Biogas apparatus for integration with an ethanol production system

• US 10,612,047 B2
• Filed: 04/21/2010
• Issued: 04/07/2020
• Est. Priority Date: 06/15/2009
• Status: Active Grant

• Current Assignee: Eisenmann Corp. (Eisenmann SE)
• Original Assignee: Eisenmann Corp. (Eisenmann SE)
• Inventors: Veit, Eberhard, Stonawski, Ondrej, Halsband, Adam
• Primary Examiner(s): Nguyen, Nghi V
• Application Number:
  US12/764,451
• Publication Number:
  US 20100317091A1
• Time in Patent Office: 3,639 Days
• Field of Search: 435165
• CPC Class Codes: C12M 21/04 for producing gas, e.g. biogas digesters for manure with production of biogas A01C3/028, biological treatment of water, waste water or sewage C02F3/00, C02F11/02, preparation of natural gas or syngas C10L3/06, C10L3/10
• CPC Class Codes: C12M 21/12 for producing fuels or solvents C12M21/04 takes precedence; liquid carbonaceous fuels C10L1/00, solid fuels C10L5/00
• CPC Class Codes: C12M 43/02 Bioreactors or fermenters combined with devices for liquid fuel extraction; Biorefineries
• CPC Class Codes: C12P 5/023 Methane
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02E 50/30 Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

An integrated system produces ethanol and biogas from raw plant materials. The system includes a pretreatment apparatus for converting raw plant materials into sugars and a fermenter for fermenting the sugars to produce a beer including ethanol. A distillation apparatus separates the beer into the ethanol and a whole stillage, and a separator then separates the whole stillage into a thin stillage and wet distillers grains. A biogas apparatus processes a first portion of the thin stillage to produce biogas and a biogas effluent, and converts a percentage of the non-fermentable solids and organic acids in the thin stillage into biogas. The pretreatment apparatus is supplied with an amount of fresh water and an amount of backset, the backset including the biogas effluent recycled from the biogas apparatus to the pretreatment apparatus.

Claims

1. An integrated apparatus for producing ethanol and biogas from raw plant materials, the integrated apparatus comprising:

a pretreatment apparatus for converting raw plant materials into sugars, the pretreatment apparatus being supplied with an amount of fresh water and an amount of backset;

a fermenter including yeast for fermenting the sugars to produce a beer comprising ethanol;

a distillation apparatus for separating the beer into the ethanol and a whole stillage;

a separator for separating the whole stillage into a thin stillage and wet distillers grains, the thin stillage comprising non-fermentable solids and organic acids;

a thin stillage tank for collection of the thin stillage, the thin stillage tank having a first supply and a second supply extending therefrom, the first supply comprising a backset return supply extending into the pretreatment apparatus and the second supply comprising a biogas supply, wherein the thin stillage tank is operable to allow for selective distribution of thin stillage to vary flow rates to the backset return supply and the biogas supply to increase;

(i) the production of ethanol for the same or less water and energy requirement, (ii) an amount of raw plant material feed directed to the pretreatment apparatus, and (iii) an amount of thin stillage fed to the backset directly from the thin stillage tank; and

a biogas apparatus for processing a first portion of the thin stillage to produce biogas and a biogas effluent, the biogas apparatus receiving the first portion of thin stillage from the thin stillage tank biogas supply, the biogas apparatus converting a percentage of the non-fermentable solids and organic acids in the thin stillage into biogas and thereby reducing the concentration of the non-fermentable solids and organic acids in the biogas effluent,

wherein the biogas apparatus comprises a biogas discharge and a biogas effluent return, the biogas effluent return extends from the biogas apparatus into the backset return supply and into the pretreatment apparatus, resulting in an integrated apparatus that produces ethanol, biogas and byproducts that are recycled into the integrated apparatus at the pretreatment apparatus, and no thin stillage discharge extends from the integrated apparatus.

2. The integrated apparatus of claim 1, the biogas apparatus comprising at least one anaerobic digester having microorganisms for processing the thin stillage.

3. The integrated apparatus of claim 2, wherein a pH of the at least one digester is controlled by addition of a neutralizing agent.

4. The integrated apparatus of claim 3, wherein the neutralizing agent is ammonia, wherein the microorganisms are adapted for an ammonia environment.

5. The integrated apparatus of claim 4, wherein nitrogen from the ammonia added as a neutralizing agent and additional ammonia generated by digestion of the organic acids is recycled via the biogas effluent return as a nutrient for the yeast in fermentation, thereby reducing or eliminating the need for a separate addition of ammonia to the fermenter.

6. The integrated apparatus of claim 2, the biogas apparatus comprising a main anaerobic digester and a secondary anaerobic digester in series.

7. The integrated apparatus of claim 2, the biogas apparatus further comprising a recuperative heat exchanger for cooling the thin stillage prior to entering the at least one digester and for reheating the biogas effluent prior to being recycled to the pretreatment apparatus.

8. The integrated apparatus of claim 1, wherein a second portion of the thin stillage is recycled directly as backset from the separator to the pretreatment apparatus;

and

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the amount of fresh water supplied to the pretreatment apparatus.

9. The integrated apparatus of claim 1, wherein a second portion of the thin stillage is recycled directly as backset from the separator to the pretreatment apparatus;

and

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the amount of the second portion of the thin stillage recycled directly as backset, reducing the amount of solids returned to the pretreatment apparatus so that more raw plant materials can be added to the pretreatment apparatus.

10. The integrated apparatus of claim 1, further comprising an evaporator for concentrating a third portion of the thin stillage into a syrup by boiling off vapor from the thin stillage;

wherein a portion of the syrup is further provided to the biogas apparatus for processing into biogas and biogas effluent, the syrup and the first portion of thin stillage being provided to the biogas apparatus in any ratio.

11. The integrated apparatus of claim 1, further comprising an evaporator for concentrating a third portion of the thin stillage into a syrup by boiling off vapor from the thin stillage;

wherein the backset further comprises the vapor boiled off from the thin stillage;

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the third portion of the thin stillage that must be concentrated by the evaporator, thereby reducing the energy loading of the evaporator; and

wherein a reduction in the third portion of the thin stillage reduces the amount of the syrup.

12. The integrated apparatus of claim 11, further comprising a dryer for drying the wet distillers grains and the syrup;

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the energy loading of the dryer by reducing the amount of the syrup that must be dried.

13. The integrated apparatus of claim 11, further comprising a dryer for drying the wet distillers grains and the syrup;

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces or eliminates the syrup load-out from the system.

14. An integrated apparatus for producing ethanol and biogas from raw plant materials, the integrated apparatus comprising:

a pretreatment apparatus for converting raw plant materials into sugars, the pretreatment apparatus being supplied with an amount of fresh water or and an amount of backset;

a fermenter including yeast for fermenting the sugars to produce a beer comprising ethanol;

a distillation apparatus for separating the beer into the ethanol and a whole stillage;

a separator for separating the whole stillage into a thin stillage and wet distillers grains, the thin stillage comprising non-fermentable solids and organic acids;

a thin stillage tank for collection of the thin stillage, the thin stillage tank having a first backset return supply extending therefrom into the pretreatment apparatus and a second biogas supply extending therefrom, wherein the thin stillage tank is operable to allow for selective distribution of thin stillage to vary flow rates to the backset return and the biogas supply to increase;

(i) the production of ethanol for the same or less water and energy requirement, (ii) an amount of raw plant material feed directed to the pretreatment apparatus, and (iii) an amount of thin stillage fed to the backset directly from the thin stillage tank;

an evaporator for concentrating a first portion of the thin stillage into a syrup by boiling off vapor from the thin stillage; and

a biogas apparatus for processing at least one of a portion of the syrup and a second portion of the thin stillage to produce biogas and a biogas effluent, the biogas apparatus converting a percentage of the non-fermentable solids and organic acids in the syrup and the thin stillage into biogas and thereby reducing the concentration of the non-fermentable solids and organic acids in the biogas effluent;

wherein the biogas apparatus comprises a biogas discharge and a biogas effluent return, the biogas effluent return extends from the biogas apparatus into the backset return and into the pretreatment apparatus, resulting in a system that produces ethanol, biogas and byproducts that are recycled into the integrated apparatus at the pretreatment apparatus, and no thin stillage discharge extends from the integrated apparatus.

15. The integrated apparatus of claim 14, wherein the syrup and the thin stillage are provided to the biogas apparatus in any ratio.

16. The integrated apparatus of claim 14, the biogas apparatus comprising at least one anaerobic digester having microorganisms for processing the thin stillage;

wherein a pH of the at least one digester is controlled by addition of ammonia as a neutralizing agent; and

wherein the microorganisms are adapted for an ammonia environment.

17. The integrated apparatus of claim 14, wherein a third portion of the thin stillage is recycled directly as backset from the separator to the pretreatment apparatus;

and

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the amount of fresh water supplied to the pretreatment apparatus.

18. The integrated apparatus of claim 14, wherein a third portion of the thin stillage is recycled directly as backset from the separator to the pretreatment apparatus;

and

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the amount of the third portion of the thin stillage recycled directly as backset, reducing the amount of solids returned to the pretreatment apparatus so that more raw plant materials can be added to the pretreatment apparatus.

19. The integrated apparatus of claim 14, wherein the backset further comprises the vapor boiled off from the thin stillage;

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the first portion of the thin stillage that must be concentrated by the evaporator, thereby reducing the energy loading of the evaporator; and

wherein a reduction in the first portion of the thin stillage reduces the amount of the syrup.

20. The integrated apparatus of claim 14, further comprising a dryer for drying the wet distillers grains and the syrup;

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces the energy loading of the dryer by reducing the amount of the syrup that must be dried.

21. The integrated apparatus of claim 14, further comprising a dryer for drying the wet distillers grains and the syrup;

wherein an increase in the amount of backset obtained by recycling the biogas effluent from the biogas apparatus reduces or eliminates the syrup load-out from the system.

22. An integrated apparatus for producing ethanol and biogas from raw plant materials, the integrated apparatus comprising:

a pretreatment apparatus for converting raw plant materials into sugars, the pretreatment apparatus being supplied with an amount of fresh water and an amount of backset;

a fermenter including yeast for fermenting the sugars to produce a beer comprising ethanol;

a distillation apparatus for separating the beer into the ethanol and a whole stillage;

a separator for separating the whole stillage into a thin stillage and wet distillers grains, the thin stillage comprising non-fermentable solids and organic acids;

a thin stillage tank for collection of the thin stillage, the thin stillage tank having a first backset return supply, and a second biogas supply extending therefrom, the first backset return supply extending into the pretreatment apparatus and the second biogas supply extending into a biogas apparatus for processing a portion of the thin stillage to produce biogas and a biogas effluent,

wherein the biogas apparatus comprises a biogas discharge and a biogas effluent return, the biogas effluent return extends from the biogas apparatus into the backset return, and no thin stillage discharge extends from the integrated apparatus.