Network of dividing-wall columns in complex processing units

• US 10,653,975 B2
• Filed: 04/27/2019
• Issued: 05/19/2020
• Est. Priority Date: 04/30/2018
• Status: Active Grant

• Current Assignee: Sulzer Management AG (Sulzer AG)
• Original Assignee: GTC Technology US, LLC (Sulzer AG)
• Inventors: Bhargava, Manish, Kalita, Roomi, Kanda, Amit
• Primary Examiner(s): Jeong, Youngsul
• Assistant Examiner(s): Gitman, Gabriel E
• Application Number:
  US16/396,663
• Publication Number:
  US 20190329151A1
• Time in Patent Office: 388 Days
• CPC Class Codes: B01D 3/141 where at least one distillation column contains at least one dividing wall
• CPC Class Codes: B01D 3/146 Multiple effect distillation
• CPC Class Codes: C10G 35/00 Reforming naphtha
• CPC Class Codes: C10G 65/043 at least one step being a change in the structural skeleton
• CPC Class Codes: C10G 7/00 Distillation of hydrocarbon oils

Abstract

A processing unit includes a naphtha hydrotreating unit comprising a first divided wall column, a naphtha splitter system, and a deisopentanizer column coupled to an output of a naphtha splitter of the naphtha splitter system, an isomerization unit coupled to an outlet of the deisopentanizer column, and a second divided wall column. The processing unit also includes an isomerization reactor coupled between the deisopentanizer column and the stabilizer column.

Claims

1. A processing unit comprising:

a naphtha hydrotreating unit comprising a first divided wall column, a naphtha splitter system, and a deisopentanizer column;

wherein the first divided wall column comprises;

a wall dividing a top portion of the first divided wall column into a first top section and a second top section;

an outlet associated with the second top section of the first divided wall column for recovery of liquid petroleum gas; and

an outlet associated with a bottoms portion of the first divided wall column and coupled to the naphtha splitter system;

wherein the deisopentanizer column is coupled to an output of the naphtha splitter system;

an isomerization unit coupled to an outlet of the deisopentanizer column and comprising a second divided wall column and a stabilizer column;

wherein the second divided wall column comprises;

a wall dividing a top portion of the second divided wall column into a first top section and a second top section;

an inlet coupled to an outlet of a stabilizer column of the isomerization unit;

an outlet associated with the second top section of the second divided wall column for recovery of a first isomerate stream; and

an outlet associated with a bottoms portion of the second divided wall column for recovery of a second isomerate stream;

wherein the stabilizer column comprises an outlet associated with a bottom section of the stabilizer column and coupled to the second divided wall column and an outlet associated with a top section of the stabilizer column and coupled to the first top section of the first divided wall column; and

an isomerization reactor coupled between the deisopentanizer column and the stabilizer column.

2. The processing unit of claim 1, wherein the naphtha splitter system comprises a third divided wall column, the third divided wall column comprising:

a wall dividing a middle portion of the third divided wall column into a first middle section and a second middle section;

an inlet coupled to the bottoms portion of the first divided wall column;

an outlet associated with a top portion of the third divided wall column for recovery of a first naphtha stream;

an outlet associated with the second middle section for recovery of a second naphtha stream; and

an outlet associated with a bottoms portion of the third divided wall column for recovery of a third naphtha stream.

3. The processing unit of claim 1, wherein the stabilizer column is coupled to an outlet of the isomerization reactor.

4. The processing unit of claim 1, wherein the isomerization reactor is coupled to the bottoms portion of the second divided wall column.

5. The processing unit of claim 1, wherein the second divided wall column is heat integrated with the deisopentanizer column.

6. The processing unit of claim 1, further comprising an inlet associated with the first top section of the first divided wall column and coupled to the bottoms portion of the first divided wall column.

7. The processing unit of claim 1, further comprising an outlet associated with the top of the second divided wall column and coupled to the deisopentanizer column.

8. The processing unit of claim 1, wherein the first top section of the first divided wall column is configured to perform as a stabilizer and the second top section of the first divided wall column is configured to perform as deethanizer.

9. The processing unit of claim 1, wherein the first top section of the second divided wall column is configured to perform as a depentanizer and the second top section of the second divided wall column is configured to perform as a deisohexanizer.

10. An integrated hydrocarbon conversion process for use in a system comprising a naphtha hydrotreating unit and an isomerization unit, the process comprising:

providing a feed to a first divided wall column, the first divided wall column comprising;

a wall dividing a top portion of the first divided wall column into a first top section and a second top section;

an outlet associated with the second top section of the first divided wall column for recovery of liquid petroleum gas; and

an outlet associated with a bottoms portion of the first divided wall column and coupled to a naphtha splitter system;

removing liquid petroleum gas from the second top section of the first divided wall column;

feeding a bottoms product from the first divided wall column to a second divided wall column, the second divided wall column comprising;

a wall dividing a middle portion of the second divided wall column into a first middle section and a second middle section;

an inlet coupled to the bottoms portion of the first divided wall column;

an outlet associated with a top portion of the second divided wall column for recovery of a first naphtha stream;

an outlet associated with the second middle section for recovery of a second naphtha stream; and

an outlet associated with a bottoms portion of the second divided wall column for recovery of a third naphtha stream;

feeding the first naphtha stream from the top portion of the second divided wall column to a deisopentanizer column;

feeding a bottoms fraction from the deisopentanizer column to an isomerization reactor;

feeding a product from the isomerization reactor to a stabilizer column;

feeding a first stabilized isomerate from the stabilizer column to a third divided wall column, the third divided wall column comprising;

a wall dividing a top portion of the third divided wall column into a first top section and a second top section;

an inlet coupled to an outlet of a stabilizer column of the isomerization unit;

an outlet associated with the second top section of the third divided wall column for recovery of a first isomerate stream; and

an outlet associated with a bottoms portion of the third divided wall column for recovery of a second isomerate stream;

feeding a second stabilized isomerate from the stabilizer column to the first top section of the first divided wall column; and

recovering isomerate from the third divided wall column.

11. The process of claim 10, further comprising exchanging heat between a fluid from the second top section of the third divided wall column and a bottoms product of the deisopentanizer column.

12. The process of claim 10, further comprising feeding a C5-containing stream from the first top section of the third divided wall column to the deisopentanizer column.

13. The process of claim 10, further comprising feeding a C6-containing stream from the third divided wall column to the isomerization reactor.

14. The process of claim 10, further comprising feeding a bottoms product of the first divided wall column to the first top section of the first divided wall column.

15. The process of claim 10, wherein the second divided wall column is heat integrated with the deisopentanizer column.

16. The process of claim 10, wherein the first divided wall column further comprises an inlet associated with the first top section of the first divided wall column and coupled to the bottoms portion of the first divided wall column.

17. The process of claim 10, wherein the second divided wall column further comprises an outlet associated with the top of the second divided wall column that is coupled to the deisopentanizer column.

18. The process of claim 10, wherein the first top section of the first divided wall column is configured to perform as a stabilizer and the second top section of the first divided wall column is configured to perform as deethanizer.

19. The process of claim 10, wherein the first top section of the third divided wall column is configured to perform as a depentanizer and the second top section of the third divided wall column is configured to perform as a deisohexanizer.