Cleaning methods and/or articles for hard surfaces

• US 20010014655A1
• Filed: 04/17/2001
• Published: 08/16/2001
• Est. Priority Date: 05/02/1997
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Kershner, Karen Marie, Moster, Heather Lynn, Rollins, David Kent, Roselle, Brian Joseph
• Granted Patent: US 6,302,969 B2
• Time in Patent Office: Days
• US Class Current: 510/180
• CPC Class Codes: C11D 1/146 Sulfuric acid esters
• CPC Class Codes: C11D 1/22 derived from aromatic compounds
• CPC Class Codes: C11D 11/0023 "Hard" surfaces
• CPC Class Codes: C11D 17/046 Insoluble free body dispenser
• CPC Class Codes: C11D 2111/14 Hard surfaces
• CPC Class Codes: C11D 3/201 linear
• CPC Class Codes: C11D 3/2044 linear
• CPC Class Codes: C11D 3/50 Perfumes

Abstract

Basic cleaning compositions using toxicologically-acceptable ingredients for cleaning hard surfaces are provided. Compositions safe for use on surfaces which are contacted by food intended for ingestion by humans or lower animals, even when the compositions are incompletely removed from the cleansed surface, are described. Liquid formulations comprising surfactant, such as sodium alkyl sulfate, sodium alkylbenzene sulfonate, etc., and having a pH of above 11.6 are contacted directly onto hard surfaces to remove soil and unwanted deposits. Articles for applying the compositions to hard surfaces by spraying are disclosed.

Claims

1. A method for cleaning hard surfaces comprising contacting said hard surfaces by direct application of an aqueous cleaning solution comprising:

(a) from about 0.001% to below about 0.5% of an anionic and/or nonionic surfactant;

(b) up to about 6% by weight of GRAS perfume;

(c) a toxicologically acceptable alkali compound;

(d) optionally, a toxicologically acceptable sequestrant/builder;

(e) optionally, a toxicologically-acceptable preservative; and

(f) the balance comprising aqueous carrier selected from water and, optionally, low molecular weight, toxicologically-acceptable organic solvent;

said aqueous cleaning solution having a pH of greater than 11.6;

wherein said aqueous cleaning solution is essentially free of C₈-C₁₈ fatty acid or salts thereof; and

wherein said aqueous cleaning solution comprises only food grade ingredients.

2. The method of

claim 1

wherein said aqueous cleaning solution has a pH of more than about 12.

3. The method of

claim 2

wherein said aqueous carrier comprises water and from about 0.05% to about 10%, by weight of the total composition, of organic solvent selected from the group consisting of ethanol, glycerol, isopropanol, and propylene glycol.

4. The method of

claim 3

wherein said surfactant is anionic.

5. The method of

claim 4

wherein said surfactant is selected from the group consisting of sodium sulfates and sulfonates, and wherein said toxicologically acceptable alkali compound is selected from the group consisting of alkali compounds having sodium cations.

6. The method of

claim 5

wherein said surfactant is selected from sodium alkyl sulfates, sodium n-alkylbenzene sulfonates, sodium mono- and dimethyl naphthalene sulfonates.

7. The method of

claim 6

wherein more than about 95%, by weight of said surfactant, of said surfactant has an alkyl chainlength of C₁₀ to C₁₆.

8. The method of

claim 7

wherein more than about 50%, by weight of said surfactant, of said surfactant has an alkyl chainlength of C₁₂.

9. The method of

claim 8

wherein said composition has a pH of greater than 12.5.

10. The method of

claim 3

wherein said toxicologically acceptable sequestrant/builder is present in said aqueous cleaning solution and is selected from the group consisting of citric acid, tartaric acid, ethylenediaminetetraacetic acid, and mixtures thereof.

11. The method of

claim 3

in which said aqueous cleaning solution has a viscosity of less than about 100 centipoise under shear of greater than about 1000 sec⁻

1.

12. The method of

claim 11

in which said aqueous cleaning solution has a viscosity of less than about 50 centipoise.

13. The method of

claim 1

wherein said aqueous cleaning solution is incompletely removed from said surface.

14. The method of

claim 1

wherein said surfactant comprises sodium alkyl sulfate;

wherein more than about 50%, by weight of said surfactant, of said surfactant has an alkyl chainlength of C₁₂;

wherein said alkali compound is selected from the group consisting sodium hydroxide, sodium carbonate, and sodium bicarbonate;

wherein said organic solvent is selected from the group consisting of ethanol, glycerol, isopropanol, and propylene glycol.

15. The method of

claim 1

wherein said aqueous cleaning solution consists essentially of:

(a) from about 0.005% to below 0.5% of an anionic and/or nonionic surfactant;

(b) from about 0.01% to about 4%, by weight the composition, of GRAS perfume;

(c) a toxicologically-acceptable alkali compound;

(d) from about 0.5% to about 8% of low molecular weight, toxicologically-acceptable organic solvent; and

(e) the balance comprising water;

said aqueous cleaning solution having a pH of greater than 11.6.

16. The method of

claim 15

wherein said surfactant is present at a level of from about 0.01% to about 0.1%.

17. The method of

claim 16

wherein said perfume is present at a level of from about 0.1% to about 2%.

18. The method of

claim 17

wherein said composition has a pH of greater than 12.

19. The method of

claim 1

wherein said aqueous cleaning solution is contained in a container and said aqueous cleaning solution is applied to said surface by dispensing said aqueous cleaning solution from said container.

20. The method of

claim 19

wherein said container is a spray container, suitable for use by an individual to clean hard surfaces.

21. The method of

claim 20

wherein said container comprises a foaming spray head.