Radially stacked solar cells based on 2D atomic crystals and methods for their production

• US 10,680,129 B1
• Filed: 10/05/2018
• Issued: 06/09/2020
• Est. Priority Date: 10/17/2016
• Status: Active Grant

• Current Assignee: UNM Rainforest Innovations (f/k/a STC.UNM) (The University of New Mexico)
• Original Assignee: UNM Rainforest Innovations (f/k/a STC.UNM) (The University of New Mexico)
• Inventors: Cavallo, Francesca, Mangu, Vijay Saradhi
• Primary Examiner(s): Leong, Susan D
• Application Number:
  US16/153,277
• Time in Patent Office: 613 Days
• CPC Class Codes: H01L 31/022425 for solar cells
• CPC Class Codes: H01L 31/02363 of the semiconductor body itself, e.g. textured active layers
• CPC Class Codes: H01L 31/032 including, apart from doping materials or other impurities, only compounds not provided for in groups H01L31/0272 - H01L31/0312
• CPC Class Codes: H01L 31/035281 Shape of the body
• CPC Class Codes: H01L 31/0392 including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate textured substrates H01L31/02366
• CPC Class Codes: H01L 31/0547 comprising light concentrating means of the reflecting type, e.g. parabolic mirrors, concentrators using total internal reflection
• CPC Class Codes: H01L 31/072 the potential barriers being only of the PN heterojunction type
• CPC Class Codes: H01L 31/0725 Multiple junction or tandem solar cells
• CPC Class Codes: H01L 31/1892 methods involving the use of temporary, removable substrates
• CPC Class Codes: Y02E 10/52 PV systems with concentrators

Abstract

A solar cell for collecting solar radiation can include a barrier layer such as a dielectric barrier layer and a heterostructure including a first light absorbing layer and at least a second light absorbing layer. A method for forming the solar cell can include forming a sacrificial layer on a support substrate and forming the barrier layer on the sacrificial layer. The barrier layer is formed to have a strain gradient through its thickness. The heterostructure is attached to the barrier layer and the sacrificial layer is removed, thereby separating the barrier layer and the heterostructure from the support substrate. During the removal of the sacrificial layer, the strain gradient causes the barrier layer and heterostructure, to roll, curl, or spiral, thereby resulting in a radially stacked heterostructure that provides a light concentrating optical cavity having multiple light absorbing layers with different band gaps.

Claims

1. A solar cell, comprising:

a barrier layer;

a plurality of nanospheres positioned on the barrier layer, wherein the plurality of nanospheres comprise silicon dioxide;

a heterostructure wherein;

the heterostructure comprises a first light absorbing layer and at least a second light absorbing layer attached to the first light absorbing layer; and

the plurality of nanospheres are positioned between the barrier layer and the heterostructure; and

a heterojunction at an interface between the first light absorbing layer and the second light absorbing layer,

wherein the barrier layer, the first light absorbing layer, and the second light absorbing layer form a spiral structure having a spiral shape.

2. The solar cell of claim 1, wherein:

the first light absorbing layer is a first transition metal dichalcogenide (TMDC) layer having a band gap;

the second light absorbing layer is a second TMDC layer having a band gap; and

the first TMDC layer is a different material having a different band gap than the second TMDC layer.

3. The solar cell of claim 1, wherein the spiral structure comprises at least five windings.

4. The solar cell of claim 1, further comprising:

a first electrical contact that electrically contacts the first light absorbing layer; and

a second electrical contact that electrically contacts the second light absorbing layer.

5. The solar cell of claim 1, further comprising a reflective core attached to the second light absorbing layer, wherein the reflective core is positioned at a center of the spiral structure.

6. The solar cell of claim 5, wherein the reflective core comprises one or more of gold, aluminum, and silver, and has a diameter of from 0.5 micrometer (μ

m) to 2.0 μ

m.

7. The solar cell of claim 6, wherein the reflective core is attached to a first end of the second light absorbing layer, and the solar cell further comprises:

a first electrical contact that electrically contacts the first light absorbing layer; and

a second electrical contact that electrically contacts the second light absorbing layer, wherein the second electrical contact is formed at a second end of the second light absorbing layer that is opposite to the first end.

8. The solar cell of claim 1, wherein the first light absorbing layer is locally strained at each interface with each nanosphere.

9. The solar cell of claim 8, wherein the first light absorbing layer comprises at least one of molybdenum disulfide (MoS₂), molybdenum diselenide (MoSe₂), tungsten disulfide (WS₂), and tungsten diselenide (WSe₂).

10. The solar cell of claim 1, wherein the solar cell has a diameter of 500 nanometers, at least five windings, an absorption efficiency of at least 85%, and a conversion efficiency of at least 20%.

11. The solar cell of claim 1, wherein each nanosphere of the plurality of nanospheres has a diameter of from 10 nanometers (nm) to 100 nm.

12. The solar cell of claim 1, wherein the plurality of nanospheres are positioned on the barrier layer at a density of from 5 nanospheres per square micrometer to 10 nanospheres per square micrometer.

13. The solar cell of claim 1, wherein:

each nanosphere of the plurality of nanospheres has a diameter of from 10 nanometers (nm) to 100 nm;

the plurality of nanospheres are positioned on the barrier layer at a density of from 5 nanospheres per square micrometer to 10 nanospheres per square micrometer; and

the first light absorbing layer is locally strained at each interface with each nanosphere.