Polysaccharide compositions for absorbing aqueous liquid

• US 10,639,611 B2
• Filed: 04/13/2018
• Issued: 05/05/2020
• Est. Priority Date: 12/22/2014
• Status: Active Grant

• Current Assignee: Nutrition & Biosciences USA 4, Inc. (International Flavors & Fragrances Incorporated)
• Original Assignee: DuPont Industrial Biosciences USA, LLC (DuPont de Nemours, Inc.)
• Inventors: Behabtu, Natnael, Nambiar, Rakesh
• Primary Examiner(s): Fronda, Christian L
• Application Number:
  US15/952,401
• Publication Number:
  US 20180229214A1
• Time in Patent Office: 753 Days
• Field of Search: None
• CPC Class Codes: A61K 47/36 Polysaccharides; Derivatives thereof, e.g. gums, starch, alginate, dextrin, hyaluronic acid, chitosan, inulin, agar or pectin
• CPC Class Codes: B01J 20/24 Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
• CPC Class Codes: C08B 37/0009 alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
• CPC Class Codes: C08L 5/00 Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
• CPC Class Codes: C12P 19/04 Polysaccharides, i.e. compounds containing more than five saccharide radicals attached to each other by glycosidic bonds
• CPC Class Codes: C12P 19/18 produced by the action of a glycosyl transferase, e.g. alpha-, beta- or gamma-cyclodextrins

Abstract

Compositions are disclosed herein comprising poly alpha-1,3-glucan or poly alpha-1,3-1,6-glucan polymer having an open-cell pore structure with an average pore size of about 100 nm to about 3000 nm in diameter. Such polymers have enhanced aqueous liquid absorption capacity, and can be comprised in various products having aqueous liquid absorption function. Methods of preparing glucan polymers of the compositions provided herein are also disclosed.

Claims

1. A composition comprising a polymer that is poly alpha-1,3-glucan having at least 90% alpha-1,3 glucosidic linkages and a degree of polymerization of at least 100, wherein the polymer comprises an open-cell pore structure, wherein the polymer has not been chemically modified, wherein the polymer can absorb aqueous liquid, and wherein the composition is a personal care product, household product, medical product, or industrial product that absorbs aqueous liquid.

2. The composition of claim 1, wherein the polymer is an insoluble product of an enzymatic reaction comprising water, sucrose and a glucosyltransferase enzyme.

3. The composition of claim 2, and wherein the polymer is not completely dried after its production in said reaction.

4. The composition of claim 2, wherein the polymer is freeze-dried after its production in said reaction, and wherein said freeze-drying is the first time the polymer is dried.

5. The composition of claim 2, wherein residual water is removed from the polymer after its production in said reaction, wherein the residual water is removed in a manner that substantially preserves the nano-structure and/or micro-structure of the polymer as it existed before removal of residual water.

6. The composition of claim 1, wherein the poly alpha-1,3-glucan has at least 95% alpha-1,3 glucosidic linkages.

7. The composition of claim 6, wherein the poly alpha-1,3-glucan has at least 99% alpha-1,3 glucosidic linkages.

8. The composition of claim 5, wherein removal of the residual water does not comprise drying the polymer at a temperature of at least about 60°

C.

9. The composition of claim 5, wherein removal of the residual water does not comprise oven drying the polymer.

10. The composition of claim 1, wherein the polymer has a water retention value (WRV) of at least about 150.

11. The composition of claim 1, wherein the composition is said personal care product.

12. The composition of claim 11, wherein the personal care product is a diaper, pad, or feminine hygiene product.

13. The composition of claim 1, wherein the composition is said medical product.

14. The composition of claim 13, wherein the medical product is a wound healing dressing.

15. The composition of claim 14, wherein the wound healing dressing is a bandage or surgical pad.

16. The composition of claim 1, wherein the composition is said industrial product.

17. The composition of claim 16, wherein the industrial product is selected from the group consisting of (i) telecommunication cable wrapping, (ii) food pad, (iii) fire-fighting device, (iv) product for cleanup of acidic or basic aqueous solutions spills, and (v) agricultural or forestry product for retaining water in soil and/or to release water to plant roots.

18. An absorption method that comprises contacting a composition according to claim 1 with an aqueous liquid-comprising composition, wherein the composition absorbs aqueous liquid from said liquid-comprising composition.

19. The absorption method of claim 18, wherein the aqueous liquid-comprising composition comprises urine, blood, blood serum, liquid fecal matter, bile, stomach acid/juice, vomit, amniotic fluid, breast milk, cerebrospinal fluid, exudate, lymph, mucus, peritoneal fluid, pleural fluid, pus, rheum, saliva, sputum, synovial fluid, sweat, or tears.

20. The absorption method of claim 19, wherein the aqueous liquid-comprising composition comprises urine or blood.