Process for obtaining superhydrophobic or superhydrophilic surfaces

• US 10,668,501 B2
• Filed: 05/20/2015
• Issued: 06/02/2020
• Est. Priority Date: 05/20/2014
• Status: Active Grant

• Current Assignee: Centre National De La Recherche Scientifique, Surfactis Technologies
• Original Assignee: Centre National De La Recherche Scientifique
• Inventors: Portet, David, Lefevre, Nicolas, Bejanin, Stephane, Taleb, Abdelhafed, Ben Jazia Dallel, Dorra, Favrat, Olivier
• Primary Examiner(s): Baldwin, Gordon
• Assistant Examiner(s): Mayy, Mohammad
• Application Number:
  US15/311,938
• Publication Number:
  US 20170120294A1
• Time in Patent Office: 1,840 Days
• CPC Class Codes: B05D 1/005 Spin coating
• CPC Class Codes: B05D 1/12 Applying particulate materials B05D1/06, B05D1/10 take precedence
• CPC Class Codes: B05D 1/18 performed by dipping
• CPC Class Codes: B05D 1/28 performed by transfer from the surfaces of elements carrying the liquid or other fluent material, e.g. brushes, pads, rollers
• CPC Class Codes: B05D 1/30 performed by gravity only, i.e. flow coating
• CPC Class Codes: B05D 1/36 Successively applying liquids or other fluent materials, e.g. without intermediate treatment
• CPC Class Codes: B05D 2201/00 Polymeric substrate or laminate
• CPC Class Codes: B05D 2203/35 Glass
• CPC Class Codes: B05D 3/0446 of a polymeric substrate
• CPC Class Codes: B05D 3/063 of polymeric substrates B05D3/064 takes precedence
• CPC Class Codes: B05D 3/108 Curing
• CPC Class Codes: B05D 3/144 of polymeric substrates
• CPC Class Codes: B05D 5/08 to obtain an anti-friction or anti-adhesive surface rendering particulate materials free-flowing in general, e.g. making them hydrophobic B01J2/30
• CPC Class Codes: B05D 5/083 involving the use of fluoropolymers

Abstract

The present invention relates to a process for texturing surfaces providing the latter with superhydrophobic, superoleophobic, superhydrophilic or even superoleophilic properties. This process comprises i) a step of texturing the surface (via the deposition of nanoparticles of different sizes); ii) a step of curing the surface thus textured (with a curing agent); and, optionally, iii) a step of modifying the properties of the surface with perfluorinated (and therefore hydrophobic) molecules. This process is suitable, inter alia, for treating transparent and/or heat-sensitive materials and surfaces. Specifically, none of the steps of the process use a temperature higher than 100° C. Thus, the process of the invention is particularly suitable for treating transparent surfaces composed of non-mineral materials, such as polycarbonate for example, as it will affect neither their transparency nor their optical properties.

Claims

1. A process for coating surfaces without the use of heat comprising:

a) depositing at least two nanoparticle populations, of different sizes, on a surface to be treated, and

b) Cross-linking the nanoparticle-coated surface using an acidic hydroalcoholic solution containing TEOS as the only cross-linking agent on the surface to be treated to form a cross-linked surface,

wherein heat is not applied to the surface to be treated.

2. The process according to claim 1, wherein said nanoparticle populations are mixed with said cross-linking agent before being deposited on said surface.

3. The process according to claim 1, wherein said nanoparticle populations are deposited successively on said surface.

4. The process according to claim 1, wherein said surface is treated with the cross-linking agent after each deposition of nanoparticles.

5. The process according to claim 1, wherein step a) contains the following sub-steps:

a1) Treating the first nanoparticle population with an adhesion agent,

a2) Contacting said first nanoparticle population with one or more other nanoparticle populations,

a3) Optionally, purifying the particles thus formed,

a4) Depositing the particles formed in steps a2) or a3) on said surface.

6. The process according to claim 5, wherein said adhesion agent is an isocyanate or epoxide compound.

7. The process according to claim 1, wherein said surface is treated with the cross-linking agent after all of said nanoparticles have been deposited.

8. The process according to claim 5, wherein the nanoparticles formed in steps a2) or a3) are mixed with said cross-linking agent before step a4).

9. The process according to claim 1, wherein said surface consists of silicon, aluminum, germanium, oxides thereof or alloys thereof, or of polycarbonate, polymethyl methacrylate (PMMA), polypropylene, polyvinyl acetate (PVA), polyamides (PA), polyethylene terephthalate (PET), polyvinyl alcohols (PVA1), polystyrenes (PS), polyvinyl chlorides (PVC) or polyacrylonitriles (PAN).

10. The process according to claim 1, wherein one of the two nanoparticle populations has a diameter comprised between 50 and 200 nm, and the other a diameter comprised between 5 and 50 nm.

11. The process according to claim 1, wherein said nanoparticles consist of silicon, germanium, alumina, titanium, oxides thereof or alloys thereof, or polycarbonate.

12. The process according to claim 1 further comprising

c) coating the cross-linked surface with a layer of hydrophobic organic molecules.

13. The process according to claim 12, wherein said organic molecules are perfluorinated.

14. The process according to claim 12, wherein said organic molecules are of formula:

15. The process of claim 1, wherein the deposition of the nanoparticles on the surface to be treated is carried out by a method selected from the group consisting of:

dip-coating, spin-coating, spray, flow-coating, and wiping.

16. A process for coating surfaces comprising:

a) depositing at least two nanoparticle populations, of different sizes, on a surface to be treated, and

b) cross-linking the nanoparticle-coated surface using an acidic hydroalcoholic solution containing TEOS as the only cross-linking agent,

wherein the process does not involve heating the surface to be treated and the nanoparticles are not coated with a compound selected from the group consisting of;

amine, cationic polymers, and combinations thereof.

17. The process of claim 16, wherein the deposition of the nanoparticles on the surface to be treated is carried out by a method selected from the group consisting of:

dip-coating, spin-coating, spray, flow-coating, and wiping.