Thermoset/thermoplastic fibers and process for producing the same

• US 20010049421A1
• Filed: 01/02/2001
• Published: 12/06/2001
• Est. Priority Date: 09/29/1999
• Status: Abandoned Application

• Current Assignee: Dominick A. Burlone, Doris Carolyn Morgan
• Original Assignee: Dominick A. Burlone, Doris Carolyn Morgan
• Inventors: Burlone, Dominick A., Morgan, Doris Carolyn
• Application Number:
  US09/750,773
• Publication Number:
  US 20010049421A1
• Time in Patent Office: Days
• US Class Current: 525/427
• CPC Class Codes: D01D 5/18 by means of rotating spinnerets
• CPC Class Codes: D01F 6/94 of other polycondensation products

Abstract

The present invention modifies a cross-linkable thermoset polymer with a thermoplastic polymer to create a spinnable thermoset/thermoplastic polymer composition that may be spun into thermoset/thermoplastic fibers.

Claims

1. A thermoset/thermoplastic fiber comprising a blend comprising:

(a) a thermoset polymer; and

(a) a thermoplastic polymer.

2. The fiber of

claim 1

, wherein the thermoset polymer is melamine.

3. The fiber of

claim 2

, wherein up to about 30 mole percent of the melamine is replaced by hydroxyalkylmelamine.

4. The fiber of

claim 2

, wherein the melamine is a condensation polymer of melamine, or melamine derivatives, with formaldehyde.

5. The fiber of

claim 4

, wherein up to about 30 mole percent of the melamine is replaced by hydroxyalkylmelamine.

6. The fiber of

claim 4

, wherein the condensation polymer is obtainable by condensation of a mixture comprising:

(a) from about 90 to about 99.9 mole percent of a mixture consisting essentially of;

(1) from about 30 to about 99 mole percent of melamine; and

(2) from about 1 to about 70 mole percent of a substituted melamine of the general formula I

 

where X, X′ and

X″

are each selected from the group consisting of —

NH₂, —

NHR, and —

NRR′ and

X, X′ and

X″

are not all —

NH₂, and R and R′

are each selected from the group consisting of hydroxy-C₂-C₁₀-alkyl, hydroxy-C₂-C₄-alkyl-(oxa-C₂-C₄-alkyl)_n, where n is a number from 1 to 5, and amino-C₂-C₁₂-alkyl, or mixtures of melamine I, and

(b) from about 0.1 to about 10 mole percent, based on (A) and (B), of phenols that are unsubstituted or that are substituted by radicals selected from the group consisting of C₁-C₉-alkyl and hydroxyl, C₁-C₄-alkanes substituted by two or three phenol groups, di(hydroxyphenyl) sulfones, or mixtures of these phenols,

with formaldehyde or formaldehyde-source compounds in a molar ratio of melamine to formaldehyde within the range of from about 1;

1.15 to about 1;

4.5, and, more preferably, from about 1;

2.

7. The fiber of

claim 1

, wherein the thermoplastic polymer is selected from the group consisting of water-soluble thermoplastic polymers.

8. The fiber of

claim 7

, wherein the thermoplastic polymer is selected from the group consisting of polyamides with solubilizing substituents and copolymers thereof, polyesters with solubilizing substituents and copolymers thereof, polyolefins with solubilizing substituents and copolymers thereof, and cellulose polymers with solubilizing substituents and copolymers thereof.

9. The fiber of

claim 8

, wherein the thermoplastic polymer is selected from water-soluble polyamides, polyesters, and polyolefins and copolymers thereof.

10. A process for producing thermoset/thermoplastic fibers comprising the steps of:

(a) providing a suitable thermoset polymer;

(b) providing a suitable thermoplastic polymer;

(c) blending the thermoset polymer with the thermoplastic polymer to form a thermoset/thermoplastic polymer composition; and

(d) spinning thermoset/thermoplastic fibers from the polymer composition.

11. The process of

claim 10

, wherein the thermoset polymer resin is melamine.

12. The process of

claim 11

, wherein the melamine is a condensation polymer of melamine, or melamine derivatives, with formaldehyde.

13. The process of

claim 11

, wherein up to about 30 mole percent of the melamine is replaced by hydroxyalkylmelamine.

14. The process of

claim 12

, wherein up to about 30 mole percent of the melamine is replaced by hydroxyalkylmelamine.

15. The process of

claim 12

, wherein the condensation polymer is obtainable by condensation of a mixture comprising:

(a) from about 90 to about 99.9 mole percent of a mixture consisting essentially of;

(1) from about 30 to about 99 mole percent of melamine; and

(2) from about 1 to about 70 mole percent of a substituted melamine of the general formula I

 

where X, X′ and

X″

are each selected from the group consisting of —

NH₂, —

NHR, and —

NRR′ and

X, X′ and

X″

are not all —

NH₂, and R and R′

are each selected from the group consisting of hydroxy-C₂-C₁₀-alkyl, hydroxy-C₂-C₄-alkyl-(oxa-C₂-C₄-alkyl)_n, where n is a number from 1 to 5, and amino-C₂-C₁₂-alkyl, or mixtures of melamine I, and

(b) from about 0.1 to about 10 mole percent, based on (A) and (B), of phenols that are unsubstituted or that are substituted by radicals selected from the group consisting of C₁-C₉-alkyl and hydroxyl, C₁-C₄-alkanes substituted by two or three phenol groups, di(hydroxyphenyl) sulfones, or mixtures of these phenols,

with formaldehyde or formaldehyde-source compounds in a molar ratio of melamine to formaldehyde within the range of from about 1;

1.15 to about 1;

4.5, and, more preferably, from about 1;

2.

16. The process of

claim 10

, wherein the thermoplastic polymer is selected from the group consisting of water-soluble thermoplastic polymers.

17. The process of

claim 16

, wherein the thermoplastic polymer is selected from the group consisting of polyamides with solubilizing substituents and copolymers thereof, polyesters with solubilizing substituents and copolymers thereof, polyolefins with solubilizing substituents and copolymers thereof, and cellulose polymers with solubilizing substituents and copolymers thereof.

18. The process of

claim 17

, wherein the thermoplastic polymer is selected from water-soluble polyamides, polyesters, and polyolefins and copolymers thereof.

19. The process of

claim 10

, wherein step (d) comprises a centrifugal spinning process.

20. The process of

claim 19

, wherein the centrifugal spinning process comprises supplying the thermoset/thermoplastic polymer composition to a whirler plate and ensuring that inside the whirler plate the resin is under a sufficient pressure to completely fill the nozzles of the whirler plate as the fibers are being spun.

21. The process of

claim 10

, further comprising the step of:

(e) subjecting the fibers to heat at temperatures ranging from about 180°

C. to about 220°

C. for a time sufficient to cure the fibers.