Diffusion treatment device and method for manufacturing R-T-B system sintered magnet using same

• US 10,639,720 B2
• Filed: 08/19/2016
• Issued: 05/05/2020
• Est. Priority Date: 08/24/2015
• Status: Active Grant

• Current Assignee: Proterial Ltd.
• Original Assignee: Hitachi Metals Limited (Hitachi Metals (Thailand) Ltd.)
• Inventors: Kuniyoshi, Futoshi
• Primary Examiner(s): Su, Xiaowei
• Application Number:
  US15/754,647
• Publication Number:
  US 20180236554A1
• Time in Patent Office: 1,355 Days
• Field of Search: None
• CPC Class Codes: B22F 2003/248 Thermal after-treatment
• CPC Class Codes: B22F 2999/00 Aspects linked to processes or compositions used in powder metallurgy
• CPC Class Codes: B22F 3/003 Apparatus, e.g. furnaces in general F27B
• CPC Class Codes: B22F 3/24 After-treatment of workpieces or articles B22F3/1146 takes precedence
• CPC Class Codes: C22C 19/07 based on cobalt
• CPC Class Codes: C22C 2202/02 Magnetic
• CPC Class Codes: C22C 28/00 Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
• CPC Class Codes: C22C 33/02 by powder metallurgy working metallic powder B22F
• CPC Class Codes: C22C 38/00 Ferrous alloys, e.g. steel alloys cast-iron alloys C22C37/00
• CPC Class Codes: C22C 38/005 containing rare earths, i.e. Sc, Y, Lanthanides
• CPC Class Codes: C22C 38/10 containing cobalt
• CPC Class Codes: C22C 38/32 with boron
• CPC Class Codes: F27D 3/12 Travelling or movable supports or containers for the charge
• CPC Class Codes: H01F 1/0536 sintered
• CPC Class Codes: H01F 1/057 and IIIa elements, e.g. Nd2Fe14B
• CPC Class Codes: H01F 1/0577 sintered
• CPC Class Codes: H01F 1/08 pressed, sintered, or bound together
• CPC Class Codes: H01F 41/02 for manufacturing cores, coils, or magnets H01F41/14 takes precedence; for dynamo-electric machines H02K15/00
• CPC Class Codes: H01F 41/0293 diffusion of rare earth elements, e.g. Tb, Dy or Ho, into permanent magnets

Abstract

A diffusion treatment device includes: a treatment container including a cylindrical main body and first and second lids, the cylindrical main body having a treatment space which is capable of receiving sintered magnet pieces and RH diffusion sources, the first and second lids being capable of hermetically sealing first and second openings, respectively, at opposite ends of the cylindrical main body; a conveyor for conveying the treatment container by a predetermined distance in an x-axis direction while a longitudinal direction of the treatment container is located in a y-axis direction in a rectangular coordinate system xyz; a heating unit including a lower heating section provided under the treatment container and an upper heating section provided above the treatment container, and a first rotating unit for rotating the treatment container around a y-axis while the longitudinal direction of the treatment container is located in the y-axis direction.

Claims

1. A diffusion treatment device, comprising:

a treatment container including a cylindrical main body and a first lid and a second lid, the cylindrical main body having a treatment space which is capable of receiving a plurality of R-T-B sintered magnet pieces and diffusion sources, the first lid and the second lid being capable of hermetically sealing a first opening and a second opening, respectively, at opposite ends of the cylindrical main body;

a conveyor for conveying the treatment container by a predetermined distance in an x-axis direction while a longitudinal direction of the treatment container is located in a y-axis direction in a rectangular coordinate system xyz where a z-axis direction is a vertical direction;

a heating unit including a lower heating section provided under the treatment container and an upper heating section provided above the treatment container, at least one of the lower heating section and the upper heating section being movable in the z-axis direction and being arrangeable so as to surround at least a central part of the treatment container,

a first rotating unit for rotating the treatment container around a y-axis while the longitudinal direction of the treatment container is located in the y-axis direction and the treatment container is surrounded by the lower heating section and the upper heating section, and

a cooling unit subsequent to the heating unit, wherein

the cooling unit includes a lower cooling section provided under the treatment container and an upper cooling section provided above the treatment container, at least one of the lower cooling section and the upper cooling section being movable in the z-axis direction and being arrangeable so as to surround at least a central part of the treatment container.

2. The diffusion treatment device of claim 1, wherein the lower heating section and the upper heating section are each movable in the z-axis direction.

3. The diffusion treatment device of claim 1, wherein

the treatment container further includes a first flange and a second flange at opposite ends in the longitudinal direction, and

when the first lid is secured to the first flange and the second lid is secured to the second flange, the first opening and the second opening are respectively hermetically sealed.

4. The diffusion treatment device of claim 3, wherein

the first rotating unit includes a first wheel pair which is in contact with at least one of the first flange and the first lid and a second wheel pair which is in contact with at least one of the second flange and the second lid, and

the first wheel pair and the second wheel pair are each arranged along the x-axis direction and each include two wheels rotatable around the y-axis.

5. The diffusion treatment device of claim 4, wherein the treatment container is detached from the conveyor while the first wheel pair and the second wheel pair support the treatment container.

6. The diffusion treatment device of claim 4, wherein the two wheels of each of the first wheel pair and the second wheel pair have a variable rotation speed and/or are reversely rotatable.

7. The diffusion treatment device of claim 1, further comprising a connecting portion connected with either of the first lid or the second lid.

8. The diffusion treatment device of claim 7, further comprising a safety valve connected with the other of the first lid or the second lid.

9. The diffusion treatment device of claim 1, further comprising a first controller for outputting a signal for controlling at least one of movement of the treatment container in the x-axis direction, movement of the lower heating section and the upper heating section in the z-axis direction, and rotation of the first rotating unit.

10. The diffusion treatment device of claim 9, further comprising a second controller for outputting a signal for controlling the heating unit.

11. The diffusion treatment device of claim 1, wherein the lower cooling section and the upper cooling section are each movable in the z-axis direction.

12. The diffusion treatment device of claim 1, further comprising a second rotating unit for rotating the treatment container around the y-axis while the longitudinal direction of the treatment container is located in the y-axis direction and the treatment container is surrounded by the lower cooling section and the upper cooling section.

13. The diffusion treatment device of claim 1, wherein at least one of the lower cooling section and the upper cooling section includes at least one of an air inlet and a spray nozzle for water.

14. The diffusion treatment device of claim 1, further comprising a third controller for outputting a signal for controlling at least one of movement of the treatment container in the x-axis direction, movement of the lower cooling section and the upper cooling section in the z-axis direction, and rotation of the second rotating unit.

15. The diffusion treatment device of claim 14, further comprising a fourth controller for outputting a signal for controlling the cooling unit.

16. A method for manufacturing an R-T-B sintered magnet, comprising:

(a) providing an R-T-B sintered magnet piece in which an amount of R, which is defined by a content of a rare earth element, is not less than 29 mass % and not more than 40 mass %;

(b) providing diffusion sources;

(c) loading at least the sintered magnet piece and the diffusion sources into the treatment space of the diffusion treatment device as set forth in of claim 1;

(d) preheating at a temperature of not less than about 200°

C. and not more than about 600°

C. while vacuum-evacuating the treatment space;

(e) after the preheating, hermetically sealing the treatment space while the treatment space is in a reduced-pressure state or contains an inert gas; and

(f) a diffusion step including, after (e), heating the treatment container to a treatment temperature of not less than about 450°

C. and not more than about 1000°

C.

17. The method of claim 16, wherein the diffusion sources are RH diffusion sources including at least one of Dy and Tb.

18. The method of claim 16, wherein the diffusion sources are RH diffusion sources including at least one of Dy and Tb and are powder including particles of not more than 90 μ

m in size.

19. The method of claim 16, wherein the RH diffusion sources include a heavy rare earth element RH (at least one of Dy and Tb) and Fe in the proportion of not less than 30 mass % and not more than 80 mass %.