Stretchable polymer thick film compositions for thermoplastic substrates and wearables electronics

• US 10,640,678 B2
• Filed: 08/08/2018
• Issued: 05/05/2020
• Est. Priority Date: 11/06/2014
• Status: Active Grant

• Current Assignee: Du Pont China Limited (DuPont de Nemours, Inc.)
• Original Assignee: DuPont Electronics, Inc. (DuPont de Nemours, Inc.)
• Inventors: Burrows, Michael Zanoni, Critzer, Mark Steven, Dorfman, Jay Robert
• Primary Examiner(s): Mc Ginty, Douglas J
• Application Number:
  US16/058,344
• Publication Number:
  US 20180346757A1
• Time in Patent Office: 636 Days
• Field of Search: 252511, 252514, 174251, 174257, 524590
• CPC Class Codes: C08K 2003/0806 Silver
• CPC Class Codes: C08K 3/08 Metals
• CPC Class Codes: C08K 3/36 Silica
• CPC Class Codes: C09D 175/08 from polyethers
• CPC Class Codes: C09D 5/24 Electrically-conducting paints conductive materials H01B1/00
• CPC Class Codes: H01B 1/22 the conductive material comprising metals or alloys
• CPC Class Codes: H05K 1/0283 Stretchable printed circuits
• CPC Class Codes: H05K 1/0326 containing O
• CPC Class Codes: H05K 1/0346 containing N
• CPC Class Codes: H05K 1/09 Use of materials for the conductive, e.g. metallic pattern
• CPC Class Codes: H05K 1/095 for polymer thick films, i.e. having a permanent organic polymeric binder
• CPC Class Codes: H05K 2201/0129 Thermoplastic polymer, e.g. auto-adhesive layer; Shaping of thermoplastic polymer

Abstract

This invention is directed to stretchable polymer thick film compositions useful for wearable garments. More specifically, the polymer thick film may be used in applications where significant stretching is required, particularly on substrates that can be highly elongated. A particular type of substrate is a thermoplastic polyurethane substrate.

Claims

1. A polymer thick film metal conductor paste composition comprising:

(a) an electrically conductive metal powder, wherein said metal is selected from the group consisting of Ag, Cu, Au, Pd, Pt, Sn, Al, Ni, an alloy of Ag, Cu, Au, Pd, Pt, Sn, Al, Ni and mixtures thereof; and

(b) an organic medium comprising 5-50 wt % thermoplastic polyurethane resin dissolved in an organic solvent, said thermoplastic polyurethane resin having a percent elongation of at least 200% and a tensile stress necessary to achieve 100% elongation of less than 1000 psi, wherein the weight percent is based on the total weight of said organic medium.

2. The polymer thick film metal conductor paste composition of claim 1, wherein said electrically conductive metal powder is silver powder and said polymer thick film metal conductor paste composition is a polymer thick film silver conductor paste composition.

3. The polymer thick film metal conductor paste composition of claim 2, wherein said silver powder is in the form of silver flakes and wherein said thermoplastic polyurethane resin is selected from the group consisting of a polyester-based polymer, a urethane homopolymer and a predominantly linear hydroxyl polyurethane.

4. The polymer thick film metal conductor paste composition of claim 1, said polymer thick film metal conductor paste composition comprising 20 to 92 wt % electrically conductive metal powder and 8 to 80 wt % organic medium, wherein the wt % are based on the total weight of said composition.

5. A polymer thick film silver/silver chloride conductor paste composition comprising:

(a) silver powder in combination with silver chloride powder; and

(b) an organic medium comprising 5-50 wt % thermoplastic polyurethane resin dissolved in an organic solvent, said thermoplastic polyurethane resin having a percent elongation of at least 200% and a tensile stress necessary to achieve 100% elongation of less than 1000 psi, wherein the weight percent is based on the total weight of said organic medium.

6. The polymer thick film silver/silver chloride conductor paste composition of claim 5, wherein said silver powder is in the form of silver flakes and wherein said thermoplastic polyurethane resin is selected from the group consisting of a polyester-based polymer, a urethane homopolymer and a predominantly linear hydroxyl polyurethane.

7. The polymer thick film silver/silver chloride conductor paste composition of claim 6, said polymer thick film silver/silver chloride conductor paste composition comprising 20 to 92 wt % silver flakes in combination with silver chloride powder and 8 to 80 wt % organic medium, wherein the wt % are based on the total weight of said composition.

8. A polymer thick film carbon paste composition comprising:

(a) graphite, conductive carbon or a mixture thereof; and

(b) an organic medium comprising 5-50wt % thermoplastic polyurethane resin dissolved in an organic solvent, said thermoplastic polyurethane resin having a percent elongation of at least 200% and a tensile stress necessary to achieve 100% elongation of less than 1000 psi, wherein the weight percent is based on the total weight of said organic medium.

9. The polymer thick film carbon paste composition of claim 8, said polymer thick film carbon paste composition comprising 20 to 92 wt % graphite, conductive carbon or a mixture thereof and 8 to 80 wt % organic medium, wherein the wt % are based on the total weight of said composition and wherein said thermoplastic polyurethane resin is selected from the group consisting of a polyester-based polymer, a urethane homopolymer and a predominantly linear hydroxyl polyurethane.