High efficiency photovoltaic cells with self concentrating effect

• US 10,644,174 B2
• Filed: 03/30/2017
• Issued: 05/05/2020
• Est. Priority Date: 09/26/2006
• Status: Active Grant

• Current Assignee: Banpil Photonics, Inc.
• Original Assignee: Banpil Photonics, Inc.
• Inventors: Dutta, Achyut Kumar
• Primary Examiner(s): Mowla, Golam
• Application Number:
  US15/474,232
• Publication Number:
  US 20170236953A1
• Time in Patent Office: 1,132 Days
• CPC Class Codes: H01L 31/02168 the coatings being antireflective or having enhancing optical properties for the solar cells
• CPC Class Codes: H01L 31/0236 Special surface textures
• CPC Class Codes: H01L 31/02363 of the semiconductor body itself, e.g. textured active layers
• CPC Class Codes: H01L 31/0296 including, apart from doping material or other impurities, only AIIBVI compounds, e.g. CdS, ZnS, HgCdTe
• CPC Class Codes: H01L 31/0352 characterised by their shape or by the shapes, relative sizes or disposition of the semiconductor regions
• CPC Class Codes: H01L 31/035281 Shape of the body
• CPC Class Codes: H01L 31/03529 Shape of the potential jump barrier or surface barrier
• CPC Class Codes: H01L 31/0547 comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
• CPC Class Codes: Y02E 10/52 PV systems with concentrators

Abstract

This invention relates to a novel structure of photovoltaic devices (e.g. photovoltaic cells also called as solar cells) are provided. The cells are based on the micro or nano scaled structures which could not only increase the surface area but also have the capability of self-concentrating the light incident onto the photonics devices. More specifically, the structures are based on 3D structure including quintic or quintic-like shaped micor-nanostructures. By using such structures reflection loss of the light from the cell is significantly reduced, increasing the absorption, which results in increasing the conversion efficiency of the solar cell, and reducing the usage of material while increasing the flexibility of the solar cell. The structures can be also used in other optical devices wherein the reflection loss and absorption are required to enhanced to significantly improve the device performances.

Claims

1. A photovoltaic cell comprising:

a substrate having a top surface,

wherein said top surface of the substrate has a three-dimensional geometric pattern etched from the substrate or formed on the substrate,

wherein the three-dimensional geometric pattern comprising an array of quintic, or quintic-like, or truncated quintic, or truncated quintic-like, or the combination thereof, shaped nano-scaled or micrometer-scaled protruding structures;

an absorption layer comprising at least one pn-junction,

wherein the at least one pn-junction comprises at least one first electrical material of p or n type, and at least one second electrical material of opposite type to the at least one first electrical material,

wherein said at least one first electrical material is conformally overlaying the protruding structures;

a pair of electrodes for a front electrode and a back electrode,

wherein the pair of electrodes electrically connects to the at least one pn-junction; and

an antireflective layer,

wherein the substrate is being a single piece of material,

wherein the nearest neighbors of two protruding structures from the array of protruding structures has a void or space created in between, and

wherein a passivation material fills the void or space between the nearest neighbors of the two protruding structures.

2. The photovoltaic cell of claim 1, wherein the protruding structures has a base, selected from a group consisting of elliptical, parabolic, rectangular, triangular, circular, trapezoidal, hexagonal, elliptical, and a combination thereof.

3. The photovoltaic cell of claim 1, wherein the protruding structures are arranged in a 2-dimensional array or in a 1-dimensional array.

4. The photovoltaic cell of claim 1, wherein the antireflective layer overlays the front electrode.

5. The photovoltaic cell of claim 1, further comprising a layer to hold the substrate.

6. The photovoltaic cell of claim 1, further comprising a reflection layer to reflect radiation back and forth until fully absorbed.

7. The photovoltaic cell of claim 4, wherein the height of each protruding structure is in between 580 nm to 1200 nm.

8. The photovoltaic cell of claim 1, wherein the protruding structures stand with an angle with respect to a base, of the protruding structures, wherein the angle is fixed or varied, and wherein the protruding structures are randomly or periodically aligned.

9. A photovoltaic cell comprising:

a substrate having a top surface,

wherein said top surface of the substrate has a three-dimensional geometric pattern etched from the substrate or formed on the substrate,

wherein the three-dimensional geometric pattern comprising an array of quintic, or quintic-like, or truncated quintic, or truncated quintic-like, or the combination thereof, shaped nano-scaled or micrometer-scaled protruding structures;

an absorption layer comprising at least one pn-junction,

wherein the at least one pn-junction comprises at least one first electrical material of p or n type, and at least one second electrical material of opposite type to the at least one first electrical material, wherein said at least one first electrical material is conformally overlaying the protruding structures;

a pair of electrodes for a front electrode and a back electrode,

wherein the pair of electrodes electrically connects to the at least one pn-junction;

at least one reflecting layer to reflect back and forth a radiation until fully absorbed; and

an antireflective layer,

wherein the substrate is being a single piece of material,

wherein the nearest neighbors of two protruding structures from the array of protruding structures has a void or space created in between, and

wherein a passivation material fills the void or space between the nearest neighbors of the two protruding structures.

10. The photovoltaic cell of claim 9, wherein the protruding structures has a base, selected from a group consisting of elliptical, parabolic, rectangular, triangular, circular, trapezoidal, hexagonal, elliptical, and a combination thereof.

11. The photovoltaic cell of claim 9, wherein the protruding structures has a gap between the structures, wherein the gaps are fixed or varied in a distance, and wherein the distances are randomly or periodically aligned.

12. The photovoltaic cell of claim 9, wherein the protruding structures has a height, wherein the height Is fixed, or varied, and wherein the protruding structures are random or periodically aligned.

13. The photovoltaic cell of claim 9, wherein the protruding structures stand with an angle with respect to a base of the protruding structures, wherein the angle is fixed or varied, and wherein the protruding structures are randomly or periodically aligned.

14. The photovoltaic cell of claim 9, wherein the protruding structures are arranged in a 2-dimensional array or in a 1-dimensional array.

15. A photovoltaic cell comprising:

a substrate having a top surface,

wherein said top surface of the substrate has a three-dimensional geometric pattern etched from the substrate or formed on the substrate,

wherein the three-dimensional geometric pattern comprising an array of quintic, or quintic-like, or truncated quintic, or truncated quintic-like, or the combination thereof, shaped nano-scaled or micrometer-scaled protruding structures;

an absorption layer comprising at least one pn-junction,

wherein the at least one pn-junction comprises at least one first electrical material of p or n type, and at least one second electrical material of opposite type to the at least one first electrical material, wherein said at least one first electrical material is conformally overlaying the protruding structures;

a pair of electrodes for a front electrode and a back electrode,

wherein the pair of electrodes electrically connects to the at least one pn-junction;

at least one reflecting layer to reflect back and forth a radiation until fully absorbed; and

an antireflective layer,

wherein the antireflective layer overlays the front electrode,

wherein the substrate is being a single piece of material,

wherein the nearest neighbors of two protruding structures from the array of protruding structures has a void or space created in between, and

wherein a passivation material fills the void or space between the nearest neighbors of the two protruding structures.

16. The photovoltaic cell of claim 15, wherein the protruding structures has a gap between the structures, wherein the gaps are fixed or varied in a distance, and wherein the distances are randomly or periodically aligned.

17. The photovoltaic cell of claim 15, wherein the protruding structures has a height, wherein the height Is fixed, or varied, and wherein the protruding structures are random or periodically aligned.

18. The photovoltaic cell of claim 15, wherein the protruding structures stand with an angle with respect to a base of the protruding structures, wherein the angle is fixed or varied, and wherein the protruding structures are random or periodically aligned.

19. The photovoltaic cell of claim 15, wherein the protruding structures are arranged in a 2-dimensional array or a 1-dimensional array.