Polyphenylene sulfide resin composition and hollow forming products using the same

• US 10,577,501 B2
• Filed: 06/23/2017
• Issued: 03/03/2020
• Est. Priority Date: 06/29/2016
• Status: Active Grant

• Current Assignee: Toray Industries Incorporated
• Original Assignee: Toray Industries Incorporated
• Inventors: Yamanaka, Yuji, Saito, Kei, Isago, Hiroyuki, Unohara, Takeshi, Matsumoto, Hideki
• Primary Examiner(s): Dollinger, Michael M
• Application Number:
  US16/310,318
• Publication Number:
  US 20190330470A1
• Time in Patent Office: 984 Days
• CPC Class Codes: C08L 101/02 characterised by the presence of specified groups , e.g. terminal or pendant functional groups
• CPC Class Codes: C08L 101/06 containing oxygen atoms C08L101/025 takes precedence
• CPC Class Codes: C08L 23/02 not modified by chemical after-treatment
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 81/02 Polythioethers; Polythioether-ethers
• CPC Class Codes: F02M 35/10 Air intakes; Induction systems
• CPC Class Codes: F02M 35/10321 Plastics; Composites; Rubbers

Abstract

A polyphenylene sulfide resin composition includes a polyphenylene sulfide resin (A), an amino group-containing compound (B), an epoxy group-containing elastomer (C), wherein the polyphenylene sulfide resin (A) forms a continuous phase and the amino group-containing compound (B) and the epoxy group-containing elastomer (C) form a dispersed phase in the morphology of a forming product composed of the resin composition observed with a transmission electron microscope, and the modulus of elongation (the elastic modulus determined by performing a tensile test on an ASTM type 1 dumbbell test piece obtained by injection molding at a cylinder temperature of 300° C. and at a mold temperature of 150° C., under the conditions in which the distance between chucks is 114 mm, the test piece distance is 100 mm, and the elongation rate is 10 mm/min) of the resin composition is 1.0 MPa or more and 1000 MPa or less.

Claims

1. A polyphenylene sulfide resin composition comprising a polyphenylene sulfide resin (A), an amino group-containing compound (B), and an epoxy group-containing elastomer (C), wherein said polyphenylene sulfide resin (A) forms a continuous phase consisting of polyphenylene sulfide resin (A) and optionally a compatibilizer and said amino group-containing compound (B) and said epoxy group-containing elastomer (C) form a dispersed phase in a morphology of a forming product composed of said resin composition observed with a transmission electron microscope, and a modulus of elongation, the elastic modulus determined by performing a tensile test on an ASTM type 1 dumbbell test piece obtained by injection molding at a cylinder temperature of 300°

C. and at a mold temperature of 150°

C., under the conditions in which the distance between chucks is 114 mm, the test piece distance is 100 mm, and the elongation rate is 10 mm/min, of said resin composition is 1.0 MPa or more and 1000 MPa or less, wherein said amino group-containing compound (B) is a polyamide resin.

2. The polyphenylene sulfide resin composition according to claim 1, comprising 0.01 to 200 parts by weight of said amino group-containing compound (B) and 1 to 200 parts by weight of said epoxy group-containing elastomer (C) based on 100 parts by weight of said polyphenylene sulfide resin (A).

3. The polyphenylene sulfide resin composition according to claim 1, wherein said epoxy group-containing elastomer (C) is more than 30% by weight and 70% by weight or less when the total of said polyphenylene sulfide resin (A), said amino group-containing compound (B), and said epoxy group-containing elastomer (C) is 100% by weight.

4. The polyphenylene sulfide resin composition according to claim 1, further comprising an elastomer (D) not containing a functional group in an amount such that the total amount of said elastomer (D) and said epoxy group-containing elastomer (C) is 200 parts by weight or less based on 100 parts by weight of said polyphenylene sulfide resin (A).

5. The polyphenylene sulfide resin composition according to claim 1, wherein said amino group-containing compound (B) forms a secondary dispersed phase in said dispersed phase of said epoxy group-containing elastomer (C).

6. The polyphenylene sulfide resin composition according to claim 1, which is a polyphenylene sulfide resin composition for an intake duct that contacts exhaust condensation water of an internal combustion engine.

7. A forming product composed of said polyphenylene sulfide resin composition according to claim 1.

8. The forming product according to claim 7, which is hollow.

9. A duct that contacts exhaust condensation water of an internal combustion engine comprising the forming product according to claim 8.

10. The duct according to claim 9, which is an intake duct.

11. The duct according to claim 9, which is an intake duct for a forced induction engine.

12. The duct according to claim 9, which is an intake duct for a forced induction engine that connects a turbocharger or a supercharger and an intercooler.