Core/shell filament for use with extrusion-based additive manufacturing system

• US 10,695,979 B2
• Filed: 08/28/2019
• Issued: 06/30/2020
• Est. Priority Date: 09/17/2010
• Status: Active Grant

• Current Assignee: Stratasys Incorporated
• Original Assignee: Stratasys Incorporated
• Inventors: Mikulak, James K., Deckard, Carl R., Zinniel, Robert L.
• Primary Examiner(s): O'Hern, Brent T
• Application Number:
  US16/554,173
• Publication Number:
  US 20190381728A1
• Time in Patent Office: 307 Days
• Field of Search: 428 98
• CPC Class Codes: B29C 2948/92704 Temperature
• CPC Class Codes: B29C 48/0021 combined with joining, lining or laminating
• CPC Class Codes: B29C 48/05 Filamentary, e.g. strands
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/154 Coating solid articles, i.e. non-hollow articles
• CPC Class Codes: B29C 48/16 Articles comprising two or more components, e.g. co-extruded layers
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/92 Measuring, controlling or regulating
• CPC Class Codes: B29C 64/118 using filamentary material being melted, e.g. fused deposition modelling [FDM]
• CPC Class Codes: B29C 64/188 involving additional operations performed on the added layers, e.g. smoothing, grinding or thickness control surface shaping B29C59/00; after-treatment of articles without altering their shape B29C71/00
• CPC Class Codes: B29C 64/40 Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
• CPC Class Codes: B32B 3/26 characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids foam layer B32B5/18; layer of synthetic resin characterised by fillers that create voids or cavities B32B27/205; characterised by an apertured layer
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 70/00 Materials specially adapted for additive manufacturing
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: D01F 8/04 from synthetic polymers
• CPC Class Codes: D01F 8/12 with at least one polyamide as constituent
• CPC Class Codes: Y10T 428/23 Sheet including cover or casing
• CPC Class Codes: Y10T 428/24612 Composite web or sheet
• CPC Class Codes: Y10T 428/2929 Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]

Abstract

A consumable filament for use in an extrusion-based additive manufacturing system, where the consumable filament comprises a core portion of a first thermoplastic material, and a shell portion of a second thermoplastic material that is compositionally different from the first thermoplastic material, where the consumable filament is configured to be melted and extruded to form roads of a plurality of solidified layers of a three-dimensional object, and where the roads at least partially retain cross-sectional profiles corresponding to the core portion and the shell portion of the consumable filament.

Claims

1. A consumable filament for use in an extrusion-based additive manufacturing system, the consumable filament comprising:

a core portion extending along a length of the consumable filament, the core portion compositionally comprising a first thermoplastic material; and

a shell portion extending along a longitudinal length of the consumable filament and at least partially encasing the core portion, the shell portion compositionally comprising a second thermoplastic material that is different from the first thermoplastic material, wherein the consumable filament is configured to be heated to a molten state and extruded to form roads of a 3D part.

2. The consumable filament of claim 1, wherein the core portion comprises a first semi-crystalline polymeric material having a first peak crystallization temperature, and wherein the shell portion comprises a second semi-crystalline polymeric material having a second peak crystallization temperature, the second peak crystallization temperature being greater than the first peak crystallization temperature.

3. The consumable filament of claim 2, wherein the second peak crystallization temperature is greater than the first peak crystallization temperature by at least about 5°

C.

4. The consumable filament of claim 2, wherein the core portion comprises a majority of a first semi-crystalline polymer and the shell portion comprises a majority of a second semi-crystalline polymer.

5. The consumable filament of claim 2, wherein a difference in melting points of the first semi-crystalline polymeric material of the core portion and the second semi-crystalline polymeric material of the shell portion is about 8°

C. or less.

6. The object of claim 2, wherein a difference in melting points of the first semi-crystalline polymeric material of the core portion and the second semi-crystalline polymeric material of the shell portion is about 3°

C. or less.

7. The consumable filament of claim 1, wherein the core portion and the shell portion each comprise polyamides, polyethylenes, polypropylenes, polyetheretherketones, polyetherarylketones, perfluoroalkoxys, polychlorotrifluoroethylenes, polyphenylene sulfides, fluorinated ethylene propylenes, polytetrafluoroethylenes, ethylene-tetrafluoroethylenes, polyvinylidene fluorides, and ethylene-chlorortifluoroethylenes, copolymers thereof, and combinations thereof.

8. The consumable filament of claim 7, wherein the polyamides comprise nylon 6, nylon 6-6, nylon 6-10, nylon 6-12, nylon 10, nylon 10-10, nylon 11, nylon 12, and combinations thereof.

9. The consumable filament of claim 7, wherein the polyethylenes include low-density polyethylene, medium-density polyethylene, high-density polyethylene, and combinations thereof.

10. The consumable filament of claim 7, wherein the polypropylenes include isotactic polypropylenes, syndiotactic polypropylenes, branched and linear variations thereof, and combinations thereof.

11. The consumable filament of claim 1, wherein the first thermoplastic material of the core portion and the second thermoplastic material of the shell portion comprise a same base polymer.

12. The consumable filament of claim 1, wherein the second thermoplastic material of the shell portion comprises a material that is at least partially soluble in an aqueous solution.

13. The consumable filament of claim 12, wherein the aqueous solution comprises an alkaline aqueous solution.

14. The consumable filament of claim 1, wherein average volume of the shell portion ranges from about 5% to about 75% of an average volume of the consumable filament.

15. The consumable filament of claim 1, wherein an average cross-sectional area of the consumable filament ranges from about 1 square millimeter to about 3 square millimeters.

16. A consumable filament for use in an extrusion-based additive manufacturing system, the consumable filament comprising:

a core portion extending along a length of the consumable filament, the core portion compositionally comprising a first thermoplastic material; and

a shell portion extending along a longitudinal length of the consumable filament and at least partially encasing the core portion, the shell portion compositionally comprising a second thermoplastic material that is compositionally different from the first thermoplastic material, and wherein the shell portion at least partially encases the core portion to provide an interface between the core portion and the shell portion wherein the first thermoplastic material and the second thermoplastic material are semi-crystalline materials having peak crystallization temperatures that have at least a 2°

C. or greater difference, wherein the consumable filament is configured to be heated to a molten state and extruded to form roads of a 3D part.

17. The consumable filament of claim 16, wherein the shell portion comprises a first semi-crystalline polymer and the core portion comprises the first semi-crystalline polymer and a crystallization inhibitor.

18. The consumable filament of claim 16, wherein the shell portion comprises a first semi-crystalline polymer and one or more nucleating agents and the core portion comprises the first semi-crystalline polymer.

19. The consumable filament of claim 16, wherein the core portion comprises a majority of a first semi-crystalline polymer and the shell portion comprises a majority of a second semi-crystalline polymer.

20. The consumable filament of claim 19, wherein a difference in melting points of the first semi-crystalline polymer and the second semi-crystalline polymer is about 8°

C. or less.

21. The consumable filament of claim 20, wherein a difference in melting points of the first semi-crystalline polymer and the second semi-crystalline polymer is about 3°

C. or less.

22. The consumable filament of claim 16, wherein the core portion and the shell portion each comprise polyamides, polyethylenes, polypropylenes, polyetheretherketones, polyetherarylketones, perfluoroalkoxys, polychlorotrifluoroethylenes, polyphenylene sulfides, fluorinated ethylene propylenes, polytetrafluoroethylenes, ethylene-tetrafluoroethylenes, polyvinylidene fluorides, and ethylene-chlorortifluoroethylenes, copolymers thereof, and combinations thereof.

23. The consumable filament of claim 22, wherein the polyamides comprise nylon 6, nylon 6-6, nylon 6-10, nylon 6-12, nylon 10, nylon 10-10, nylon 11, nylon 12, and combinations thereof.

24. The consumable filament of claim 22, wherein the polyethylenes include low-density polyethylene, medium-density polyethylene, high-density polyethylene, and combinations thereof.

25. The consumable filament of claim 22, wherein the polypropylenes include isotactic polypropylenes, syndiotactic polypropylenes, branched and linear variations thereof, and combinations thereof.

26. The consumable filament of claim 16, wherein the second thermoplastic material of the shell portion comprises a material that is at least partially soluble in an aqueous solution.

27. The consumable filament of claim 26, wherein the aqueous solution comprises an alkaline aqueous solution.

28. The consumable filament of claim 16, wherein an average volume of the shell portion ranges from about 5% to about 75% of an average volume of the consumable filament.

29. The consumable filament of claim 16, wherein an average cross-sectional area of the consumable filament ranges from about 1 square millimeter to about 3 square millimeters.