Supercritical CO2 power generating system for preventing cold-end corrosion

• US 10,641,132 B2
• Filed: 07/09/2018
• Issued: 05/05/2020
• Est. Priority Date: 07/17/2017
• Status: Active Grant

• Current Assignee: Doosan Heavy Industries and Construction Company Limited
• Original Assignee: Doosan Heavy Industries Construction Co., Ltd.
• Inventors: Cha, Song Hun
• Primary Examiner(s): Nguyen, Hoang M
• Application Number:
  US16/029,651
• Publication Number:
  US 20190017417A1
• Time in Patent Office: 666 Days
• Field of Search: 60670-681
• CPC Class Codes: F01K 11/02 the engines being turbines
• CPC Class Codes: F01K 13/003 Arrangements for measuring or testing in general G01
• CPC Class Codes: F01K 13/02 Controlling, e.g. stopping or starting
• CPC Class Codes: F01K 25/103 Carbon dioxide F01K25/065 takes precedence
• CPC Class Codes: F01K 7/32 the engines using steam of critical or overcritical pressure

Abstract

A supercritical CO₂ power generating system prevents cold-end corrosion capable of improving reliability against cold-end corrosion by including a recirculation pump. Part of the working fluid heated in the low-temperature-side external heat exchanger using the recirculation pump is mixed with the low-temperature working fluid at the rear end of the pump, to heat the working fluid above the temperature of the dewpoint of the waste heat gas. The heated working fluid is then supplied to the external heat exchanger. By reducing the cold-end corrosion phenomenon of the low-temperature-side external heat exchanger, the life of the external heat exchanger can be increased and the reliability of the external heat exchanger and the supercritical CO₂ power generating system can be improved.

Claims

1. A power generating system using supercritical CO₂ as a working fluid for driving a turbine, the system comprising:

a plurality of heat exchangers for heating the working fluid using heat supplied from an external heat source, the plurality of heat exchangers including a low-temperature-side heat exchanger;

a pump for compressing the working fluid, the working fluid passing through the pump being branched into a first part of the working fluid and a second part of the working fluid for supplying the low-temperature-side heat exchanger;

a pump for compressing the working fluid, the working fluid passing through the pump being branched into a first part of the working fluid and a second part of the working fluid for supplying the low-temperature-side heat exchanger;

at least one recuperator for exchanging heat between the working fluid passing through the turbine and the first part of the working fluid passing through the pump, to cool the working fluid from the turbine and to heat the working fluid from the pump; and

a condenser for cooling the working fluid primarily cooled by the at least one recuperator and supplying the cooled working fluid to the pump,

wherein the second part of the working fluid passing through the pump is mixed with an additional part of the working fluid to be supplied to the low-temperature-side heat exchanger, and

wherein the additional part of the working fluid to be supplied to the low-temperature-side heat exchanger is branched from an outlet of the low-temperature-side heat exchanger.

2. The system of claim 1, further comprising:

a recirculation pump for pressurizing the additional part of the working fluid to be supplied to the low-temperature-side heat exchanger.

3. The system of claim 2, wherein the plurality of heat exchangers use waste heat gas as the external heat source and include:

a high-temperature-side heat exchanger which is adjacent to an inlet end into which the waste heat gas is introduced from the external heat source, and

the low-temperature-side heat exchanger which is adjacent to an outlet end from which the waste heat gas is discharged.

4. The system of claim 3,

wherein the working fluid passing through the recirculation pump includes the additional part of the working fluid to be supplied to the low-temperature-side heat exchanger, and the working fluid supplied to the low-temperature-side heat exchanger is the mixture of the second part of the working fluid and the additional part of the working fluid, and

wherein the temperature of the working fluid supplied to the low-temperature-side heat exchanger is above a dewpoint temperature of the waste heat gas supplied to the low-temperature-side heat exchanger.

5. The system of claim 4, further comprising:

a control valve connected to an outlet of the recirculation pump and configured to control a flow rate of the working fluid supplied to the low-temperature-side heat exchanger.

6. The system of claim 4, further comprising:

a variable frequency driver provided to the recirculation pump to control a flow rate of the working fluid supplied to the low-temperature-side heat exchanger.

7. The system of claim 4, further comprising:

at least one temperature indicating transmitter for measuring the temperature of the working fluid at the inlet of the low-temperature-side heat exchanger.

8. The system of claim 7, further comprising:

a controller connected to the temperature indicating transmitter to control, based on the measured temperature, a flow rate of the working fluid supplied to the low-temperature-side heat exchanger.

9. The system of claim 8, wherein the controller increases the flow rate of the working fluid supplied to the recirculation pump if the temperature of the waste heat gas introduced into the low-temperature-side heat exchanger is lower than a preset temperature.

10. The system of claim 8, wherein the controller decreases the flow rate of the working fluid supplied to the recirculation pump if the temperature of the waste heat gas introduced into the low-temperature-side heat exchanger is higher than a preset temperature.

11. The system of claim 8, wherein the controller increases the flow rate of the working fluid supplied to the recirculation pump if the temperature of the working fluid introduced into the low-temperature-side heat exchanger is lower than a preset temperature.

12. The system of claim 8, wherein the controller decreases the flow rate of the working fluid supplied to the recirculation pump if the temperature of the working fluid introduced into the low-temperature-side heat exchanger is higher than a preset temperature.

13. A power generating system using supercritical CO₂ as a working fluid for driving a turbine, the system comprising:

a plurality of heat exchangers for heating the working fluid using heat supplied from an external heat source, the plurality of heat exchangers including a low-temperature-side heat exchanger and at least one of a high-temperature-side heat exchanger and a middle-temperature heat exchanger;

a pump for compressing the working fluid, the working fluid passing through the pump being branched into a first part of the working fluid and a second part of the working fluid for supplying the low-temperature-side heat exchanger;

at least one recuperator for exchanging heat between the working fluid passing through the turbine and the first part of the working fluid passing through the pump, to cool the working fluid from the turbine and to heat the working fluid from the pump;

a condenser for cooling the working fluid primarily cooled by the at least one recuperator and supplying the cooled working fluid to the pump; and

a recirculation pump connected to an outlet of the low-temperature-side heat exchanger to recirculate part of the working fluid discharged from the low-temperature-side heat exchanger,

wherein the low-temperature-side heat exchanger is supplied with a mixture of the working fluid passing through the recirculation pump and the second part of the working fluid passing through the pump.

14. The system of claim 13, wherein the plurality of heat exchangers use waste heat gas as the external heat source and include:

a high-temperature-side heat exchanger which is adjacent to an inlet end into which the waste heat gas is introduced from the external heat source, and

the low-temperature-side heat exchanger which is adjacent to an outlet end from which the waste heat gas is discharged.

15. The system of claim 14, wherein the mixture of the working fluid passing through the recirculation pump and the second part of the working fluid passing through the pump has a temperature above a dewpoint temperature of the waste heat gas supplied to the low-temperature-side heat exchanger.

16. A power generating system using supercritical CO₂ as a working fluid for driving a turbine, the system comprising:

a plurality of heat exchangers for heating the working fluid using heat supplied from an external heat source, the plurality of heat exchangers including a low-temperature-side heat exchanger and at least one of a high-temperature-side heat exchanger and a middle-temperature heat exchanger;

a pump for compressing the working fluid, the working fluid passing through the pump being branched into a first part of the working fluid and a second part of the working fluid for supplying the low-temperature-side heat exchanger;

at least one recuperator for exchanging heat between the working fluid passing through the turbine and the first part of the working fluid passing through the pump, to cool the working fluid from the turbine and to heat the working fluid from the pump;

a condenser for cooling the working fluid primarily cooled by the at least one recuperator and supplying the cooled working fluid to the pump; and

a recirculation pump connected to an inlet of the condenser to recompress part of the working fluid supplied to the condenser,

wherein the low-temperature-side heat exchanger is supplied with a mixture of the working fluid passing through the recirculation pump and the second part of the working fluid passing through the pump.

17. The system of claim 16, wherein the plurality of heat exchangers use waste heat gas as the external heat source and include:

a high-temperature-side heat exchanger which is adjacent to an inlet end into which the waste heat gas is introduced from the external heat source, and

the low-temperature-side heat exchanger which is adjacent to an outlet end from which the waste heat gas is discharged.

18. The system of claim 17, wherein the mixture of the working fluid passing through the recirculation pump and the second part of the working fluid passing through the pump has a temperature above a dewpoint temperature of the waste heat gas supplied to the low-temperature-side heat exchanger.