Hydrocarbon combustion power generation system with CO2 sequestration

• US 20010015061A1
• Filed: 12/20/2000
• Published: 08/23/2001
• Est. Priority Date: 06/07/1995
• Status: Active Grant

• Current Assignee: World Energy Systems
• Original Assignee: World Energy Systems
• Inventors: Viteri, Fermin, Anderson, Roger E., Brandt, Harry, Taylor, James P.
• Granted Patent: US 6,389,814 B2
• Time in Patent Office: Days
• US Class Current: 60/791
• CPC Class Codes: B60K 6/24 characterised by the combustion engines
• CPC Class Codes: B60K 6/48 Parallel type
• CPC Class Codes: F01K 21/047 having at least one combustion gas turbine
• CPC Class Codes: F02B 75/02 Engines characterised by their cycles, e.g. six-stroke
• CPC Class Codes: F02G 1/04 of closed-cycle type
• CPC Class Codes: F25J 2200/52 in the high pressure column of a double pressure main column system
• CPC Class Codes: F25J 2205/30 using a washing, e.g. "scrubbing" or bubble column for purification purposes
• CPC Class Codes: F25J 2230/80 the fluid being carbon dioxide
• CPC Class Codes: F25J 2260/80 Integration in an installation using carbon dioxide, e.g. for EOR, sequestration, refrigeration etc.
• CPC Class Codes: F25J 3/04018 of main feed air
• CPC Class Codes: F25J 3/04066 of oxygen
• CPC Class Codes: F25J 3/04109 Arrangements of compressors and /or their drivers using work extraction by mechanical coupling of compression and cold expansion F25J3/04381
• CPC Class Codes: F25J 3/04121 Steam turbine as the prime mechanical driver
• CPC Class Codes: F25J 3/04127 Gas turbine as the prime mechanical driver
• CPC Class Codes: F25J 3/04133 Electrical motor as the prime mechanical driver
• CPC Class Codes: F25J 3/04139 Combination of different types of drivers mechanically coupled to the same compressor, possibly split on multiple compressor casings
• CPC Class Codes: F25J 3/04163 Hot end purification of the feed air arrangements of cold regenerators F25J5/00
• CPC Class Codes: F25J 3/04296 Claude expansion, i.e. expanded into the main or high pressure column
• CPC Class Codes: F25J 3/04412 in a classical double column flowsheet, i.e. with thermal coupling by a main reboiler-condenser in the bottom of low pressure respectively top of high pressure column
• CPC Class Codes: F25J 3/04533 for the direct combustion of fuels in a power plant, so-called "oxyfuel combustion"
• CPC Class Codes: F25J 3/04987 : for offshore use
• CPC Class Codes: Y02C 20/40 : of CO2
• CPC Class Codes: Y02E 20/32 : Direct CO2 mitigation
• CPC Class Codes: Y02T 10/62 : Hybrid vehicles

Abstract

A low or no pollution engine is provided for delivering power for vehicles or other power applications. The engine has an air inlet which collects air from a surrounding environment. At least a portion of the nitrogen in the air is removed using a technique such as liquefaction, pressure swing adsorption or membrane based air separation. The remaining gas is primarily oxygen, which is then compressed and routed to a gas generator. The gas generator has an igniter and inputs for the high pressure oxygen and a high pressure hydrogen-containing fuel, such as hydrogen, methane or a light alcohol. The fuel and oxygen are combusted within the gas generator, forming water and carbon dioxide with carbon containing fuels. Water is also delivered into the gas generator to control the temperature of the combustion products. The combustion products are then expanded through a power generating device, such as a turbine or piston expander to deliver output power for operation of a vehicle or other power uses. The combustion products, steam and, with carbon containing fuels, carbon dioxide, are then passed through a condenser where the steam is condensed and the carbon dioxide is collected or discharged. A portion of the water is collected for further processing and use and the remainder is routed back to the gas generator. The carbon dioxide is compressed and cooled so that it is in a liquid phase or super critical state. The dense phase carbon dioxide is then further pressurized to a pressure matching a pressure, less hydrostatic head, existing deep within a porous geological formation, a deep aquifer, a deep ocean location or other terrestrial formation from which return of the CO2 into the atmosphere is inhibited.

Claims

1. A combustion engine providing clean power for various applications and featuring low NOx production and low CO2 release into the atmosphere, comprising in combination:

a source of air, the air including nitrogen and oxygen;

a source of fuel, the fuel including hydrogen and carbon;

an air separator having an inlet coupled to said source of air, a nitrogen separator, an oxygen enriched air outlet, and a nitrogen outlet separate from said oxygen enriched air outlet, such that at least a portion of the nitrogen is removed from the air entering said inlet;

a fuel combustor, said fuel combustor receiving fuel from said source of fuel and oxygen enriched air from said oxygen enriched air outlet of said air separator, said combustor combusting the fuel with the oxygen enriched air to produce elevated pressure and elevated temperature combustion products including H2O and CO2, said combustor having a discharge for said combustion products;

a combustion product expansion device located downstream from said discharge of said combustion device, said expansion device outputting power from said system and having an exhaust for said combustion products;

a combustion products separator downstream from said exhaust, said separator having a first outlet for combustion products including H2O and a second gaseous combustion product outlet, said combustion products separator configured such that at least a portion of the CO2 remains gaseous and at least a portion of the CO2 exits said combustor through said second gaseous combustion product outlet;

said first outlet containing a stream of combustion products from said separator having a greater percentage of H2O than a percentage of H2O in the combustion products entering said separator, such that the stream of combustion products passing through said first outlet is H2O enriched;

a compressor located downstream from said gaseous combustion product outlet, said compressor compressing said gaseous combustion products to above atmospheric pressure; and

a terrestrial formation injection system located downstream from said compressor and upstream from a terrestrial formation beneath the atmosphere, said terrestrial formation capable of holding CO2 therein.

2. The system of

claim 1

wherein said first outlet recirculates back into said system upstream of said expansion device.

3. The system of

claim 2

wherein said first outlet recirculates at least a portion of the combustion products including H2O into said combustor.

4. The system of

claim 1

wherein said compressor has sufficient capability to compress gases passing there through to a pressure at which a liquid phase of CO2 can exist;

and

wherein said terrestrial formation injection system includes a liquid CO2 pump, said liquid CO2 pump including means to further pressurize the CO2 passing there through to a pressure corresponding to a fluid pressure existing at a depth within the terrestrial formation into which the terrestrial formation injection system is connected, such that the CO2 can be delivered into the terrestrial formation at the desired depth and without release of the CO2 into the atmosphere.

5. A combustion engine providing clean power for various applications and featuring low NOx production and low CO2 release into the Earth'"'"'s atmosphere, comprising in combination:

a source of air, the air including nitrogen and oxygen;

a source of fuel, the fuel including hydrogen and carbon;

an air treatment device having an inlet coupled to said source of air, and having an outlet, said air treatment device including a nitrogen separator, such that at least a portion of the nitrogen is removed from the air entering said inlet;

a fuel combustor, said fuel combustor receiving fuel from said source of fuel and O2 enriched air from said outlet of said air treatment device, said combustor combusting said fuel with the O2 enriched air to produce elevated pressure and elevated temperature combustion products including steam and carbon dioxide, said combustor having a discharge for said combustion products;

a combustion product expander located downstream from said discharge of said combustor, said expander outputting power from said engine and having an exhaust for said combustion products;

wherein said fuel combustor produces elevated pressure and elevated temperature combustion products including H2O and CO2;

a combustion products separator located downstream of said combustor exhaust, said separator including an H2O outlet for an H2O enriched stream of the combustion products and a CO2 outlet for a CO2 enriched stream of the combustion products;

wherein said CO2 rich combustion product outlet of said separator is located upstream from a compressor, said compressor compressing the gaseous combustion products including CO2 to a pressure above atmospheric pressure; and

a terrestrial formation injection system located downstream from said compressor and upstream from a terrestrial formation beneath the atmosphere, said terrestrial formation capable of holding CO2 therein without substantial release of CO2 into the atmosphere.

6. The engine of

claim 5

wherein said separator receives all of said combustion products exiting said exhaust.

7. The engine of

claim 5

wherein said expander exhaust is located upstream from a condenser, said condenser having an H2O outlet for liquid H2O and a gaseous combustion product outlet, said gaseous combustion products being a majority CO2, said condenser configured such that the CO2 remains gaseous and exits said condenser through said gaseous combustion product outlet;

whereby CO2 generated by said engine is separated from other combustion products for further storage, handling and disposal of the CO2.

8. The engine of

claim 5

wherein said nitrogen separator of said air treatment device includes a means to remove at least a portion of the nitrogen from the air entering said inlet of said air treatment device.

9. The engine of

claim 5

wherein said H2O outlet is coupled to a fluid conduit directing at least a portion of the H2O rich stream of combustion products passing through said H2O outlet back into said engine upstream of said combustion product expander.

10. The engine of

claim 5

wherein at least a portion of the CO2 enriched combustion products exiting said CO2 outlet are routed to a condenser, said condenser condensing at least a portion of H2O remaining within the CO2 enriched combustion products entering said condenser, said condensed H2O exiting said condenser and routed back into said system upstream from said combustion product expansion device.

11. The engine of

claim 5

wherein said fuel combustor includes an H2O inlet coupled to a pressurized source of H2O said H2O inlet delivery H2O into said combustor to control a temperature of the combustion products in said combustor and exiting said combustor.

12. A combustion device producing carbon dioxide for various applications and featuring low NOx production and low CO2 release into the atmosphere, comprising in combination:

a source of air, the air including nitrogen and oxygen;

a source of fuel, the fuel including hydrogen and carbon;

an air separator having an inlet coupled to said source of air, a nitrogen separator, an oxygen enriched air outlet, and a nitrogen outlet separate from said oxygen enriched air outlet, such that at least a portion of the nitrogen is removed from the air entering said inlet;

a fuel combustor, said fuel combustor receiving fuel from said source of fuel and oxygen enriched air from said outlet of said air separator, said combustor combusting the fuel with the oxygen enriched air to produce elevated pressure and elevated temperature combustion products including H2O and CO2, said combustor having a discharge for said combustion products;

a combustion products separator downstream from said combustor device which separates at least a portion of the H2O from other combustion products including CO2 downstream from said discharge and including an H2O outlet for an H2O rich stream of the combustion products and an exhaust for the other combustion products including CO2;

a compressor downstream from said exhaust, said compressor pressurizing fluids passing there through to a pressure above atmospheric pressure; and

a terrestrial formation injection system downstream from said compressor, said injection system leading to a terrestrial formation beneath the atmosphere, said terrestrial formation capable of holding CO2 therein.

13. The combustion device of

claim 12

wherein at least a portion of the H2O exiting said combustion products separator through said H2O outlet is routed through a fluid conduit to said fuel combustor where the H2O is combined with said combustion products to decrease a temperature of the combustion products and increase an amount of H2O exiting said discharge of said fuel combustor.

14. The combustion device of

claim 12

wherein said combustion products separator includes a condenser, said condenser having a temperature and pressure therein at which at least a portion of the H2O in the combustion products condenses into a liquid phase and at which at least a portion of the CO2 in the combustion products remains in a gaseous phase.

15. The combustion device of

claim 12

wherein a mass fraction of H2O in the said H2O rich stream of the combustion products is greater than a mass fraction of other components in said H2O rich stream of the combustion products.

16. The combustion device of

claim 12

wherein the terrestrial formation is a subterranean formation which contains at least some hydrocarbons therein, the subterranean formation being penetrated by one or more wells, an injection system capable of injecting combustion products including CO2 into the hydrocarbon containing formation such that recovery of hydrocarbons from the hydrocarbon containing formation is enhanced.

17. The combustion device of

claim 12

wherein a CO2 pump is located downstream from said compressor and upstream of said terrestrial formation injection system, said CO2 pump increasing a pressure of the CO2 exiting the exhaust of the combustion products separator while the CO2 is at least partially in a liquid state.

18. The combustion device of

claim 17

wherein said CO2 pump includes means to pressurize the fluids passing there through to a pressure which results in a pressure of between 10 psi above the pressure of the fluid in said formation and a pressure less than 0.8 psi per foot of depth of said formation.

19. The combustion device of

claim 12

wherein a combustion product expansion device is interposed between said discharge of said fuel combustor and said separator, said combustion product expansion device including means to output power from said engine.

20. The combustion device of

claim 19

wherein said output power is at least partially used to supply operative power to said air separator.

21. The combustion device of

claim 19

wherein said combustion product expansion device includes at least two turbines including a high pressure turbine located downstream from said discharge of said fuel combustor and upstream from a reheater, said reheater receiving fuel from said source of fuel and O2 enriched air from said outlet of said air separator, said reheater combusting the fuel with the O2 enriched air to produce combustion products including H2O and CO2, said reheater also receiving H2O and CO2 from said high pressure turbine and mixing at least a portion of said H2O and said CO2 from said high pressure turbine with at least a portion of said H2O and said CO2 generated within said reheater.

22. The combustion device of

claim 12

wherein said injection system is configured to deliver at least a portion of the combustion products including CO2 into a terrestrial formation taken from the group of terrestrial formations including:

beneath the surface of an ocean, into an aquifer, into a hydrocarbon containing formation and into a porous underground geological formation.

23. The combustion device of

claim 12

wherein said exhaust of said combustion products separator discharges primarily CO2 and said compressor pressurizes the CO2 until the CO2 becomes a super critical fluid.