Detection of nitrogen containing and nitrogen free explosives

• US 10,641,752 B2
• Filed: 05/30/2017
• Issued: 05/05/2020
• Est. Priority Date: 05/30/2017
• Status: Active Grant

• Current Assignee: Scintrex Trace Corporation (AUTOCLEAR)
• Original Assignee: Scintrex Trace Corporation (AUTOCLEAR)
• Inventors: Nguyen, Dao Hinh
• Primary Examiner(s): Hixson, Christopher Adam
• Assistant Examiner(s): Berkeley, Emily R.
• Application Number:
  US15/608,911
• Publication Number:
  US 20180348184A1
• Time in Patent Office: 1,071 Days
• Field of Search: 422940
• CPC Class Codes: G01N 21/766 of gases
• CPC Class Codes: G01N 27/125 Composition of the body, e.g. the composition of its sensitive layer
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array
• CPC Class Codes: G01N 33/0037 NOx
• CPC Class Codes: G01N 33/004 CO or CO2
• CPC Class Codes: Y02A 50/20 Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

Abstract

A compact explosive detecting system collects explosive residues in the form of vapor powder. The residues are accumulated on a desorber which is subjected to pyrolysis to release a gaseous sample. The sample is pumped to a detecting system through a metering valve. A luminol cell reacts with the gaseous sample to create chemiluminescence, the light output of which is measured by a photo multiplier tube. The light intensity is indicative of the amount of explosive present. Based on the amount of explosive present, a metering valve is adjusted to pass the gaseous sample into a highly sensitive metal oxide sensor array to detect NO₂ from nitrogen containing explosive and CO/CO₂ from non nitrogen containing explosive. The metal oxide sensor array reliably selects explosives from those compounds indicating chemiluminescence.

Claims

1. A system for screening for the presence of nitrogen containing explosives, the system comprising:

a. a chamber for collecting explosive residues;

b. a desorber;

c. a pyrolysis tube for pyrolyzing said explosive residue to generate a gaseous sample from decomposition of the explosive residues comprising NO₂;

d. a pump for pumping the gaseous sample sequentially into a luminol reaction cell followed by transferring a smaller portion of the gaseous sample to a metal oxide sensor (MOS) array or pumping the gaseous sample partially into a luminol cell and partially to an MOS array;

e. said luminol producing chemiluminescence by a chemical reaction between said luminol and said gaseous sample within said reaction cell;

f. measuring means comprising photomultiplier tube or photodiode array for measuring the intensity of chemiluminescence and for outputting a first electrical signal indicative of the amount of explosive detected;

g. a reduced quantity of said gaseous sample configured to be pumped to said metal oxide sensor array to prevent saturation of metal oxide detector;

h. the MOS array comprising a conductivity sensor having a thin ceramic or fused silica sheet with an oxide sensing layer or oxide film and electrodes for measuring electrical resistance of the oxide sensing layer or oxide film, said electrical resistance being changed by adsorption of said pumped gaseous sample indicating the presence of said explosive;

whereby the chemiluminescence measurement is refined by the metal oxide sensor measurement to eliminate the interference composition from detection.

2. The system for screening for the presence of explosives as recited by claim 1, wherein said explosive is a nitrogen free explosive, the pyrolysis of which releases CO/CO₂.

3. The system for screening for the presence of explosives as recited by claim 1, wherein said metal oxide sensor array includes metal oxide sensors for detecting NO₂.

4. The system for screening for the presence of explosives as recited by claim 1, wherein the resistance of said metal oxide sensor increases when exposed to a gaseous sample containing oxidized NO₂.

5. The system for screening for the presence of explosives as recited by claim 1, wherein the resistance of said metal oxide sensor decreases when exposed to a gaseous sample containing reduced CO/CO₂.

6. A system as recited by claim 1, wherein said metal oxide sensor is made by coating a thin sheet of ceramic or a thin sheet of fused silica onto the underside with a nickel or nickel chromium electrode heater having the top surface coated with sensing metal oxide film.

7. A system as recited by claim 6, wherein said metal oxide sensor is operated at a temperature range of 300 to 800°

C.

8. A system as recited by claim 6, wherein said metal oxide sensor is operated at a temperature of 700°

C.

9. A system as recited by claim 6, wherein said metal oxide film is a member selected from the group consisting of tin oxide, indium tin oxide, and tungsten oxide semiconductor.

10. A system for screening for the presence of nitrogen containing explosives, the system comprising:

a. a chamber for collecting explosive residues;

b. a desorber;

c. a pyrolysis tube for pyrolyzing said explosive residue to generate a gaseous sample from decomposition of the explosive residues comprising NO₂;

d. a pump for pumping the gaseous sample to a metal oxide sensor (MOS) array;

e. a metering valve for reducing the quantity of said gaseous sample to said metal oxide sensor array, to prevent saturation of metal oxide detector;

f. the MOS array comprising a conductivity sensor having a thin ceramic sheet or fused silica sheet with an oxide sensing layer or oxide film and electrodes for measuring electrical resistance of the oxide sensing layer or oxide film, said electrical resistance being changed by adsorption of said pumped gaseous sample indicating the presence of said explosive.