Water insoluble alpha-(1,3-glucan) composition

• US 10,731,297 B2
• Filed: 10/24/2016
• Issued: 08/04/2020
• Est. Priority Date: 10/26/2015
• Status: Active Grant

• Current Assignee: Nutrition & Biosciences USA 4, Inc. (International Flavors & Fragrances Incorporated)
• Original Assignee: DuPont Industrial Biosciences USA, LLC (DuPont de Nemours, Inc.)
• Inventors: Behabtu, Natnael, Li, Xiaoqing, Wolfe, Michael Stephen
• Primary Examiner(s): Cohen, Stefanie J
• Application Number:
  US15/756,681
• Publication Number:
  US 20180258590A1
• Time in Patent Office: 1,380 Days
• Field of Search: None
• CPC Class Codes: C08B 37/0009 alpha-D-Glucans, e.g. polydextrose, alternan, glycogen; (alpha-1,4)(alpha-1,6)-D-Glucans; (alpha-1,3)(alpha-1,4)-D-Glucans, e.g. isolichenan or nigeran; (alpha-1,4)-D-Glucans; (alpha-1,3)-D-Glucans, e.g. pseudonigeran; Derivatives thereof
• CPC Class Codes: C08K 13/08 Ingredients of unknown constitution and ingredients covered by the main groups C08K3/00 - C08K9/00
• CPC Class Codes: C08L 5/00 Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
• CPC Class Codes: C09D 105/00 Coating compositions based on polysaccharides or on their derivatives, not provided for in groups C09D101/00 or C09D103/00
• CPC Class Codes: D06P 1/44 using insoluble pigments or auxiliary substances, e.g. binders
• CPC Class Codes: D06P 1/48 Derivatives of carbohydrates
• CPC Class Codes: D06P 5/30 Ink jet printing
• CPC Class Codes: D21H 19/36 Coatings with pigments D21H19/66 takes precedence; metal powder D21H19/06
• CPC Class Codes: D21H 19/52 Cellulose; Derivatives thereof
• CPC Class Codes: D21H 19/62 Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D21H 19/72 Coated paper characterised by the paper substrate
• CPC Class Codes: D21H 21/16 Sizing or water-repelling agents

Abstract

The disclosure relates to a coating composition that can be applied to a substrate, especially a cellulose substrate. A layer of the coating composition applied to the substrate provides an excellent ink receptive layer and can be used as a coating on paper. The disclosure also relates to aqueous compositions and method for applying the layer of the coating composition onto the substrate.

Claims

1. A substrate, wherein at least a portion of the substrate is coated with a layer of a coating composition, the coating composition comprising:

i) water insoluble α

-(1,3→

glucan) polymer having 90% or greater a-1,3-glycosidic linkages, less than 1% of α

-1,3,6-glycosidic branch points and a number average degree of polymerization in the range of 55 to 10,000; and

ii) at least one pigment, at least one binder, or a combination thereof wherein the layer of coating composition comprises an average pore volume in the range of 0.1 to 0.50 milliliters/gram as measured by mercury porosimetry.

2. The substrate of claim 1, wherein the substrate is a cellulose substrate, polymer, paper, textile, paperboard, cardboard, or corrugated board.

3. The substrate of claim 1, wherein the binder is polyvinyl alcohol, polyvinyl acetate, partially saponified polyvinyl acetate, silanol-modified polyvinyl alcohol, polyurethane, starch, corn dextrin, carboxy methyl cellulose, cellulose ether, hydroxyethyl cellulose, hydroxypropyl cellulose, ethylhydroxyethyl cellulose, methyl cellulose, alginate, sodium alginate, xanthan, carrageenan, casein, soy protein, guar gum, synthetic polymer, styrene butadiene latex, styrene acrylate latex, or a combination thereof.

4. The substrate of claim 1, wherein the coating composition comprises in the range of 0.1 to 50% by weight of the water insoluble α

-(1,3→

glucan) polymer, based on the total weight of the coating composition.

5. The substrate of claim 1, wherein the coating composition further comprises at least one additive.

6. The substrate of claim 1, wherein the water insoluble α

-(1,3→

glucan) polymer is a linear polymer having greater than or equal to 99% α

-1,3-glycosidic linkages and less than 1% α

-1,3,6-glycosidic branch points.

7. The substrate of claim 1, wherein the coating composition is free from starch or hydroxy alkyl starch.

8. The substrate of claim 5, wherein the additive is a dispersant, a quaternary ammonium salt, calcium chloride, a surfactant, a hardener, a flowability improver, a lubricant, an antifoam, a releasing agent, a foaming agent, a penetrant, an optical brightener, a preservative, a biocide, a yellowing inhibitor, an ultraviolet absorber, an antioxidant, an insolubiliser, an antistatic agent, a pH regulator, a water-resistance agent, a wet and/or dry strengthening agent, a cross-linking agent, a gloss-ink holdout additive, a grease and oil resistance additive, a leveling aid, or a combination thereof.

9. An aqueous coating composition comprising the coating composition of claim 1 and iii) an aqueous carrier.

10. The aqueous coating composition of claim 9, wherein the aqueous coating composition is free from water soluble polysaccharides.

11. The aqueous coating composition of claim 9, wherein the aqueous carrier comprises less than or equal to 60% by weight of the total weight of the aqueous coating composition.

12. The aqueous coating composition of claim 9, wherein the composition further comprises at least one additive.

13. The aqueous coating composition of claim 9, wherein the composition is free from starch or hydroxyalkyl starch.

14. The aqueous coating composition of claim 9, wherein the α

-(1,3→

glucan) polymer is a linear polymer having greater than or equal to 99% α

-1,3-glucosydic linkages and less than 1% α

-1,3,6-branching points.

15. The aqueous coating composition of claim 9, wherein the binder is polyvinyl alcohol, polyvinyl acetate, partially saponified polyvinyl acetate, silanol-modified polyvinyl alcohol, polyurethane, starch, corn dextrin, cellulose ether, hydroxyethyl cellulose, hydroxypropyl cellulose, ethylhydroxyethyl cellulose, methyl cellulose, alginate, sodium alginate, xanthan, carrageenan, guar gum, synthetic polymer, styrene butadiene latex, or a combination thereof.

16. The aqueous coating composition of claim 12, wherein the additive is a dispersant, a quaternary ammonium salt, calcium chloride, a surfactant, a hardener, a flowability improver, a lubricant, an antifoam, a releasing agent, a foaming agent, a penetrant, an optical brightener, a preservative, a biocide, a yellowing inhibitor, an ultraviolet absorber, an antioxidant, an insolubiliser, an antistatic agent, a pH regulator, a water-resistance agent, a wet and/or dry strengthening agent, a cross-linking agent, a gloss-ink holdout additive, a grease and oil resistance additive, a leveling aid, or a combination thereof.

17. A method of forming a layer of a coating composition on a substrate comprising:

1) applying an aqueous coating composition to at least a portion of a substrate, wherein the aqueous coating composition comprises;

i) water insoluble α

-(1,3→

glucan) polymer having 90% or greater a-1,3-glycosidic linkages, less than 1% α

-1,3,6-glycosidic branch points and a number average degree of polymerization in the range of 55 to 10,000

ii) a pigment, a binder, or a combination thereof;

iii) an aqueous carrier; and

2) removing at least a portion of the aqueous carrier from the applied layer of the aqueous coating composition to form the layer of the coating composition, wherein the layer of coating composition comprises an average pore volume in the range of 0.1 to 0.50 milliliters/gram as measured by mercury porosimetry.

18. The method of claim 17, wherein the substrate is paper or a polymer.

19. The method of claim 17, wherein applying the aqueous coating composition to at least a portion of the substrate is performed before or during a printing operation.