Intermediate film for laminated glass, and laminated glass

• US 10,639,868 B2
• Filed: 03/31/2015
• Issued: 05/05/2020
• Est. Priority Date: 03/31/2014
• Status: Active Grant

• Current Assignee: Sekisui Chemical Company Limited (Sekisui)
• Original Assignee: Sekisui Chemical Company Limited (Sekisui)
• Inventors: Yamamoto, Masaki, Yamaguchi, Kouhei, Nakajima, Daisuke
• Primary Examiner(s): Rioja, Melissa A
• Application Number:
  US15/129,738
• Publication Number:
  US 20170144413A1
• Time in Patent Office: 1,862 Days
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10678 comprising UV absorbers or stabilizers, e.g. antioxidants
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2250/03 3 layers
• CPC Class Codes: B32B 2307/304 Insulating
• CPC Class Codes: B32B 2307/54 Yield strength; Tensile strength
• CPC Class Codes: B32B 2307/558 Impact strength, toughness
• CPC Class Codes: B32B 2307/71 Resistive to light or to UV
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/20 using fillers, pigments, thixotroping agents
• CPC Class Codes: B32B 27/22 using plasticisers
• CPC Class Codes: B32B 27/42 comprising condensation resins of aldehydes, e.g. with phenols, ureas or melamines
• CPC Class Codes: B32B 37/10 characterised by the pressing technique, e.g. using action of vacuum or fluid pressure

Abstract

There is provided an interlayer film for laminated glass with which the adhesivity between a plastic layer and a resin layer can be heightened and the handling properties of laminated glass can be enhanced. The interlayer film for laminated glass according to the present invention includes a plastic layer with a Young'"'"'s modulus of higher than or equal to 1 GPa and a first resin layer layered on a first surface of the plastic layer, and is provided with a second resin layer layered on a second surface opposite to the first surface of the plastic layer or is provided with no second resin layer on a second surface opposite to the first surface of the plastic layer, and when a first lamination interface between the plastic layer and the first resin layer on a section in the thickness direction of the interlayer film is observed, the proportion of the length of a portion, which is not brought into contact with the first resin layer, of the plastic layer in the first lamination interface to 100% of the whole length of the plastic layer in the first lamination interface is less than or equal to 75%.

Claims

1. An interlayer film for laminated glass, comprising a plastic layer with a Young'"'"'s modulus of higher than or equal to 1 GPa and a first resin layer layered on a first surface of the plastic layer, the first resin layer having a Young'"'"'s modulus of lower than or equal to 0.05 GPa, and

being provided with a second resin layer layered on a second surface opposite to the first surface of the plastic layer or being provided with no second resin layer on a second surface opposite to the first surface of the plastic layer,

when a first interface between the plastic layer and the first resin layer on a section in a thickness direction of the interlayer film is observed, a proportion of a length of the plastic layer that is not in contact with the first resin layer is less than or equal to 75%, based upon 100% of a whole length of the plastic layer in the first interface.

2. The interlayer film for laminated glass according to claim 1, wherein in the case where the interlayer film is provided with the second resin layer, the Young'"'"'s modulus of the plastic layer is higher than the Young'"'"'s modulus of the second resin layer.

3. The interlayer film for laminated glass according to claim 1, wherein, in the case where the interlayer film is provided with the second resin layer, when a second interface between the plastic layer and the second resin layer on a section in the thickness direction of the interlayer film is observed, a proportion of a length of the plastic layer that is not in contact with the second resin layer is less than or equal to 75%, based upon 100% of a whole length of the plastic layer in the second interface.

4. The interlayer film for laminated glass according to claim 1, wherein the first resin layer contains a polyvinyl acetal resin and a plasticizer, and in the case where the interlayer film is provided with the second resin layer, the second resin layer contains a polyvinyl acetal resin and a plasticizer.

5. The interlayer film for laminated glass according to claim 1, wherein the first resin layer and the plastic layer are subjected to thermocompression bonding by a roll-to-roll process under conditions of a heating temperature of higher than or equal to 65°

C. and lower than or equal to 150°

C., a pressure at the time of compression bonding of greater than or equal to 0.1 kN and less than or equal to 5 kN and a tensile force during a step of transportation of the plastic layer in the roll-to-roll process of less than or equal to 100 N.

6. The interlayer film for laminated glass according to claim 1, being provided with the second resin layer.

7. The interlayer film for laminated glass according to claim 1, wherein the first resin layer contains an ultraviolet ray screening agent.

8. The interlayer film for laminated glass according to claim 1, being provided with the second resin layer,

wherein the second resin layer contains an ultraviolet ray screening agent.

9. The interlayer film for laminated glass according to claim 1, wherein the first resin layer contains an oxidation inhibitor.

10. The interlayer film for laminated glass according to claim 1, being provided with the second resin layer,

wherein the second resin layer contains an oxidation inhibitor.

11. A laminated glass, comprising a first laminated glass member, a second laminated glass member and an interlayer film for laminated glass according to claim 1, the interlayer film for laminated glass being arranged between the first laminated glass member and the second laminated glass member.

12. The interlayer film for laminated glass according to claim 7 wherein the content of the ultraviolet ray screening agent in the first resin layer is greater than or equal to 0.1% by weight and less than or equal to 2.5% by weight in 100% by weight of the first resin layer.

13. The interlayer film for laminated glass according to claim 1, wherein the plastic layer comprises two or more selected from the group consisting of a light stabilizer, a flame retardant, an antistatic agent, a pigment, a dye, an adhesive force regulating agent, a moisture-resistance improving agent, and a fluorescent brightening agent.

14. The interlayer film for laminated glass according to claim 6, wherein each of the first resin layer and the second resin layer comprises at least one selected from the group consisting of a phthalocyanine compound, a naphthalocyanine compound, and an anthracyanine compound.