Vehicular exterior electrically variable reflectance mirror reflective element assembly

• US 10,661,716 B2
• Filed: 07/29/2019
• Issued: 05/26/2020
• Est. Priority Date: 09/20/2002
• Status: Expired due to Term

• Current Assignee: Donnelly Corporation (Magna International Incorporated)
• Original Assignee: Donnelly Corporation (Magna International Incorporated)
• Inventors: McCabe, Ian A., Varaprasad, Desaraju V., Habibi, Hamid, Lynam, Niall R.
• Primary Examiner(s): Alexander, William R
• Assistant Examiner(s): Broome, Sharrief I
• Application Number:
  US16/524,290
• Publication Number:
  US 20190351828A1
• Time in Patent Office: 302 Days
• CPC Class Codes: B60Q 1/2665 on rear-view mirrors lighting devices for vehicle interior on or for rear-view mirrors B60Q3/258
• CPC Class Codes: B60Q 1/34 for indicating change of drive direction B60Q1/22 takes precedence
• CPC Class Codes: B60Q 2400/40 Welcome lights, i.e. specific or existing exterior lamps to assist leaving or approaching the vehicle
• CPC Class Codes: B60R 1/04 mounted inside vehicle B60R1/025, B60R1/08 take precedence
• CPC Class Codes: B60R 1/06 mounted on vehicle exterior B60R1/025, B60R1/08 take precedence
• CPC Class Codes: B60R 1/088 using a cell of electrically changeable optical characteristic, e.g. liquid-crystal or electrochromic mirrors
• CPC Class Codes: B60R 1/1207 with lamps; with turn indicators
• CPC Class Codes: F21S 43/14 Light emitting diodes [LED]
• CPC Class Codes: F21Y 2103/10 comprising a linear array of point-like light-generating elements
• CPC Class Codes: F21Y 2115/10 Light-emitting diodes [LED]
• CPC Class Codes: G02B 5/0875 the reflecting layers comprising two or more metallic layers
• CPC Class Codes: G02B 5/10 with curved faces
• CPC Class Codes: G02F 1/155 Electrodes
• CPC Class Codes: G02F 1/157 Structural association of cells with optical devices, e.g. reflectors or illuminating devices
• CPC Class Codes: G02F 1/161 Gaskets; Spacers; Sealing of cells; Filling or closing of cells
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor

Abstract

An electrically variable reflectance mirror reflective element includes front and rear glass substrates with an electrochromic medium disposed therebetween and bounded by a perimeter seal. A perimeter layer is disposed at a second surface of the front substrate proximate a perimeter edge of the front substrate. The perimeter layer conceals the perimeter seal from view by a driver of a vehicle. No part of the rear substrate extends beyond any part of the front substrate. At least a portion of the mirror reflector disposed at at least a portion of the third surface of the rear substrate extends from under the perimeter seal outward towards at least a portion of the perimeter edge of the rear substrate. The mirror reflector includes a stack of thin films that includes at least a first metal thin film and a second metal thin film.

Claims

1. An exterior electrically variable reflectance mirror reflective element assembly suitable for use for a vehicle, said exterior electrically variable reflectance mirror reflective element assembly comprising:

an electrically variable reflectance mirror reflective element;

wherein said electrically variable reflectance mirror reflective element comprises a front glass substrate and a rear glass substrate and an electrochromic medium disposed between said front and rear glass substrates;

wherein said front glass substrate has a first surface and a second surface and wherein a transparent electrically conductive layer is disposed at said second surface of said front glass substrate;

wherein said rear glass substrate has a third surface and a fourth surface and wherein a mirror reflector is disposed at at least a portion of said third surface of said rear glass substrate;

wherein said mirror reflector comprises a stack of thin films and wherein said stack of thin films comprises at least a first metal thin film and a second metal thin film;

wherein said first metal thin film is formed of a first metal material and said second metal thin film is formed of a second metal material;

wherein said first metal material of said first metal thin film is different than said second metal material of said second metal thin film;

wherein said mirror reflector provides at least 55 percent photopic reflectance measured in accordance with Society of Automotive Engineers test procedure SAE J964a;

wherein said electrochromic medium is disposed in an interpane cavity between said third surface of said rear glass substrate and said second surface of said front glass substrate and is bounded by a perimeter seal;

wherein width of said perimeter seal is at least 0.5 mm;

wherein no part of said rear glass substrate extends beyond any part of said front glass substrate;

wherein at least a perimeter edge portion of said rear glass substrate is inward of a corresponding perimeter edge portion of said front glass substrate by at least 0.1 mm;

wherein a perimeter layer is disposed at said second surface of said front glass substrate proximate a perimeter edge of said front glass substrate, and wherein said perimeter layer comprises a reflective perimeter layer;

wherein said perimeter layer comprises at least one metal thin film and wherein said perimeter layer is electrically conductive;

wherein said perimeter layer conceals said perimeter seal from view by a driver of a vehicle normally viewing said front glass substrate when said exterior electrically variable reflectance mirror reflective element assembly is mounted in an exterior mirror assembly attached at an exterior portion of the vehicle;

wherein at least a portion of said mirror reflector extends from under said perimeter seal outward towards at least a portion of said perimeter edge of said rear glass substrate;

wherein light that reflects off of said mirror reflector and passes through said electrochromic medium and said front glass substrate has an untinted reflectant characteristic to a viewer normally viewing said front glass substrate of said electrically variable reflectance mirror reflective element when no voltage is applied to said electrochromic medium; and

wherein said rear glass substrate has a thickness of 0.063 inches or less.

2. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein said mirror reflector has a sheet resistance of no greater than 5 ohms per square.

3. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein said first metal thin film has a thickness of at least 600 angstroms.

4. The exterior electrically variable reflectance mirror reflective element assembly of claim 3, wherein said first metal material of said first metal thin film has a specific resistivity of less than 1×

10−

3 ohm·

cm, and wherein said second metal material of said second metal thin film has a specific resistivity of less than 1×

10−

3 ohm·

cm.

5. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein width of said perimeter seal is not greater than 2 mm.

6. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein width of said perimeter seal is not greater than 3 mm.

7. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein said exterior electrically variable reflectance mirror reflective element assembly comprises a driver-side exterior electrically variable reflectance mirror reflective element assembly suitable for use in a driver-side exterior mirror assembly attached at a driver-side exterior portion of a vehicle.

8. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein said perimeter seal is at least partially visible to a viewer viewing through said rear glass substrate.

9. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein electrically conductive epoxy is in electrical contact with at least one selected from the group consisting of (i) said perimeter layer disposed at said second surface of said front glass substrate and (ii) said transparent electrically conductive layer disposed at said second surface of said front glass substrate.

10. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein electrically conductive epoxy is in electrical contact with said at least a portion of said mirror reflector that extends from under said perimeter seal outward towards said at least a portion of said perimeter edge of said rear glass substrate.

11. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein the at least a perimeter edge portion of said rear glass substrate is inward of the corresponding perimeter edge portion of said front glass substrate by no greater than 2 mm.

12. The exterior electrically variable reflectance mirror reflective element assembly of claim 1, wherein said exterior electrically variable reflectance mirror reflective element assembly comprises a light source, and wherein said light source comprises a light source of an indicator, and wherein said indicator is disposed rearward of said electrically variable reflectance mirror reflective element and, when actuated, illuminates through said electrically variable reflectance mirror reflective element.

13. An exterior electrically variable reflectance mirror reflective element assembly suitable for use for a vehicle, said exterior electrically variable reflectance mirror reflective element assembly comprising:

an electrically variable reflectance mirror reflective element;

wherein said electrically variable reflectance mirror reflective element comprises a front glass substrate and a rear glass substrate and an electrochromic medium disposed between said front and rear glass substrates;

wherein said front glass substrate has a first surface and a second surface and wherein a transparent electrically conductive layer is disposed at said second surface of said front glass substrate;

wherein said rear glass substrate has a third surface and a fourth surface and wherein a mirror reflector is disposed at at least a portion of said third surface of said rear glass substrate;

wherein said mirror reflector comprises a stack of thin films and wherein said stack of thin films comprises at least a first metal thin film and a second metal thin film;

wherein said first metal thin film is formed of a first metal material and said second metal thin film is formed of a second metal material;

wherein said first metal material of said first metal thin film is different than said second metal material of said second metal thin film;

wherein said mirror reflector provides at least 55 percent photopic reflectance measured in accordance with Society of Automotive Engineers test procedure SAE J964a;

wherein said electrochromic medium is disposed in an interpane cavity between said third surface of said rear glass substrate and said second surface of said front glass substrate and is bounded by a perimeter seal;

wherein width of said perimeter seal is at least 0.5 mm and wherein width of said perimeter seal is not greater than 3 mm;

wherein no part of said rear glass substrate extends beyond any part of said front glass substrate;

wherein at least a perimeter edge portion of said rear glass substrate is inward of a corresponding perimeter edge portion of said front glass substrate by at least 0.1 mm;

wherein the at least a perimeter edge portion of said rear glass substrate is inward of the corresponding perimeter edge portion of said front glass substrate by no greater than 2 mm;

wherein a perimeter layer is disposed at said second surface of said front glass substrate proximate a perimeter edge of said front glass substrate, and wherein said perimeter layer comprises a reflective perimeter layer;

wherein said perimeter layer comprises at least one metal thin film and wherein said perimeter layer is electrically conductive;

wherein said perimeter layer conceals said perimeter seal from view by a driver of a vehicle normally viewing said front glass substrate when said exterior electrically variable reflectance mirror reflective element assembly is mounted in an exterior mirror assembly attached at an exterior portion of the vehicle;

wherein at least a portion of said mirror reflector extends from under said perimeter seal outward towards at least a portion of said perimeter edge of said rear glass substrate; and

wherein light that reflects off of said mirror reflector and passes through said electrochromic medium and said front glass substrate has an untinted reflectant characteristic to a viewer normally viewing said front glass substrate of said electrically variable reflectance mirror reflective element when no voltage is applied to said electrochromic medium.

14. The exterior electrically variable reflectance mirror reflective element assembly of claim 13, wherein said first metal thin film has a thickness of at least 600 angstroms.

15. The exterior electrically variable reflectance mirror reflective element assembly of claim 14, wherein said mirror reflector has a sheet resistance of no greater than 5 ohms per square.

16. The exterior electrically variable reflectance mirror reflective element assembly of claim 15, wherein said first metal material of said first metal thin film has a specific resistivity of less than 1×

10−

3 ohm·

cm, and wherein said second metal material of said second metal thin film has a specific resistivity of less than 1×

10−

3 ohm·

cm.

17. The exterior electrically variable reflectance mirror reflective element assembly of claim 16, wherein width of said perimeter seal is not greater than 2 mm.

18. The exterior electrically variable reflectance mirror reflective element assembly of claim 16, wherein said exterior electrically variable reflectance mirror reflective element assembly comprises a driver-side exterior electrically variable reflectance mirror reflective element assembly suitable for use in a driver-side exterior mirror assembly attached at a driver-side exterior portion of a vehicle.

19. The exterior electrically variable reflectance mirror reflective element assembly of claim 18, wherein said perimeter seal is at least partially visible to a viewer viewing through said rear glass substrate.

20. The exterior electrically variable reflectance mirror reflective element assembly of claim 16, wherein electrically conductive epoxy is in electrical contact with at least one selected from the group consisting of (i) said perimeter layer disposed at said second surface of said front glass substrate and (ii) said transparent electrically conductive layer disposed at said second surface of said front glass substrate.

21. The exterior electrically variable reflectance mirror reflective element assembly of claim 13, wherein electrically conductive epoxy is in electrical contact with said at least a portion of said mirror reflector that extends from under said perimeter seal outward towards said at least a portion of said perimeter edge of said rear glass substrate.

22. The exterior electrically variable reflectance mirror reflective element assembly of claim 21, wherein said exterior electrically variable reflectance mirror reflective element assembly comprises a light source, and wherein said light source comprises a light source of an indicator, and wherein said indicator is disposed rearward of said electrically variable reflectance mirror reflective element and, when actuated, illuminates through said electrically variable reflectance mirror reflective element.

23. An exterior electrically variable reflectance mirror reflective element assembly suitable for use for a vehicle, said exterior electrically variable reflectance mirror reflective element assembly comprising:

an electrically variable reflectance mirror reflective element;

wherein said electrically variable reflectance mirror reflective element comprises a front glass substrate and a rear glass substrate and an electrochromic medium disposed between said front and rear glass substrates;

wherein said front glass substrate has a first surface and a second surface and wherein a transparent electrically conductive layer is disposed at said second surface of said front glass substrate;

wherein said rear glass substrate has a third surface and a fourth surface and wherein a mirror reflector is disposed at at least a portion of said third surface of said rear glass substrate;

wherein said mirror reflector comprises a stack of thin films and wherein said stack of thin films comprises at least a first metal thin film and a second metal thin film;

wherein said first metal thin film is formed of a first metal material and said second metal thin film is formed of a second metal material;

wherein said first metal material of said first metal thin film is different than said second metal material of said second metal thin film;

wherein said mirror reflector provides at least 55 percent photopic reflectance measured in accordance with Society of Automotive Engineers test procedure SAE J964a;

wherein said electrochromic medium is disposed in an interpane cavity between said third surface of said rear glass substrate and said second surface of said front glass substrate and is bounded by a perimeter seal;

wherein width of said perimeter seal is at least 0.5 mm and wherein width of said perimeter seal is not greater than 3 mm;

wherein no part of said rear glass substrate extends beyond any part of said front glass substrate;

wherein at least a perimeter edge portion of said rear glass substrate is inward of a corresponding perimeter edge portion of said front glass substrate by at least 0.1 mm;

wherein the at least a perimeter edge portion of said rear glass substrate is inward of the corresponding perimeter edge portion of said front glass substrate by no greater than 2 mm;

wherein a perimeter layer is disposed at said second surface of said front glass substrate proximate a perimeter edge of said front glass substrate, and wherein said perimeter layer comprises a reflective perimeter layer;

wherein said perimeter layer comprises at least one metal thin film and wherein said perimeter layer is electrically conductive;

wherein said perimeter layer conceals said perimeter seal from view by a driver of a vehicle normally viewing said front glass substrate when said exterior electrically variable reflectance mirror reflective element assembly is mounted in an exterior mirror assembly attached at an exterior portion of the vehicle;

wherein at least a portion of said mirror reflector extends from under said perimeter seal outward towards at least a portion of said perimeter edge of said rear glass substrate;

wherein light that reflects off of said mirror reflector and passes through said electrochromic medium and said front glass substrate has an untinted reflectant characteristic to a viewer normally viewing said front glass substrate of said electrically variable reflectance mirror reflective element when no voltage is applied to said electrochromic medium; and

wherein electrically conductive epoxy is in electrical contact with said at least a portion of said mirror reflector that extends from under said perimeter seal outward towards said at least a portion of said perimeter edge of said rear glass substrate.

24. The exterior electrically variable reflectance mirror reflective element assembly of claim 23, wherein said perimeter seal is at least partially visible to a viewer viewing through said rear glass substrate.

25. The exterior electrically variable reflectance mirror reflective element assembly of claim 24, wherein said rear glass substrate has a thickness of 0.063 inches or less.

26. The exterior electrically variable reflectance mirror reflective element assembly of claim 25, wherein said front glass substrate has a thickness of 0.063 inches or less.

27. The exterior electrically variable reflectance mirror reflective element assembly of claim 26, wherein said exterior electrically variable reflectance mirror reflective element assembly comprises a driver-side exterior electrically variable reflectance mirror reflective element assembly suitable for use in a driver-side exterior mirror assembly attached at a driver-side exterior portion of a vehicle.

28. The exterior electrically variable reflectance mirror reflective element assembly of claim 27, wherein said first metal thin film has a thickness of at least 600 angstroms.

29. The exterior electrically variable reflectance mirror reflective element assembly of claim 27, wherein said mirror reflector has a sheet resistance of no greater than 5 ohms per square.

30. The exterior electrically variable reflectance mirror reflective element assembly of claim 27, wherein said first metal material of said first metal thin film has a specific resistivity of less than 1×

10−

3 ohm·

cm, and wherein said second metal material of said second metal thin film has a specific resistivity of less than 1×

10−

3 ohm·

cm.

31. The exterior electrically variable reflectance mirror reflective element assembly of claim 27, wherein width of said perimeter seal is not greater than 2 mm.

32. The exterior electrically variable reflectance mirror reflective element assembly of claim 23, wherein electrically conductive epoxy is in electrical contact with said perimeter layer disposed at said second surface of said front glass substrate.

33. The exterior electrically variable reflectance mirror reflective element assembly of claim 23, wherein electrically conductive epoxy is in electrical contact with said transparent electrically conductive layer disposed at said second surface of said front glass substrate.