Methods for retrieving, reclaiming, or recycling petroleum-based products and byproducts

• US 10,640,712 B2
• Filed: 05/18/2018
• Issued: 05/05/2020
• Est. Priority Date: 11/18/2016
• Status: Active Grant

• Current Assignee: Kailey Marie Fitzpatrick, Kevin Thomas Fitzpatrick, Michael Fitzpatrick, Michelle Kotevska, Stojan Kotefski
• Original Assignee: Kailey Marie Fitzpatrick, Kevin Thomas Fitzpatrick, Michael Fitzpatrick, Michelle Kotevska, Stojan Kotefski
• Inventors: Kotefski, Stojan, Fitzpatrick, Michael, Fitzpatrick, Kevin Thomas, Kotevska, Michelle, Fitzpatrick, Kailey Marie
• Primary Examiner(s): Singh, Prem C
• Assistant Examiner(s): Doyle, Brandi M
• Application Number:
  US15/983,886
• Publication Number:
  US 20180334620A1
• Time in Patent Office: 718 Days
• CPC Class Codes: B01D 11/0288 Applications, solvents
• CPC Class Codes: B01D 11/0296 Condensation of solvent vapours condensation in general B01D5/00
• CPC Class Codes: B09B 3/00 Destroying solid waste or transforming solid waste into something useful or harmless
• CPC Class Codes: B09B 3/40 involving thermal treatment, e.g. evaporation processes using mineral binders involving a melting or softening step B09B3/29; involving radiation B09B3/50
• CPC Class Codes: B09B 3/80 involving an extraction step
• CPC Class Codes: B09C 1/02 Extraction using liquids, e.g. washing, leaching , flotation
• CPC Class Codes: C10C 1/14 Winning of tar oils from tar
• CPC Class Codes: C10C 1/18 by extraction with selective solvents preparation of hydrocarbon oils from tar oils C10G21/00
• CPC Class Codes: C10C 3/007 winning and separation of asphalt from mixtures with aggregates, fillers and other products, e.g. winning from natural asphalt and regeneration of waste asphalt
• CPC Class Codes: C10C 3/08 by selective extraction

Abstract

A method is disclosed for the retrieval and recovery of organic-based or organic-containing materials, including naturally occurring substances such as crude oil, and other petroleum-based or containing materials, natural gas, and the like, from environments where they are entrained within or otherwise admixed or complexed with other organic or inorganic materials, such as rock, sand, shale and the like. The method comprises: retrieving a quantity of the petroleum-containing mixture, treating the petroleum-containing mixture with a solvent for the petroleum material to separate the petroleum material from the mixture, and recovering the separated petroleum-containing material. The solvent may be at approximately ambient temperature and may be, for instance, heptane, hexane, naphtha, kerosene, gasoline or a petroleum based solvent or any other suitable solvent in which the asphalt binder is soluble.

Claims

1. A method to remove, retrieve, or recover a petroleum product or a petroleum byproduct from a petroleum-containing mixture, wherein the petroleum-containing mixture is composed of a petroleum-based material or a petroleum-containing material, and an inorganic material or mineral, the method comprising:

providing the petroleum-containing mixture;

wherein the petroleum product or petroleum byproduct is contained in any of the petroleum-based material or the petroleum-containing material, and is in a solid state at ambient temperature;

submerging the petroleum-containing mixture in a liquid oil-based solution that is heated and maintained at a temperature higher than a phase-change or melting temperature of the petroleum product or the petroleum byproduct;

upon submerging the petroleum-containing mixture in the heated liquid oil-based solution, the heated liquid oil-based solution provides an environmental seal to the petroleum product or petroleum byproduct, so that the environmental seal prevents the sealed petroleum product or petroleum byproduct from degrading or burning, which allows the environmentally sealed petroleum product or petroleum byproduct to achieve phase-change from the solid state to a liquid state; and

wherein the liquified petroleum product or petroleum byproduct dissolves into the heated liquid oil-based solution, to create a liquid composition of oil-based solution and of petroleum product or petroleum byproduct; and

substantially removing, retrieving, or recovering the petroleum product or petroleum byproduct from the petroleum-containing mixture.

2. The method of claim 1, wherein the solid petroleum product or petroleum byproduct is bonded to the inorganic material or mineral contained in the petroleum-containing mixture;

and

wherein as the liquified petroleum product or petroleum byproduct dissolves in the liquid oil-based solution, the inorganic material or mineral becomes separated, in a free state, from the bond of the petroleum product or petroleum byproduct.

3. The method of claim 2, wherein the liquid composition provides a liquid oil-based coating on the separated inorganic material or mineral.

4. The method of claim 3, further including using a solvent to remove the liquid oil-based coating from the inorganic material or mineral.

5. The method of claim 1, further including, prior to submerging the petroleum-containing mixture in the liquid oil-based solution, providing at ambient temperature, a single solvent wash or bath in which the solid state petroleum product or petroleum byproduct dissolves in part.

6. The method of claim 5, wherein the single solvent wash or bath dissolves between 25% to 50% of the solid state petroleum product or petroleum byproduct.

7. The method of claim 6, further including separating or recovering the petroleum product or petroleum byproduct from the solvent.

8. The method of claim 1, wherein the petroleum-containing mixture includes asphalt mixture.

9. The method of claim 8, wherein the asphalt mixture contains any one or more of:

roofing shingle;

roofing paper;

roofing tar;

asphalt;

used pavement asphalt;

asphalt milling;

patch mix material;

crack sealer material;

surface texture material; and

petroleum coating.

10. The method of claim 1, wherein the petroleum product or petroleum byproduct that is removed, retrieved, or recovered from the petroleum-containing mixture includes asphalt binder, asphalt, or petroleum.

11. The method of claim 1, wherein removing, retrieving, or recovering the petroleum product or the petroleum byproduct from the petroleum-containing mixture, includes treating a contaminated site.

12. The method of claim 11, wherein treating the contaminated site includes treating any one or more of:

an oil spill, a soil contamination, and a hazardous waste spill.

13. The method of claim 11, wherein the petroleum product or petroleum byproduct that is removed, retrieved, or recovered from the contaminated site includes any one or more of:

gasoline, kerosene, heating oil, and diesel fuel.

14. The method of claim 1, wherein removing, retrieving, or recovering the petroleum product or the petroleum byproduct from the petroleum-containing mixture, includes treating a natural mixture or deposit.

15. The method of claim 14, wherein the natural mixture or deposit includes any one or more of:

oil sand, tar sand, and shale.

16. The method of claim 15, wherein the petroleum product or petroleum byproduct that is removed, retrieved, or recovered from the natural mixture or deposit includes any one or more of:

petroleum;

oil; and

shale oil.

17. The method of claim 1, wherein upon submerging the petroleum-containing mixture in the heated liquid oil-based solution, the heated liquid oil-based solution provides a thermal conductance and heat energy to the petroleum product or petroleum byproduct to provide thermal energy that allows the petroleum product or petroleum byproduct to phase-change from the solid state to the liquid state.

18. The method of claim 1, wherein the petroleum product or petroleum byproduct coats the inorganic material or mineral in the petroleum-containing mixture.

19. The method of claim 7, wherein separating or recovering the petroleum product or petroleum byproduct from the solvent includes using a solvent recovery system.

20. The method of claim 1, wherein the oil-based solution includes any one or more of:

virgin motor oil, recycled motor oil, and a petroleum-based liquid that can be safely elevated to temperatures up to 500 degrees Fahrenheit at atmospheric pressure.