Intermediate film for laminated glass, laminated glass, and method of mounting laminated glass

• US 10,654,250 B2
• Filed: 07/31/2013
• Issued: 05/19/2020
• Est. Priority Date: 07/31/2012
• Status: Active Grant

• Current Assignee: Sekisui Chemical Company Limited (Sekisui)
• Original Assignee: Sekisui Chemical Company Limited (Sekisui)
• Inventors: Ohmoto, Izumi, Nakajima, Daisuke, Ii, Daizou, Fukatani, Juichi
• Primary Examiner(s): Khan, Tahseen
• Application Number:
  US14/418,931
• Publication Number:
  US 20150168619A1
• Time in Patent Office: 2,484 Days
• Field of Search: 359359
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10431 Specific parts for the modulation of light incorporated into the laminated safety glass or glazing
• CPC Class Codes: B32B 17/10633 Infrared radiation absorbing or reflecting agents
• CPC Class Codes: B32B 17/10651 comprising colorants, e.g. dyes or pigments
• CPC Class Codes: B32B 17/10678 comprising UV absorbers or stabilizers, e.g. antioxidants
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2419/00 Buildings or parts thereof
• CPC Class Codes: B32B 2605/00 Vehicles
• CPC Class Codes: B32B 2605/08 Cars
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: G02B 5/287 comprising at least one layer of organic material
• CPC Class Codes: Y10T 29/49826 Assembling or joining
• CPC Class Codes: Y10T 428/3163 Next to acetal of polymerized unsaturated alcohol [e.g., formal butyral, etc.]

Abstract

There is provided an interlayer film for laminated glass which is high in heat shielding properties. The intermediate film for laminated glass according to the present invention is provided with an infrared ray reflection layer which reflects infrared rays, a first resin layer which is arranged on a first surface side of the infrared ray reflection layer and contains a thermoplastic resin, and a second resin layer which is arranged on a second surface side of the infrared ray reflection layer and contains a thermoplastic resin; and the infrared ray transmittance in the wavelength of 780 to 2100 nm of the first resin layer is higher than the infrared ray transmittance in the wavelength of 780 to 2100 nm of the second resin layer.

Claims

1. An interlayer film for laminated glass, comprising an infrared ray reflection layer which reflects infrared rays, a first resin layer which is arranged on a first surface side of the infrared ray reflection layer and contains a thermoplastic resin and an ultraviolet ray shielding agent, a content of the ultraviolet ray shielding agent in 100% by weight of the first resin layer being 0.1% by weight or more, and a second resin layer which is arranged on a second surface side opposite to the first surface of the infrared ray reflection layer and contains a thermoplastic resin, an ultraviolet ray shielding agent and a heat shielding compound, the second resin layer containing both of metal-doped tungsten oxide particles and at least one compound among a phthalocyanine compound, a naphthalocyanine compound and an anthracyanine compound as the heat shielding compound, a content of the at least one compound in 100% by weight of the second resin layer being 0.1% by weight or less,

the first resin layer containing or not containing a heat shielding compound, a content in % by weight of the heat shielding compound in the first resin layer being smaller than a content in % by weight of the heat shielding compound in the second resin layer by 0.05% by weight or more, and

the infrared ray transmittance in the wavelength of 780 to 2100 nm of the first resin layer being higher than the infrared ray transmittance in the wavelength of 780 to 2100 nm of the second resin layer.

2. The interlayer film for laminated glass according to claim 1, wherein the infrared ray reflection layer is a resin film with metal foil, a multilayer laminated film in which a metal layer and a dielectric layer are formed on a resin layer, a multilayer resin film or a liquid crystal film.

3. The interlayer film for laminated glass according to claim 1, wherein the thermoplastic resin in the first resin layer is a polyvinyl acetal resin and the thermoplastic resin in the second resin layer is a polyvinyl acetal resin.

4. The interlayer film for laminated glass according to claim 1, wherein the first resin layer contains a plasticizer and the second resin layer contains a plasticizer.

5. A laminated glass, comprising a first laminated glass member, a second laminated glass member and an interlayer film arranged between the first laminated glass member and the second laminated glass member, the interlayer film being an interlayer film for laminated glass according to claim 1, the first laminated glass member being arranged on the outside of the first resin layer in the interlayer film for laminated glass, and the second laminated glass member being arranged on the outside of the second resin layer in the interlayer film for laminated glass.

6. The laminated glass according to claim 5, wherein the infrared ray transmittance in the wavelength of 780 to 2100 nm of the first laminated glass member is higher than the infrared ray transmittance in the wavelength of 780 to 2100 nm of the second laminated glass member.

7. A method of mounting laminated glass according to claim 5 for a building or a vehicle on an opening part between an outer space and an inner space into which heat rays are made incident from the outer space, comprising the step of mounting the laminated glass on the opening part so that the first laminated glass member is positioned at the outer space side and the second laminated glass member is positioned at the inner space side.

8. The interlayer film for laminated glass according to claim 1, wherein the first resin layer contains an oxidation inhibitor.

9. The interlayer film for laminated glass according to claim 1, wherein the second resin layer contains an oxidation inhibitor.

10. The interlayer film for laminated glass according to claim 1, wherein each ultraviolet ray shielding agent is a benzotriazole compound, a benzophenone compound, a triazine compound, a malonic acid ester compound, an oxalic anilide compound, or a benzoate compound.

11. The interlayer film for laminated glass according to claim 1, wherein the content of the ultraviolet ray shielding agent in 100% by weight of the first resin layer is 0.1% by weight or more and 0.8% by weight or less.

12. The interlayer film for laminated glass according to claim 1, wherein a content of the ultraviolet ray shielding agent in 100% by weight of the second resin layer is 0.1% by weight or more.

13. The interlayer film for laminated glass according to claim 1, wherein a content of the ultraviolet ray shielding agent in 100% by weight of the second resin layer is 0.1% by weight or more and 0.8% by weight or less.

14. The interlayer film for laminated glass according to claim 8, wherein

the oxidation inhibitor comprises at least one of a sulfur-based oxidation inhibitor and a phosphorus-based oxidation inhibitor.

15. The interlayer film for laminated glass according to claim 9, wherein

the oxidation inhibitor comprises at least one of a sulfur-based oxidation inhibitor and a phosphorus-based oxidation inhibitor.

16. The interlayer film for laminated glass according to claim 1, wherein

the at least one compound among a phthalocyanine compound, a naphthalocyanine compound and an anthracyanine compound has a structural unit in which an oxygen atom is bonded to a vanadium atom.

17. The interlayer film for laminated glass according to claim 1, wherein

the first resin layer further contains at least one compound among a phthalocyanine compound, a naphthalocyanine compound and an anthracyanine compound as the heat shielding compound, and

a content in % by weight of the at least one compound among a phthalocyanine compound, a naphthalocyanine compound and an anthracyanine compound in the first resin layer is less than the content in % by weight of the at least one compound among a phthalocyanine compound, a naphthalocyanine compound and an anthracyanine compound in the second resin layer.