Method for producing tetrafluoropropene

• US 10,640,438 B2
• Filed: 05/17/2017
• Issued: 05/05/2020
• Est. Priority Date: 05/19/2016
• Status: Active Grant

• Current Assignee: Arkema France (Arkema)
• Original Assignee: Arkema France (Arkema)
• Inventors: Deur-Bert, Dominique, Garrait, Dominique, Pigamo, Anne, Wendlinger, Laurent
• Primary Examiner(s): Parsa, Jafar F
• Application Number:
  US16/099,208
• Publication Number:
  US 20190210943A1
• Time in Patent Office: 1,084 Days
• CPC Class Codes: B01J 19/02 Apparatus characterised by being constructed of material selected for its chemically-resistant properties
• CPC Class Codes: B01J 2208/00371 gaseous
• CPC Class Codes: B01J 2219/0286 Steel
• CPC Class Codes: B01J 2219/0295 Synthetic organic materials
• CPC Class Codes: B01J 38/12 Treating with free oxygen-containing gas
• CPC Class Codes: B01J 8/0457 the beds being placed in separate reactors
• CPC Class Codes: B01J 8/0492 Feeding reactive fluids for solid material, see B01J8/0015
• CPC Class Codes: C07C 17/206 the other compound being HX
• CPC Class Codes: C07C 21/18 containing fluorine

Abstract

The present invention concerns a method for preparing tetrafluoropropene utilising three reactors and comprising the steps of (a) implementing, in the first and second reactors, at least one step of reacting, in the gas phase, a compound B in the presence of hydrofluoric acid and a catalyst, in alternation with a step of regenerating the catalyst by bringing it into contact with a regeneration flow comprising an oxidising agent, (b) implementing, in the third reactor, a preliminary step of producing the compound B, in alternation with a step of regenerating the preliminary catalyst with a regeneration flow comprising an oxidising agent. The step of regenerating the preliminary catalyst in the third reactor is implemented in the absence of a step of reacting the compound B in the presence of hydrofluoric acid in said first and second reactors. The present invention also concerns a facility configured to implement the present method.

Claims

1. A process for the manufacture of tetrafluoropropene employing three reactors and comprising the stages of:

carrying out, in the first and the second reactor, at least one stage of reaction in the gas phase of a compound B in the presence of hydrofluoric acid and of a catalyst, in order to form the tetrafluoropropene;

alternately with a stage of regeneration of the catalyst by bringing the latter into contact with a regeneration stream comprising an oxidizing agent,

carrying out, in the third reactor, a preliminary stage of manufacture of the compound B using a preliminary catalyst, alternately with a stage of regeneration of the preliminary catalyst with a regeneration stream comprising an oxidizing agent,

wherein;

when the stage of regeneration of the preliminary catalyst in the third reactor is carried out, the first reactor and the second reactor are, independently of one another, either in a phase of regeneration of the catalyst or in a waiting phase.

2. The process as claimed in claim 1, further comprising:

collecting a stream of products on conclusion of the preliminary stage of manufacture of the compound B;

using said stream of products in order to carry out the stage of reaction of the compound B in the presence of hydrofluoric acid; and

separating the stream of products resulting from the stage of reaction of the compound B in the presence of hydrofluoric acid into a first stream comprising hydrochloric acid and tetrafluoropropene and a second stream comprising hydrofluoric acid and the compound B;

optionally, collecting said second stream comprising hydrofluoric acid and the compound B, and the recycling said second stream in the stage of reaction of the compound B with hydrofluoric acid or of the preliminary stage of manufacture of the compound B.

3. The process as claimed in claim 1, wherein the stage of regeneration of the preliminary catalyst in the third reactor is carried out simultaneously with the stage of regeneration of the catalyst in the first reactor or the second reactor or both.

4. The process as claimed in claim 1, wherein, in the first reactor and the second reactor, the stage of reaction of a compound B in the presence of hydrofluoric acid is carried out alternately with the regeneration stage.

5. The process as claimed in claim 1, wherein the reactors are made of steel and have an interior surface covered with an alloy comprising more than 30% by weight of nickel or with a fluoropolymer-type coating.

6. The process as claimed in claim 1, wherein the tetrafluoropropene comprises 2,3,3,3-tetrafluoropropene or 1,3,3,3-tetrafluoropropene.

7. The process as claimed in claim 1, wherein the preliminary stage of manufacture of compound B is a preliminary stage of reaction in the gas phase of a compound A in the presence of hydrofluoric acid and of a preliminary catalyst, said compound A being different from said compound B, wherein the compound A is selected from the group consisting of tetrachloropropenes, chlorotrifluoropropenes, pentachloropropanes, dichlorotrifluoropropanes, trichlorodifluoropropanes, tetrachlorofluoropropanes, dichlorodifluoropropenes, trichlorofluoropropenes and the mixtures of these;

and the compound B is selected from the group consisting of chlorotrifluoropropenes, pentafluoropropanes, dichlorotrifluoropropanes, trichlorodifluoropropanes, tetrachlorofluoropropanes, dichlorodifluoropropenes, trichlorofluoropropenes and the mixtures of these.

8. The process as claimed in claim 1, wherein the regeneration stream is in the same direction or in the reverse direction, with respect to the direction of introduction into the first reactor or the second reactor of a reaction stream comprising the compound B and hydrofluoric acid.

9. The process as claimed in claim 1, wherein the direction of the regeneration stream is alternated at each regeneration stage.