sec) or less at 25° C., and consisting essentially of: (a) a polymer-dispersed pigment colorant at 0.9-6 weight %; (b) a composition consisting of one or more compounds represented by the following Structure (I):
HO—CH₂—CH₂—R  (I)
wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, at 0.5-2 weight %; and (c) a water-soluble humectant, co-solvents, or both, at 20 weight %. Each polymer-dispersed pigment colorant has a 50^th percentile particle diameter of less than 70 nm and a 95^th percentile particle diameter of less than 150 nm, measured using a dynamic light scattering particle size analyzer. Replenishment or maintenance fluids containing a Structure (I) compound can also be used during the inkjet printing process.

Claims

1. A method of inkjet printing, comprising:

providing a substrate;

inkjet printing an aqueous inkjet ink composition from a printhead in a controlled manner onto a surface of the substrate to provide an inkjet printed image on the surface of the substrate,

wherein the aqueous inkjet ink composition has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C., and consists essentially of;

(a) one or more polymer-dispersed pigment colorants in a total amount of at least 0.9 weight % and up to and including 6 weight %, based on the total weight of the aqueous inkjet ink composition;

(b) a composition consisting of one or more compounds represented by the following Structure (I);

HO—

CH₂—

CH₂—

R 

 

(I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of the aqueous inkjet ink composition; and

(c) one or more compounds selected from water-soluble humectants, co-solvents, and a combination of water-soluble humectants and co-solvents, in an amount of less than or equal to 20 weight %, based on the total weight of the aqueous inkjet ink composition,

wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 70 nm and a 95^th percentile particle diameter of less than 150 nm, all particle diameters being measured using a dynamic light scattering particle size analyzer.

2. The method of claim 1, comprising inkjet printing the aqueous inkjet ink composition from a main fluid supply as a continuous stream of the aqueous inkjet ink composition that is broken into both printing drops and non-printing drops.

3. The method of claim 2, further comprising collecting and returning the non-printing drops to the main fluid supply.

4. The method of claim 1, further comprising inkjet printing one or more additional aqueous inkjet ink compositions in a sequence with the inkjet printing of the aqueous inkjet ink composition, in a controlled manner, to provide a multicolor inkjet printed-image on the surface of the substrate.

5. The method of claim 1, further comprising replenishing the main fluid supply with replenishing fret aqueous inkjet ink composition that consists essentially of the same or different (a) one or more polymer-dispersed pigment colorants, (b) composition, and (c) one or more compounds that are present in the aqueous inkjet ink composition.

6. The method of claim 1, wherein the aqueous inkjet ink composition further comprises a (d) supplemental antimicrobial agent that is different from the (b) composition.

7. The method of claim 1, wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 60 nm and a 95^th percentile particle diameter of less than 110 nm, all particle diameters being measured using a dynamic laser light scattering particle size analyzer.

8. The method of claim 1, wherein the aqueous inkjet ink composition further contains one or more promoters for the one or more Structure (I) compounds of the (b) composition, each of which promoter is an alkane diol having a least 7 carbon atoms and up to and including 12 carbon atoms, in an amount of less than or equal to 1.5 weight %, based on the total weight of the aqueous inkjet ink composition.

9. The method of claim 1, further comprising replenishing the main fluid supply with an aqueous particle-free fluid that has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C., and consists essentially of;

the same or different (b) composition that is present in the aqueous inkjet ink composition.

10. The method of claim 9, wherein the aqueous particle-free fluid further comprises a (d) supplemental antimicrobial agent that is different from the (b) composition.

11. The method of claim 9, wherein the aqueous particle-free fluid further contains one or more promoters for the (b) composition, each promoter being an alkane diol having a least 7 carbon atoms and up to and including 12 carbon atoms, in an amount of less than or equal to 1.5 weight %, based on the total weight of the aqueous inkjet ink composition.

12. The method of claim 1, further comprising:

stopping the inkjet printing of the aqueous inkjet ink composition;

delivering an aqueous particle-free fluid from a maintenance fluid supply to the printhead; and

ejecting the aqueous particle-free fluid from the printhead to purge the aqueous inkjet ink composition from the printhead,

wherein the aqueous particle-free fluid has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C. and consists essentially of;

the same or different (b) composition that is present in the aqueous inkjet ink composition, and

a solvo-surfactant in an amount of at least 0.1 weight % and up to and including 20 weight %, based on the total weight of the aqueous particle-free fluid.

13. The method of claim 12, wherein the solvo-surfactant is an asymmetric polyhydric alcohol or mono-alkyl ether derived from a polyhydric alcohol.

14. The method of claim 12, wherein the solvo-surfactant is present in the aqueous particle-free fluid an amount of at least 3 weight % and up to and including 6 weight %, based on the total weight of the aqueous particle-free fluid.

15. The method of claim 12, wherein the aqueous particle-free fluid further comprises a humectant, co-solvent, or both, that is different from the solvo-surfactant.

16. The method of claim 12, wherein the aqueous particle-free fluid further contains one or more promoters for the (b) composition, each of which promoters is an alkane diol having a least 7 carbon atoms and up to and including 12 carbon atoms, in an amount of less than or equal to 1.5 weight %, based on the total weight of the aqueous particle-free fluid.

17. The method of claim 12, further comprising storing the aqueous particle-free fluid in the printhead for a period of time and subsequently restarting printing with the aqueous inkjet ink composition from the main fluid supply to the printhead to start a new printing procedure.

18. The method of claim 1, further comprising:

replenishing the aqueous inkjet ink composition with an aqueous particle-free fluid comprising the (b) composition.

19. A method of printing an image using a continuous inkjet printer system, the method comprising:

providing a substrate;

providing a jetting module having a plurality of nozzles including a nozzle in fluid communication with a main fluid supply containing an aqueous inkjet ink composition;

causing drops of the aqueous inkjet ink composition to be formed while it is jetted through the nozzle in fluid communication with the main fluid supply by drop stimulation in response to time-varying electrical signals;

providing a catcher including a drop contact face;

using a deflection mechanism to deflect at least some of the drops of the aqueous inkjet ink composition onto the drop contact face of the catcher while allowing other drops of the aqueous inkjet ink composition to pass by the catcher and to be deposited onto a surface of the substrate; and

causing the drops of the aqueous inkjet ink composition that contact the drop contact face to flow along the drop contact face,

wherein the aqueous inkjet ink composition has a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C. as measured using a rolling ball viscometer, and consists essentially of;

(a) one or more polymer-dispersed pigment colorants in a total amount of at least 0.9 weight % and up to and including 6 weight %, based on the total weight of the aqueous inkjet ink composition;

(b) a composition consisting of one or more compounds represented by the following Structure (I);

HO—

CH₂—

CH₂—

R 

 

(I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of the aqueous inkjet ink composition; and

(c) one or more compounds selected from water-soluble humectants, co-solvents, and a combination of water-soluble humectants and co-solvents, in an amount of less than or equal to 20 weight %, based on the total weight of the aqueous inkjet ink composition,

wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 70 nm and a 95^th percentile particle diameter of less than 150 nm, all particle diameters being measured using a dynamic light scattering particle size analyzer.

20. A method of continuous inkjet printing, comprising:

supplying a main fluid supply of a continuous inkjet printer with an aqueous inkjet ink composition having a dynamic viscosity of less than or equal to 5 centipoise (5 mPa-sec) at 25°

C., and consisting essentially of;

(a) one or more polymer-dispersed pigment colorants in a total amount of at least 0.9 weight % and up to and including 6 weight %, based on the total weight of the aqueous inkjet ink composition;

(b) a composition consisting of one or more compounds represented by the following Structure (I);

HO—

CH₂—

CH₂—

R 

 

(I)

wherein R is a substituted or unsubstituted phenyl group or a substituted or unsubstituted phenoxy group, in a total amount of at least 0.5 weight % and up to and including 2 weight %, based on the total weight of the aqueous inkjet ink composition; and

(c) one or more compounds selected from water-soluble humectants, co-solvents, and a combination of water-soluble humectants and co-solvents, in an amount of less than or equal to 20 weight %, based on the total weight of the aqueous inkjet ink composition,

wherein each of the one or more polymer-dispersed pigment colorants has a 50^th percentile particle diameter of less than 70 nm and a 95^th percentile particle diameter of less than 150 nm, all particle diameters being measured using a dynamic light scattering particle size analyzer;

ejecting a continuous stream of drops of the first aqueous inkjet ink composition from a drop generator mechanism;

in response to electrical signals received from a control mechanism, selecting between printing drops for imaging a substrate and nonprinting drops that are collected and returned to the main fluid supply, both types of drops from the aqueous inkjet ink composition; and

replenishing the main fluid supply as a function of resistivity of the aqueous inkjet ink composition in the main fluid supply, with an aqueous particle-free fluid comprising the (b) composition.