Fluid for electrowetting device and electrowetting device using the same

• US 10,642,024 B2
• Filed: 03/27/2015
• Issued: 05/05/2020
• Est. Priority Date: 05/22/2014
• Status: Active Grant

• Current Assignee: Samsung Electronics Co. Ltd., Seoul National University R&DB Foundation (Seoul National University)
• Original Assignee: Samsung Electronics Co. Ltd.
• Inventors: Choi, Kyuhwan, Bae, Jungmok, Kwon, Yongjoo, Kim, Yunhee, Chung, Taekdong, Choi, Yoonsun
• Primary Examiner(s): Thomas, Brandi N
• Application Number:
  US14/671,171
• Publication Number:
  US 20150338636A1
• Time in Patent Office: 1,866 Days
• Field of Search: 359237, 359242, 359245, 359250, 359253, 359254, 359290-292, 359295, 359296, 359298
• CPC Class Codes: G02B 26/005 based on electrowetting

Abstract

An electrowetting device which includes a polarizable liquid; and a nonpolar solution separated from the polarizable liquid by an interface. The polarizable liquid may include a polar solvent, an organic acid, and ammonium hydroxide having at least one alkyl group.

Claims

1. A fluid for an electrowetting device, the fluid comprising:

a polarizable liquid; and

a nonpolar solution separated from the polarizable liquid by an interface,

wherein the polarizable liquid comprises a polar solvent, an organic acid, and ammonium hydroxide having at least one alkyl group,

wherein a weight of the organic acid with respect to a total weight of the polarizable liquid is 0.1% to 10%,

wherein the polar solvent comprises ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, diethylene glycol, propylene carbonate, diethyl carbonate, gamma-butyrolactone (GBL), dimethylformamide (DMF), N-methylpyrrolidone (NMP), or a mixture thereof, and

wherein a weight ratio of the ammonium hydroxide having the at least one alkyl group to the organic acid is in a range of about 0.8 to about 1.2, and

when the weight ratio is 1, the polarizable liquid has a first surface tension,

when the weight ratio is 0.8, the polarizable liquid has a surface tension of about 50% of the first surface tension, and

when the weight ratio is 1.2, the polarizable liquid has a surface tension of about 200% of the first surface tension.

2. The fluid of claim 1, wherein the organic acid comprises acetic acid, propionic acid, acrylic acid, lactic acid, isobutyric acid, tartaric acid, citric acid, cresol, phenol, polyacetic acid, polyacrylic acid, or a derivative thereof.

3. The fluid of claim 1, wherein the ammonium hydroxide having the at least one alkyl group comprises tetramethylammonium hydroxide, tetraethylammonium hydroxide, triethylmethylammonium hydroxide, diethyl dimethylammonium hydroxide, ethyltrimethylammonium hydroxide, or trimethylphenylammonium hydroxide.

4. The fluid of claim 1, wherein the nonpolar solution comprises oil.

5. The fluid of claim 1, wherein the polarizable liquid has an electrical conductivity of about 10 μ

S/cm to about 10,000 μ

S/cm.

6. The fluid of claim 1, wherein the polarizable liquid has a freezing point of about −

5°

C. to about −

100°

C.

7. The fluid of claim 1, wherein the polarizable liquid has a surface tension of about 6 mN/m to about 12 mN/m.

14. The fluid of claim 1, wherein the weight of the organic acid with respect to the total weight of the polarizable liquid is 0.1% to 3.0%.

8. An electrowetting device comprising:

a first electrode and a second electrode facing each other;

a dielectric film formed on the first electrode and the second electrode; and

a fluid for electrowetting disposed between the first electrode and the second electrode, and separated from the first electrode and the second electrode by the dielectric film,

wherein the fluid for electrowetting comprises a polarizable liquid comprising a polar solvent, an organic acid, and ammonium hydroxide having at least one alkyl group, and a nonpolar solution separated from the polarizable liquid by an interface,

wherein a weight of the organic acid with respect to a total weight of the polarizable liquid is 0.1% to 10%,

wherein the polar solvent comprises ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, diethylene glycol, propylene carbonate, diethyl carbonate, gamma-butyrolactone (GBL), dimethylformamide (DMF), N-methylpyrrolidone (NMP), or a mixture thereof, and

wherein a weight ratio of the ammonium hydroxide having the at least one alkyl group to the organic acid is in a range of about 0.8 to about 1.2, and

when the weight ratio is 1, the polarizable liquid has a first surface tension,

when the weight ratio is 0.8, the polarizable liquid has a surface tension of about 50% of the first surface tension, and

when the weight ratio is 1.2, the polarizable liquid has a surface tension of about 200% of the first surface tension.

9. The electrowetting device of claim 8, wherein the organic acid comprises acetic acid, propionic acid, acrylic acid, lactic acid, isobutyric acid, tartaric acid, citric acid, cresol, phenol, polyacetic acid, polyacrylic acid, or a derivative thereof.

10. The electrowetting device of claim 8, wherein the ammonium hydroxide having the at least one alkyl group comprises tetramethylammonium hydroxide, tetraethylammonium hydroxide, triethylmethylammonium hydroxide, diethyldimethylammonium hydroxide, ethyltrimethylammonium hydroxide, or trimethylphenylammonium hydroxide.

11. The electrowetting device of claim 8, wherein the nonpolar solution comprises oil.

12. The electrowetting device of claim 8, wherein signals are applied to the first and second electrodes to control a contact angle of the first fluid and the second fluid within a range of about 20°

to about 160°

.

13. An electrowetting cell comprising:

a first electrode;

a second electrode; and

a fluid comprising a polarizable liquid and a nonpolar solution,

wherein the polarizable liquid and the nonpolar solution are separated by an interface, the polarizable liquid comprises a polar solvent, an organic acid, and ammonium hydroxide having at least one alkyl group, and signals applied to the first and second electrodes control an incline angle of the interface,

wherein a weight of the organic acid with respect to a total weight of the polarizable liquid is 0.1% to 10%,

wherein the polar solvent comprises ethylene glycol, 1,2-propylene glycol, 1,3-propylene glycol, diethylene glycol, propylene carbonate, diethyl carbonate, gamma-butyrolactone (GBL), dimethylformamide (DMF), N-methylpyrrolidone (NMP), or a mixture thereof, and

wherein a weight ratio of the ammonium hydroxide having the at least one alkyl group to the organic acid is in a range of about 0.8 to about 1.2, and

when the weight ratio is 1, the polarizable liquid has a first surface tension,

when the weight ratio is 0.8, the polarizable liquid has a surface tension of about 50% of the first surface tension, and

when the weight ratio is 1.2, the polarizable liquid has a surface tension of about 200% of the first surface tension.