Three-dimensional printing systems for rapidly producing objects

• US 10,639,877 B2
• Filed: 05/16/2016
• Issued: 05/05/2020
• Est. Priority Date: 05/15/2015
• Status: Active Grant

• Current Assignee: Dentsply Sirona INC. (Astrazeneca PLC)
• Original Assignee: Dentsply Sirona INC. (Astrazeneca PLC)
• Inventors: Sun, Benjamin Jiemin, Sun, Jessica Jiaxin
• Primary Examiner(s): Minskey, Jacob T
• Assistant Examiner(s): Tsui, Melody
• Application Number:
  US15/156,164
• Publication Number:
  US 20160332367A1
• Time in Patent Office: 1,450 Days
• CPC Class Codes: B29C 64/124 using layers of liquid which are selectively solidified
• CPC Class Codes: B29C 64/129 characterised by the energy source therefor, e.g. by global irradiation combined with a mask
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: B29C 64/205 Means for applying layers
• CPC Class Codes: B29C 64/314 Preparation
• CPC Class Codes: B29C 64/40 Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
• CPC Class Codes: B29K 2105/16 Fillers
• CPC Class Codes: B29L 2031/7536 Artificial teeth
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 30/00 Apparatus for additive manufacturing; Details thereof or accessories therefor
• CPC Class Codes: B33Y 50/02 for controlling or regulating additive manufacturing processes
• CPC Class Codes: B33Y 70/10 Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: C08F 20/12 of monohydric alcohols or phenols
• CPC Class Codes: C08K 2003/2227 of aluminium
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C08L 33/08 Homopolymers or copolymers of acrylic acid esters

Abstract

This invention relates to rapid prototyping systems, specifically, a continuous moving surface liquid resin system (CMSL) and fast printing method for making any 3D objects, such as dental devices, including but not limited to artificial teeth, dentures, orthodontic appliances, aligners, splints, veneers, inlays, onlays, copings, frame patterns, crowns and bridges and the like. 3D printers, such as DLP or stereolithography printer, are used to cure polymerizable material in a layer-by-layer manner to build-up the object rapidly and continuously.

Claims

1. A method for making a three-dimensional object comprising the steps of

a. loading a polymerizable liquid resin material or heated resin material as a liquid into a resin bath (vat) of a 3D printer;

b. positioning one or more mechanical arms on top of a clear and/or transparent window proximate to a bottom surface of the resin bath to maintain a liquid interface between a build surface and the clear and/or transparent window proximate to the bottom of the resin bath;

wherein the one or more mechanical arms include an edge that is in contact with the clear and/or transparent window;

c. applying sequential voxel planes into the liquid resin or the heated resin to form a first layer of material, which polymerizes into a first solid layer;

d. moving the one or more mechanical arms at a speed so that the edge removes at least a portion of the liquid resin or heated resin from pre-matured polymerization while separating and removing a portion of the first solid layer from the clear and/or transparent window using the edge of the one or more mechanical arms to clean the clear and/or transparent window;

e. supplying additional liquid resin or heated resin to the cleaned clear and/or transparent window;

f. applying sequential voxel planes into the additional liquid resin or the heated resin to form a second layer of material, which polymerizes into a second solid layer;

g. adjusting the speed of the one or more arms based on curing rate, curing area, curing volume, moving of building platform, and/or rheological behavior of the polymerizable liquid resin material or heated resin material so that the edge separates and removes a portion of the additional liquid resin or heated resin and a portion of the second solid layer from the clear and/or transparent window; and

h. applying one or more successive layers of the polymerized material continuously until a predetermined shape is formed.

2. The method of claim 1, wherein the applying steps are accomplished by a 3D printer selected from the group consisting of a DLP based, stereolithography based and other light irradiation based 3D printer.

3. The method of claim 1, wherein the one or more mechanical arms are in a form selected from the group consisting of a thin wire, a thin knife, a thin disk, a thin half circle wire, and any combinations thereof.

4. The method of claim 1, wherein the one or more mechanical arms are continuously moving during printing to maintain a thin liquid layer at ambient or elevated temperature on the clear and/or transparent window at the bottom of the resin bath.

5. The method of claim 4, wherein the thin liquid layer has a thickness of from about 0.02 mm to about 2 mm.

6. The method of claim 1, wherein the one or more mechanical arms have different cross-section shapes selected from the group consisting of a circle, triangle, square, wedge, rectangle, elliptical, diamond, and any combinations thereof.

7. The method of claim 1, wherein the one or more mechanical arms enable the continuous flow of highly viscous materials on the clear and/or transparent window at the bottom of the resin bath.

8. The method of claim 1, wherein a shear strain from the one or more mechanical arms form a thin layer of flowable material at the bottom of the resin bath.

9. The method of claim 1, wherein the one or more mechanical arms is at least two mechanical arms.

10. The method of claim 1, further comprising the step of utilizing a physical constraint form intimately above the one or more moveable mechanical arms, wherein the physical constraint form is in a shape selected from the group consisting of a tube, a ring, a diamond ring, a half-moon ring, a half cycle ring, an elliptical ring, a square ring, a rectangle ring and a combination thereof according to the predetermined need of the printed object and a shape of a building platform.

11. The method of claim 1, wherein the three-dimensional object is a dental prosthesis or dental device, selected from the group consisting of an artificial tooth, a denture, an orthodontic appliance, an aligner, a splint, a veneer, an inlay, an onlay, a coping, a frame pattern, a crown and a bridge.

12. The method of claim 1, wherein the liquid resin material or the heated resin material comprises at least a polymerizable material and polymerization initiation system capable of being activated by light.

13. The method of claim 1, wherein the resin material is heated to have a reduced viscosity or to achieve a sufficient flowable state.

14. The method of claim 12, wherein the polymerizable material comprises at least one of polymerizable acrylic oligomers, one or more prepolymers and one or more monomers.

15. The method of claim 12, wherein the polymerizable material further comprises a particulate filler.

16. The method of claim 15, wherein the particulate filler is selected from the group consisting of silica, alumina, silicon nitride, polymers, inorganic articulates, glasses and any combinations thereof.

17. The method of claim 12, wherein the polymerization initiation system comprises a photoactive agent, selected from the group consisting of camphorquinone, 2,4,6 trimethylbenzoyldiphenyl phosphine oxide, and any combination thereof.

18. The method of claim 12, wherein the polymerizable material further comprises one or more pigments.

19. The method of claim 12, wherein the polymerizable material further comprises one or more inhibitors.