Alkaline cell with improved separator

• US 20010028976A1
• Filed: 12/18/2000
• Published: 10/11/2001
• Est. Priority Date: 03/29/1999
• Status: Active Grant

• Current Assignee: Duracell U.S. Operations, Inc. (Berkshire Hathaway Incorporated)
• Original Assignee: Gillette Company (The Procter & Gamble Company)
• Inventors: Licata, John, Sargeant, Sean, Treger, Jack
• Granted Patent: US 6,514,637 B2
• Time in Patent Office: Days
• US Class Current: 429/56
• CPC Class Codes: H01M 12/06 with one metallic and one gaseous electrode
• CPC Class Codes: H01M 50/403 Manufacturing processes of separators, membranes or diaphragms
• CPC Class Codes: H01M 50/414 Synthetic resins, e.g. thermoplastics or thermosetting resins
• CPC Class Codes: H01M 50/46 Separators, membranes or diaphragms characterised by their combination with electrodes
• CPC Class Codes: H01M 50/491 Porosity
• CPC Class Codes: H01M 6/06 Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

An electrochemical separator is formed insitu on an electrode surface within an electrochemical cell, preferably an alkaline cell cathode surface. The alkaline cell comprises a zinc anode, a and potassium hydroxide electrolyte. The cathode may comprise a cathode comprising manganese dioxide. The separator may be formed by coating an electrode surface preferably with a low molecular weight copolymer of polyvinyalcohol and polyvinylacetate. The film can be coagulated to form a permeable separator uniformly conforming to and covering the electrode surface irrespective of the shape and contour of the electrode. A separate protector disk can be inserted onto the top surface of the cathode to protect the cathode from shorting in the event that imperfections in the separator surface develop. The protector disk can have a protruding lip which surrounds and protects the inside corner edge of the cathode.

Claims

1. In an alkaline electrochemical cell, said cell having an open ended cylindrical casing, said cell having a positive and a negative terminal, an anode comprising zinc and a cathode comprising manganese dioxide, said cathode having an outside surface contacting said casing and an inside surface of said cathode facing said anode, a separator contacting said inside surface of the cathode, an electrically insulating sealing disk having a rupturable membrane therein, said insulating sealing disk having an electrically conductive current collector passing therethrough, said insulating sealing disk sealing the open end of said casing and providing electrical insulation between said current collector and said casing, the improvement comprising:

the separator adhering to the inside surface of the cathode;

an electrically insulating protector disk in contact with a surface of said cathode, said protector disk being located between the said cathode and said insulating sealing disk.

2. The cell of

claim 1

wherein the cathode runs along a major portion of the length of the inside surface of said casing, wherein said cathode has a top surface defined as the surface of the cathode in closest proximity to the open end of the casing, wherein the protector disk has a solid surface having a hollow core therethrough, and wherein said protector disk solid surface is in contact with said cathode top surface covering at least a portion of said cathode top surface.

3. The cell of

claim 2

wherein the protector disk has lip protruding from said solid surface, wherein said lip forms a continuous closed surface defining said hollow core, wherein said lip covers a portion of the inside surface of said cathode facing said anode.

4. The cell of

claim 2

wherein said protector disk interlocks with said insulating sealing disk providing a seal therebetween.

5. In an alkaline electrochemical cell, said cell having an open ended cylindrical cell casing and an end cap assembly inserted therein closing said casing, said cell having a positive and a negative terminal, an anode comprising zinc, and a cathode comprising manganese dioxide, said cathode having an outside surface contacting said casing and an inside surface of said cathode facing said anode, a separator contacting said inside surface of the cathode, said end cap assembly comprising an end cap and an electrically insulating sealing disk having a rupturable membrane therein, said insulating sealing disk having an elongated electrically conductive current collector passing therethrough, the current collector being in electrical contact with the end cap, said insulating sealing disk sealing the open end of said casing and providing electrical insulation between said current collector and said casing, the improvement comprising:

an electrically insulating protector member in contact with a surface of said cathode, said protector member being located between said cathode and said insulating sealing disk.

6. The cell of

claim 5

wherein the protector member is a disk having a solid surface having at least one hollow core therethrough.

7. The cell of

claim 5

wherein the protector member interloccks with said insulating sealing disk.

8. The cell of

claim 7

wherein the cathode runs along a major portion of the length of the inside surface of said casing, wherein said cathode has a top surface defined as the surface of the cathode in closest proximity to the open end of the casing, and wherein said protector disk is in contact with said cathode top surface.

9. The cell of

claim 8

wherein said solid surface of the protector disk contacts and covers at least a portion of said top surface of the cathode.

10. The cell of

claim 9

wherein said solid surface of the protector disk forms an annular surface conforming to the top surface of the cathode, thereby covering said cathode top surface.

11. The cell of

claim 10

wherein the protector disk has a lip protruding from said protector disk solid surface, said protruding lip defining said hollow core.

12. The cell of

claim 11

wherein said lip forms a circumferential surface defining said hollow core.

13. The cell of

claim 12

wherein said lip is perpendicular to said protector disk solid surface.

14. The cell of

claim 12

wherein said lip covers a portion of the inside surface of said cathode facing said anode.

15. The cell of

claim 14

wherein said cathode is in the form of an elongated annulus having a top surface, an outside surface and an inside surface, wherein said cathode outside surface contacts said casing and said cathode inside surface faces said anode with said separator therebetween, wherein said cathode top surface faces the open end the cell, wherein said cathode top surface intersects with said cathode inside surface to from a top inside edge of said cathode, wherein said protector disk comprising said protruding lip covers said top inside edge of the cathode.

16. The cell of

claim 15

wherein said cell has an anode cavity for insertion of said anode and the shape of said protector hollow core defined by said protruding lip conforms to the shape of said anode cavity.

17. The cell of

claim 15

wherein the protector disk has an outer edge which contacts a portion of the inside surface of said casing immediately above said cathode top surface.

18. The cell of

claim 15

wherein said protector disk contacts said insulating sealing disk providing a seal therebetween.

19. The cell of

claim 15

wherein the inside surface of said cathode is convoluted.

20. The cell of

claim 19

wherein the inside surface of said cathode is a circumferential convoluted surface having alternating convex and concave curvatures.

21. The cell of

claim 16

wherein said hollow core of the protector disk is of semicircular shape.

22. The cell of

claim 16

wherein said hollow core of the protector disk is of circular shape.

23. The cell of

claim 15

wherein said separator is a polymeric coating adhered to the inside surface of said cathode.

24. The cell of

claim 23

wherein said separator is a polymeric film comprising a copolymer of polyvinylalcohol and polyvinylacetate.

25. In an alkaline electrochemical cell, said cell having an open ended cylindrical casing, said cell having a positive and a negative terminal, an anode comprising zinc anode material and a cathode comprisng manganese dioxide, said cathode having an outside surface contacting said casing and an inside surface of said cathode facing said anode, a separator contacting said inside surface of the cathode, an electrically insulating sealing disk having a rupturable membrane therein, said insulating sealing disk having an electrically conductive current collector passing therethrough, said insulating sealing disk sealing the open end of said casing and providing electrical insulation between said current collector and said casing, the improvement comprising:

the separator adhering to the inside surface of the cathode;

said insulating sealing disk has a circuferential skirt protruding into the cell interior, wherein a portion of said skirt extends over and contacts a portion of the cathode inside surface thereby providing an impenetrable barrier between said anode material and said casing.

26. The cell of

claim 25

wherein the cathode runs along a major portion of the length of the inside surface of said casing, wherein said cathode has a top surface defined as the surface of the cathode in closest proximity to the open end of the casing, and wherein a second portion of said skirt contacts and covers a portion of said cathode top surface.