Oxidatively drying polyurethane dispersions with particularly high chemical resistance
First Claim
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1. A polyurethane A) comprising as synthesis components:
- A1) 40 to 60 wt % of an oxidatively drying, OH-functional triglyceride,A2) 30 to 55 wt % of 4,4′
-diisocyanato-dicyclohexylmethane,A3) 3 to 15 wt % of one or more cycloaliphatic diols comprising cyclohexanedimethanol,A4) 1 to 20 wt % of a compound having at least one isocyanate-reactive group and at least one ionic and/or potentially ionic function,A5) 1 to 20 wt % of one or more mono-, di- or triamines having a molecular weight of less than 300 g/mol,A6) 0 to 10 wt % of a neutralizing agent for converting a potentially ionic function, where present, of component A4) into an ionic function, andA7) 0 to 5 wt % of a urethanization catalyst,wherein the wt % is based on the total amount of all synthesis components, and the sum total of all the components does not exceed 100%.
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Abstract
The present invention relates to hydrophilized polyurethanes having a particularly high content of hydroxy-functional, unsaturated triglycerides, to a process for preparing polyurethane dispersions based thereon, to the use of the dispersions as binders in oxidatively drying coating materials having particularly high chemical resistance, and to articles and substrates coated with these coating materials.
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14 Claims
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1. A polyurethane A) comprising as synthesis components:
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A1) 40 to 60 wt % of an oxidatively drying, OH-functional triglyceride, A2) 30 to 55 wt % of 4,4′
-diisocyanato-dicyclohexylmethane,A3) 3 to 15 wt % of one or more cycloaliphatic diols comprising cyclohexanedimethanol, A4) 1 to 20 wt % of a compound having at least one isocyanate-reactive group and at least one ionic and/or potentially ionic function, A5) 1 to 20 wt % of one or more mono-, di- or triamines having a molecular weight of less than 300 g/mol, A6) 0 to 10 wt % of a neutralizing agent for converting a potentially ionic function, where present, of component A4) into an ionic function, and A7) 0 to 5 wt % of a urethanization catalyst, wherein the wt % is based on the total amount of all synthesis components, and the sum total of all the components does not exceed 100%. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 10, 11, 12, 13, 14)
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9. A polyurethane A) consisting of as synthesis components:
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A1) 40 to 60 wt % of an oxidatively drying, OH-functional triglyceride, A2) 30 to 55 wt % of 4,4′
-diisocyanato-dicyclohexylmethane,A3) 3 to 15 wt % of one or more cycloaliphatic diols comprising cyclohexanedimethanol, A4) 1 to 20 wt % of a compound having at least one isocyanate-reactive group and at least one ionic and/or potentially ionic function, A5) 1 to 20 wt % of one or more mono-, di- or triamines having a molecular weight of less than 300 g/mol, A6) 0 to 10 wt % of a neutralizing agent for converting a potentially ionic function, where present, of component A4) into an ionic function, and A7) 0 to 5 wt % of a urethanization catalyst, wherein the wt % is based on the total amount of all synthesis components, and the sum total of all the components does not exceed 100%.
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Specification