Method for controlling zinc addition to power reactor

• US 20010026604A1
• Filed: 03/28/2001
• Published: 10/04/2001
• Est. Priority Date: 10/05/1998
• Status: Abandoned Application

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Marble, William J.
• Application Number:
  US09/818,777
• Publication Number:
  US 20010026604A1
• Time in Patent Office: Days
• US Class Current: 376/306
• CPC Class Codes: G21C 17/0225 Chemical surface treatment, e.g. corrosion corrosion prevention in presence of water from scale removal or by modification of the properties of the liquid C02F5/00; inhibiting corrosion by adding corrosion inhibitors C23F11/00
• CPC Class Codes: G21C 19/307 specially adapted for liquids decontamination of liquids G21F9/04
• CPC Class Codes: Y02E 30/30 Nuclear fission reactors

Abstract

Method for controlling the introduction of zinc to a nuclear power reactor to control radiation build-up wherein zinc ions are introduced into the reactor water to counteract loss of zinc within the reactor system. In the process, the rate of introduction of zinc ions into the reactor water is balanced with the rate at which zinc ions are lost from the reactor.

Claims

1. A method of controlling zinc addition to a nuclear power reactor to control radiation build-up wherein zinc ions are introduced into the reactor water, which comprises balancing the rate of introduction of zinc ions into the reactor water with the rate at which zinc ions are lost to the reactor system.

2. A method according to

claim 1

, wherein the zinc ions are introduced to produce a zinc ion concentration of about 1 ppb to 100 ppb.

3. A method according to

claim 2

, wherein the zinc ion concentration is about 1 ppb to 50 ppb.

4. A method according to

claim 1

, wherein the zinc ions are introduced according to the equation:

Zinc In=Zinc Out+Zinc Accumulation

wherein zinc in is the amount of zinc entering the reactor water, zinc out is the amount of zinc lost to system processes, and zinc accumulation is combination of the zinc which is incorporated with particulate iron entering with feedwater, zinc which is deposited on the fuel cladding surface as a result of boiling, and zinc which is incorporated into oxide film which forms on surfaces of the reactor and components thereof.

5. A method according to

claim 4

, wherein zinc in is defined by the equation:

Zinc In=F×

(Zn_FS+Zn_F1)

where;

F=Feedwater flow rate (M#/hr)

Zn_FS=Soluble zinc concentration in the feedwater (ppb)

Zn_F1=Insoluble zinc concentration in the feedwater (ppb).

6. A method according to

claim 5

, wherein zinc out is defined by the equation:

Zinc Out=R×

{((Zn_Rs+Zn_R1)−

(Zn_REs+Zn_RE1)}+(S×

Zn_S)  

 

(3)

where;

R=Reactor water clean up flow rate (M#/hr)

Zn_Rs=Soluble zinc concentration in the reactor water (ppb)

Zn_R1=Insoluble zinc concentration in the reactor water (ppb)

Zn_REs=Soluble zinc concentration in the RWCU effluent (ppb)

Zn_RE1=Insoluble zinc concentration in the RWCU effluent (ppb)

S=Steam flow rate (M#/hr)

Zn_S=Total zinc concentration in the steam (ppb)

7. A method according to

claim 6

, wherein zinc accumulation is defined by the equation:

Zinc Accumulation=(Zinc to Particulate)+(Zinc To Boiling Deposition)+(Zinc To Corrosion Film Incorporation)  

 

(4)

8. A method according to

claim 7

, wherein zinc to particulate incorporation is defined by the equation:

Zinc To Particulate=F×

(Fe_Fs+Fe_F1)×

(a×

Zn_Rs)  

 

(5)

where;

Fe_Fs=Soluble iron concentration in the feed water (ppb)

Fe_F1=Insoluble iron concentration in the feedwater (ppb)

a=Incorporation fraction for zinc (# Zn/# Fe/ppb of zinc)

Zn_Rs=Soluble zinc concentration in the reactor water (ppb)

S=Steam flow rate (M#/hr)

Zn_S=Total zinc concentration in the steam (ppb).

9. A method according to

claim 8

, wherein zinc to boiling deposition is defined by the equation:

Zinc to Boiling Deposition=F×

(b×

Zn_Rs)  

 

(6)

where;

b=Boiling deposition fraction for zinc (# Zn/# H₂O/ppb of zinc).

10. A method according to

claim 9

, wherein zinc to corrosion film incorporation is defined by the equation:

Zinc to Corrosion Film Incorporation=(c×

Zn_Rs)×

ƒ

C_(t)dt  

 

(7)

where;

c=corrosion incorporation fraction for zinc (# Zn/# Oxide/ppb of Zn)

C_(t)=Oxide formation rate as function of time (# Oxide/hr)

t=time (hr)

11. A method for estimating the concentration factor for zinc between the reactor water and the feed water of a nuclear reactor comprising using the equation:

CF=1/{(0.9*RWCU)+(0.02*Fe_FW)+(0.008)} 

 

(8)

where;

CF=Concentration Factor (R×

W Zn/FW Zn)

RWCU=Size of the reactor water cleanup system (% of FW flow)

Fe_FW=Total iron concentration in the feedwater ppb)

wherein 0.9 represents the efficiency of removal by the reactor water cleanup system, 0.02 represents the amount of zinc absorbed by the feedwater iron per ppb of zinc in the reactor water, and 0.008 represents the boiling deposition factor for zinc.

12. A method according to

claim 11

, wherein the consumption rate of zinc is defined by the equation:

Zn#/yr={(Zn_R*0.9*RWCU)+Zn_R*0.02(*Fe_Fw)+(Zn_R*0.008)}*FW*(1E−

9)*24*365

where;

Zn_R=Target reactor water zinc concentration (ppb)

FW=Feedwater flow rate (lbs/hr)

13. A method according to

claim 12

, wherein the total pounds of ZnO required is obtained by dividing the answer obtained according to the equation as defined in claim 14 by 0.8.