Method and apparatus for three-dimensional fabrication

• US 10,710,305 B2
• Filed: 05/07/2018
• Issued: 07/14/2020
• Est. Priority Date: 02/12/2013
• Status: Active Grant

• Current Assignee: Carbon, Inc.
• Original Assignee: Carbon, Inc.
• Inventors: DeSimone, Joseph M., Ermoshkin, Alexander, Samulski, Edward T.
• Primary Examiner(s): Del Sole, Joseph S
• Assistant Examiner(s): Nguyen, Thu Khanh T
• Application Number:
  US15/972,729
• Publication Number:
  US 20190126547A1
• Time in Patent Office: 799 Days
• Field of Search: 4251744, 425375, 264308, 264401
• CPC Class Codes: B29C 64/124 using layers of liquid which are selectively solidified
• CPC Class Codes: B29C 64/129 characterised by the energy source therefor, e.g. by global irradiation combined with a mask
• CPC Class Codes: B29C 64/20 Apparatus for additive manufacturing; Details thereof or accessories therefor
• CPC Class Codes: B29C 64/264 Arrangements for irradiation
• CPC Class Codes: B29C 64/386 Data acquisition or data processing for additive manufacturing
• CPC Class Codes: B29C 64/40 Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof
• CPC Class Codes: B29K 2105/0058 Liquid or visquous
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 30/00 Apparatus for additive manufacturing; Details thereof or accessories therefor
• CPC Class Codes: B33Y 50/02 for controlling or regulating additive manufacturing processes

Abstract

The present invention relates to methods and an apparatus for the fabrication of solid three-dimensional objects from liquid polymerizable materials.

Claims

1. A method of forming a three-dimensional object, comprising the steps of:

(a) providing a carrier and a rigid stationary build plate, said build plate comprising a fixed semipermeable member, said semipermeable member comprising a build surface and a feed surface separate from said build surface, with said build surface and said carrier defining a build region therebetween, and with said feed surface in fluid contact with a polymerization inhibitor;

(b) filing said build region with a polymerizable liquid, said polymerizable liquid contacting said build segment,

(c) irradiating said build region through said build plate to produce a solid polymerized region in said build region, with a liquid film release layer comprised of said polymerizable liquid formed between said solid polymerized region and said build surface, the polymerization of which liquid film is inhibited by said polymerization inhibitor; and

(d) advancing said carrier with said polymerized region adhered thereto and said build plate away from one another solely in the Z (vertical) direction to create a subsequent build region between said polymerized region and said top zone, wherein;

said filling step is carried out by forcing said polymerizable liquid into said build region under pressure, and

said advancing step or steps is/are carried out at a cumulative rate of at least 0.1 to 1000 microns per second; and

/or

said pressure is sufficient to increase the rate of said advancing step(s) at least 2 times as compared to the maximum rate of repetition of said advancing steps in the absence of said pressure.

2. The method of claim 1, further comprising:

(e) continuing and/or repeating steps (b) through (d) to produce a subsequent polymerized region adhered to a previous polymerized region until the continued or repeated deposition of polymerized regions adhered to one another forms said three-dimensional object.

3. The method of claim 2, wherein steps (b) through (d) are carried out sequentially.

4. The method of claim 2, wherein steps (b) through (d) are carried out concurrently.

5. The method of claim 1, wherein said both said feed surface and said polymerizable liquid are in fluid contact with the same compressed gas, which compressed gas comprises from 20 to 95 percent by volume of oxygen, said oxygen serving as said polymerization inhibitor.

6. The method of claim 1, wherein said advancing step is carried out in uniform increments.

7. The method of claim 1, wherein said advancing step is carried out in variable increments.

8. The method of claim 1, wherein said advancing step is carried out by advancing said carrier vertically from said build surface.

9. The method of claim 1, wherein said build surface is flat and smooth.

10. The method of claim 1, wherein said build surface is curved, textured, or a combination thereof.

11. The method of claim 1, wherein:

said semipermeable member comprises a top surface portion, a bottom surface portion, and an edge surface portion;

said build surface is on said top surface portion; and

said feed surface is on at least one of said top surface portion, said bottom surface portion, and said edge surface portion.

12. The method of claim 1, wherein said semipermeable member has a thickness of from 0.1 millimeters to 100 millimeters.

13. The method of claim 1, wherein said semipermeable member has a permeability to oxygen of at least 10 Barrers.

14. The method of claim 1, wherein said irradiating step is carried out with actinic radiation.

15. The method of claim 1, wherein said polymerizable liquid comprises a polymerizable monomer.

16. The method of claim 15, wherein said polymerizable liquid further comprises an active agent, a detectable agent, solid particles, or a combination thereof.

17. The method of claim 1, wherein said three-dimensional object comprises an medical device.

18. The method of claim 1, wherein said three-dimensional object comprises a rod or fiber.

19. The method of claim 1, wherein said irradiating step is carried out with patterned irradiation.