Packaging material for electrochemical cells

• US 10,644,271 B1
• Filed: 06/25/2018
• Issued: 05/05/2020
• Est. Priority Date: 01/08/2013
• Status: Active Grant

• Current Assignee: Rutgers University
• Original Assignee: Rutgers University
• Inventors: Amatucci, Glenn G., Halajko, Anna B., Sung, Linda Wu, Ferrer, Anthony
• Primary Examiner(s): Yanchuk, Stephen J
• Application Number:
  US16/017,927
• Time in Patent Office: 680 Days
• CPC Class Codes: B32B 2250/02 2 layers
• CPC Class Codes: B32B 2250/24 All layers being polymeric
• CPC Class Codes: B32B 2255/10 on synthetic resin layer or on natural or synthetic rubber layer
• CPC Class Codes: B32B 2255/205 Metallic coating
• CPC Class Codes: B32B 2307/31 Heat sealable
• CPC Class Codes: B32B 2307/732 Dimensional properties
• CPC Class Codes: B32B 2457/10 Batteries
• CPC Class Codes: B32B 2553/00 Packaging equipment or accessories not otherwise provided for
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/28 comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
• CPC Class Codes: C08G 2261/3424 non-conjugated, e.g. paracyclophanes or xylenes
• CPC Class Codes: C08G 2261/614 for liquids
• CPC Class Codes: C09D 165/04 Polyxylylenes
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 50/124 having a layered structure
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The described invention relates to the use of parylene and composites of parylene as a flexible, sealable, and near hermetic barrier packaging material for nonaqueous electrochemical cells. Additionally, the invention relates to the technique of sealing of battery packaging material through the use of ultrasonic energy, and to the use of a low melting temperature inorganic barrier, which is predisposed between higher melting temperature polymer layers, that can be sealed to form a truly hermetic barrier at the interface.

Claims

1. A method comprising:

obtaining an electrochemical cell;

forming a first sheet of packaging material;

wherein the first sheet of packaging material comprises a first layer of para-xylylene polymer;

forming a second sheet of packaging material;

wherein the second sheet of packaging material comprises a second layer of para-xylylene polymer;

bonding the first layer of para-xylylene polymer of the first sheet to the second layer of para-xylylene polymer of the second sheet using ultrasonic energy to form a bonded sheet;

bonding the first layer of para-xylylene polymer to a third layer of first metal to form the first sheet of packaging material;

bonding the second layer of para-xylylene polymer to a fourth layer of second metal to form the second sheet of packaging material;

forming a free-standing package using the bonded sheet;

encapsulating the electrochemical cell in the free-standing package;

wherein the electrochemical cell comprises an anode, a cathode, and an electrolyte in contact with the anode and the cathode, wherein the first layer of para-xylylene polymer and the second layer of para-xylylene polymer are in contact with the electrolyte.

2. The method of claim 1, wherein the forming the free-standing package step and the encapsulating step are conducted concomitantly.

3. The method of claim 1, wherein at least one of the first metal and the second metal comprises at least one of aluminum, copper, bismuth, lead, tin, gallium, or indium.

4. The method of claim 3, further comprising bonding the third layer of the first metal and the fourth layer of the second metal to form a hermetic seal.

5. The method of claim 4, wherein the step of bonding the third layer of the first metal and the fourth layer of the second metal is conducted using at least one of thermal energy, ultrasonic energy, or laser energy.

6. The method of claim 1, wherein the electrochemical cell comprises current collecting tabs, wherein the current collecting tabs extend from an interior space of the free-standing package to an environment outside of the free-standing package between the first sheet of packaging material and the second sheet of packaging material.

7. The method of claim 1, wherein at least one of the first sheet of packaging material or the second sheet of packaging material comprises a plurality of alternating layers of para-xylylene polymer and metal.

8. A method comprising:

forming a first sheet of packaging material;

wherein the first sheet of packaging material comprises a first layer of para-xylylene polymer;

forming a second sheet of packaging material;

wherein the second sheet of packaging material comprises a second layer of para-xylylene polymer;

bonding the first layer of para-xylylene polymer of the first sheet to the second layer of para-xylylene polymer of the second sheet using ultrasonic energy to form a bonded sheet;

bonding the first layer of para-xylylene polymer to a third layer of first metal to form the first sheet of packaging material;

bonding the second layer of para-xylylene polymer to a fourth layer of second metal to form the second sheet of packaging material;

forming a free-standing package using the bonded sheet,

wherein the free-standing package is configured to encapsulate an electrochemical cell comprising an anode, a cathode, and an electrolyte in contact with the anode and the cathode, wherein the first layer of para-xylylene polymer and the second layer of para-xylylene polymer are in contact with the electrolyte.

9. The method of claim 8, wherein at least one of the first metal and the second metal comprises at least one of aluminum, copper, bismuth, lead, tin, gallium, or indium.

10. The method of claim 9, further comprising bonding the third layer of the first metal and the fourth layer of the second metal to form a hermetic seal.

11. The method of claim 10, wherein the step of bonding the third layer of the first metal and the fourth layer of the second metal is conducted using at least one of thermal energy, ultrasonic energy, or laser energy.

12. The method of claim 8, wherein at least one of the first sheet of packaging material or the second sheet of packaging material comprises a plurality of alternating layers of para-xylylene polymer and metal.