Methods for determining anode integrity during fuel cell vehicle operation

• US 10,644,336 B2
• Filed: 12/12/2014
• Issued: 05/05/2020
• Est. Priority Date: 12/12/2014
• Status: Active Grant

• Current Assignee: Ford Global Technologies, LLC (Ford Motor Company)
• Original Assignee: Ford Global Technologies, LLC (Ford Motor Company)
• Inventors: Milacic, Milos, Peterson, Craig Winfield, Schamel, Andreas R.
• Primary Examiner(s): Ruddock, Ula C
• Assistant Examiner(s): Parsons, Thomas H.
• Application Number:
  US14/568,994
• Publication Number:
  US 20160172696A1
• Time in Patent Office: 1,971 Days
• CPC Class Codes: H01M 2250/20 Fuel cells in motive systems, e.g. vehicle, ship, plane
• CPC Class Codes: H01M 8/04574 Current
• CPC Class Codes: H01M 8/04679 of fuel cell stacks
• CPC Class Codes: H01M 8/04753 of fuel cell reactants
• CPC Class Codes: H01M 8/04992 characterised by the implementation of mathematical or computational algorithms, e.g. feedback control loops, fuzzy logic, neural networks or artificial intelligence
• CPC Class Codes: Y02E 60/50 Fuel cells
• CPC Class Codes: Y02T 90/40 Application of hydrogen technology to transportation, e.g. using fuel cells

Abstract

A system and methods are provided for testing anode integrity during vehicle operation. In one example described, the system and methods allow for anode leak tests during vehicle operation based on a flow of hydrogen into a fuel cell, the flow of hydrogen into the fuel cell maintaining the vehicle power while the leak test is performed. The methods further allow for operational adjustments responsive to the leak test, which may include controlling the vehicle power to manage vehicle operations in the presence of a hydrogen leak in some instances.

Claims

1. A method, comprising:

identifying an anode leak during vehicle operation while a fuel cell is not under stable load via a leak test that compares a current generated by the fuel cell to a current predicted for a flow of hydrogen to the fuel cell, the current generated by the fuel cell maintaining a vehicle power, including,

calculating the current predicted based on electrochemical conversion of the flow of hydrogen to the fuel cell,

storing current predicted data and current generated data over time in a data buffer, the current predicted including a running average current predicted calculated from the stored current predicted data corresponding only to when a hydrogen purge valve is closed and the current generated including a running average current generated calculated from the stored current generated data corresponding only to when the hydrogen purge valve is closed, and

identifying the anode leak based on the current generated deviating from the current predicted.

2. The method of claim 1, further comprising reducing the vehicle power responsive to identifying the anode leak while providing sufficient power to operate a vehicle.

3. The method of claim 2, wherein reducing the vehicle power includes actuating a tank valve to reduce the flow of hydrogen to the fuel cell, the reduced flow of hydrogen providing the reduced vehicle power that operates the vehicle.

4. The method of claim 1, further comprising identifying the anode leak based on a statistical comparison of the current generated and the current predicted for the flow of hydrogen to the fuel cell, the statistical comparison being a two-sample t-test.

5. The method of claim 4, wherein the current predicted exceeds the current generated when a leak is present, an extent of the current predicted relative to the current generated being further used to determine a size of the leak.

6. The method of claim 5, wherein the flow of hydrogen to the fuel cell is adjusted while providing power to a vehicle, the flow of hydrogen being adjusted to supply sufficient fuel for powering the vehicle in the presence of the leak.

7. The method of claim 6, further comprising closing a tank valve to shut-off the flow of hydrogen to the fuel cell responsive to the leak.

8. The method of claim 7, wherein operational adjustments are made to power the vehicle using an alternate power source responsive to the flow of hydrogen to the fuel cell.

9. The method of claim 1, wherein identifying the anode leak based on the current generated deviating from the current predicted includes identifying the anode leak based on the current generated deviating from the current predicted in response to an amount of storage capacity consumed by current data stored in the data buffer increasing above a threshold storage capacity.

10. The method of claim 1, wherein storing current predicted data and current generated data over time in the data buffer includes storing the current predicted data and the current generated data over time in the data buffer when the hydrogen purge valve is open and when the hydrogen purge valve is closed.

11. A method for a hydrogen fuel cell, comprising:

determining anode integrity during vehicle operation while the fuel cell is under variable load via a leak test configured to compare a predicted current based on a flow of hydrogen to the fuel cell to a current generated by the fuel cell, wherein the predicted current includes a running average predicted current calculated from predicted current data stored over time in a data buffer corresponding only to when hydrogen purging from the fuel cell is stopped, and wherein the current generated includes a running average current generated calculated from current generated data stored over time in the data buffer corresponding only to when hydrogen purging from the fuel cell is stopped, the flow of hydrogen to the fuel cell providing power to a vehicle during the leak test, wherein a leak is identified in response to the generated current deviating from the predicted current by more than a threshold amount, and the predicted current is calculated based on electrochemical conversion of the flow of hydrogen to the fuel cell.

12. The method of claim 11, wherein the comparison includes processing a data envelope associated with one or more of the predicted and generated currents, the comparison further including a two-sample t-test that determines anode integrity based on the data envelope.

13. The method of claim 12, further comprising estimating an extent of the leak based on a degree of difference between the predicted and generated currents and the data envelope associated therewith.

14. The method of claim 13, further comprising adjusting the flow of hydrogen to the fuel cell responsive to the leak, and performing a confirmatory leak test.

15. The method of claim 14, wherein the confirmatory leak test is one or more of an idle leak test and a pressure decay test.

16. The method of claim 15, wherein the extent of the leak determines the anode integrity, the anode integrity being further communicated to a vehicle operator.

17. A method for a hydrogen fuel cell vehicle, comprising:

identifying an anode leak during vehicle operation while a fuel cell is operated under variable load based on a comparison of a current generated by the fuel cell to a current predicted for a flow of hydrogen delivered to the fuel cell, the current predicted including a running average current predicted calculated from current predicted data stored over time in a data buffer corresponding only to when purging of hydrogen from the fuel cell is stopped, the current generated including a running average current generated calculated from current generated data stored over time in the data buffer corresponding only to when purging of hydrogen from the fuel cell is stopped, the flow of hydrogen delivered to the fuel cell maintaining vehicle operation in a presence of the leak, wherein the current predicted is calculated based on electrochemical conversion of the flow of hydrogen delivered to the fuel cell, and the leak is identified in response to the current generated deviating from the current predicted by more than a threshold amount;

estimating a size of the leak and setting a flag that communicates the leak to a vehicle operator; and

adjusting the flow of hydrogen responsive to the leak to adjust a vehicle power.

18. The method of claim 17, further comprising reducing the flow of hydrogen to the fuel cell responsive to the leak and performing a confirmatory leak test responsive to the reduced flow of hydrogen, the confirmatory leak test comprising a pressure decay test.

19. The method of claim 18, further including switching the vehicle power to an alternate power source to power the vehicle while the flow of hydrogen to the fuel cell is reduced.

20. The method of claim 18, further comprising shutting off the flow of hydrogen to the fuel cell responsive to the confirmatory leak test indicating the presence of the leak.