Compositions for three-dimensional printing of solid objects

• US 20010050031A1
• Filed: 04/13/2001
• Published: 12/13/2001
• Est. Priority Date: 04/14/2000
• Status: Abandoned Application

• Current Assignee: Z CORPORATION (A Holdings Corp.)
• Original Assignee: Z CORPORATION (A Holdings Corp.)
• Inventors: Bredt, James F., Anderson, Timothy, Tarkanian, Michael J., Clark, Sarah L., DiCologero, Matthew, Uy, Evert
• Application Number:
  US09/835,292
• Publication Number:
  US 20010050031A1
• Time in Patent Office: Days
• US Class Current: 106/162.9
• CPC Class Codes: B29C 41/003 characterised by the choice of material
• CPC Class Codes: B29C 64/112 using individual droplets, e.g. from jetting heads
• CPC Class Codes: B29C 64/165 using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber
• CPC Class Codes: B29C 67/24 characterised by the choice of material
• CPC Class Codes: B29K 2033/08 Polymers of acrylic acid esters, e.g. PMA, i.e. polymethylacrylate
• CPC Class Codes: B29K 2105/0097 Glues or adhesives, e.g. hot melts or thermofusible adhesives
• CPC Class Codes: B33Y 10/00 Processes of additive manufacturing
• CPC Class Codes: B33Y 70/10 Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: C09D 11/00 Inks

Abstract

A three-dimensional printing materials system and method can produce both appearance models and small numbers of functional parts in an office environment. The method can include building cross-sectional portions of a three-dimensional article, and assembling the individual cross-sectional areas in a layer-wise fashion to form a final article. The individual cross-sectional areas can be built by using an ink-jet printhead to deliver an aqueous solvent or binder to an adhesive particulate mixture, causing the particles of the mixture to adhere together, and to previous cross-sectional areas. The binder can include at least one of nonaqueous organic monomeric compound, anionically ionizable polymer, cationic polymer, polymer, waterborne colloid, or inorganic solute.

Claims

1. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the component comprising a nonaqueous organic monomeric compound.

2. The compositing of

claim 1

, wherein the compound includes at least one of an alcohol, an ester, an ether, a silane, a vinyl monomer, an acrylic monomer, or a methacrylate monomer.

3. The composition of

claim 1

, comprising a solvent and a solute, and wherein the compound is the solvent.

4. The composition of

claim 3

, wherein the solvent includes an alcohol.

5. The composition of

claim 4

, wherein the alcohol is methyl alcohol, ethyl alcohol, isopropanol, or t-butanol.

6. The composition of

claim 3

, wherein the solvent includes an ester.

7. The composition of

claim 6

, wherein the ester includes at least one of ethyl acetate, dimethyl succinate, diethyl succinate, dimethyl adipate, or ethylene glycol diacetate.

8. The composition of

claim 2

, wherein the compound includes a mixed vinyl-silane monomer.

9. The composition of

claim 8

, wherein the mixed monomer includes vinyltriisopropoxysilane.

10. The composition of

claim 2

, wherein the acrylic monomer includes at least one of tri(propylene glycol) diacrylate, ethylene glycol phenyl ether acrylate, or 1,6 hexanediol diacrylate.

11. The composition of

claim 2

, wherein the methacrylic monomer includes at least one of 1,3 butylene glycol dimethacrylate, neopentyl glycol dimethacrylate, butyl methacrylate, 1,6 hexanediol dimethacrylate, or di(propylene glycol) allyl ether methacrylate.

12. The composition of

claim 1

, wherein the compound is curable in combination with a photoinitiator to form a solid, by ultraviolet radiation having a wavelength between about 320-500 nm and an energy density of about 1 joule/cm².

13. The composition of

claim 1

, wherein the compound is a solvent for a resin in the particulate material.

14. The composition of

claim 13

, wherein the resin includes at least one of shellac, polyvinyl pyrrolidone, polyvinyl acetate, polyvinyl alcohol, polystyrene, styrene-butadiene copolymer, or acrylonitrile-butadiene-styrene copolymer.

15. The composition of

claim 1

, wherein the particulate material includes a filler that includes an inorganic compound.

16. The composition of

claim 15

, wherein the filler includes at least one of clay, aluminum oxide, silicon dioxide, aluminum silicate, potassium aluminum silicate, calcium silicate, calcium hydroxide, calcium aluminate, calcium carbonate, sodium silicate, zinc oxide, titanium dioxide, or magnetite.

17. The composition of

claim 15

, further comprising a printing aid dispersed throughout the filler.

18. The composition of

claim 17

, wherein the printing aid includes at least one of sorbitan trioleate, sorbitan mono-oleate, sorbitan monolaurate, polyoxyethylene sorbitan mono-oleate, polyethylene glycol, soybean oil, mineral oil, propylene glycol, fluroaklkyl polyoxyethylene polymers, glycerol triacetate, polypropylene glycol, ethylene glycol octanoate, ethylene glycol decanoate, ethoxylated derivatives of 2,4,7,9-Tetramethyl-5-decyne-4,7-diol, oleyl alcohol, or oleic acid.

19. A binder composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the binder composition including an adhesive in combination with a fluid, the adhesive comprising a nonaqueous organic monomeric compound.

20. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the composition comprising an anionically ionizable polymer consisting of compounds selected from the group including polymethacrylic acid, polymethacrylic acid sodium salt, and sodium polystyrene sulfonate.

21. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the composition including an adhesive in combination with a fluid, the adhesive comprising an anionically ionizable polymer consisting of compounds selected from the group including polymethacrylic acid, polymethacrylic acid sodium salt, and sodium polystyrene sulfonate.

22. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the composition comprising a cationic polymer.

23. The composition of

claim 22

, wherein the polymer includes polyethyleneimine and polydiallyldimethylammonium chloride.

24. A binder composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the binder composition including an adhesive in combination with a fluid, the adhesive comprising a cationic polymer.

25. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the composition comprising a nonionic polymer.

26. The composition of

claim 25

, wherein the polymer includes at least one of polyvinyl pyrrolidone, polyvinyl pyrrolidone copolymer with polyvinyl acetate, polyvinyl alcohol, polyvinyl methyl ether, polyacrylamide, or poly-2-ethyl-2-oxazoline.

27. A binder composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the binder including an adhesive in combination with a fluid, the adhesive comprising a nonionic polymer.

28. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the adhesive comprising a polymer selected from the group consisting of polymethacrylic acid, polymethacrylic acid sodium salt, sodium polystyrene sulfonate, and polyethyleneimine.

29. A binder composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the binder including an adhesive in combination with a fluid, the adhesive comprising a polymer selected from the group consisting of polymethacrylic acid, polymethacrylic acid sodium salt, sodium polystyrene sulfonate, and polyethyleneimine.

30. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the adhesive comprising a waterborne colloid selected from the group consisting of polymethyl methacrylate, polystyrene, natural rubber, polyurethane, polyvinyl acetate, and alkyd resins.

31. A binder composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the binder including an adhesive in combination with a fluid, the adhesive comprising a polymer selected from the group consisting of polymethyl methacrylate, polystyrene, natural rubber, polyurethane, polyvinyl acetate, and alkyd resins.

32. A chemical composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the adhesive comprising an inorganic solute selected from the group consisting of sodium polyphosphate, sodium hydrogen phosphate, sodium hydrogen pyrophosphate, sodium tetraborate, ammonium hydrogen phosphate, sodium chloride, ammonium nitrate, potassium sulfate, ammonium chloride, and calcium formate.

33. A binder composition for selectively adhering particulate material to form a solid object in a three-dimensional printer, the binder including an adhesive in combination with a fluid, the adhesive comprising an inorganic solute selected from the group consisting of sodium polyphosphate, sodium tetraborate, sodium chloride, ammonium nitrate, potassium sulfate, ammonium chloride, and calcium formate.

34. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition including a nonaqueous organic monomeric compound.

35. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition comprising an anionically ionizable polymer consisting of compounds selected from the group including polymethacrylic acid, polymethacrylic acid sodium salt, and sodium polystyrene sulfonate.

36. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition comprising a cationic polymer.

37. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition comprising a nonionic polymer.

38. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition comprising a polymer selected from the group consisting of polymethacrylic acid, polymethacrylic acid sodium salt, sodium polystyrene sulfonate, and polyethyleneimine.

39. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition comprising a waterborne colloid selected from the group consisting of polymethyl methacrylate, polystyrene, natural rubber, polyurethane, polyvinyl acetate, and alkyd resins.

40. A method of forming a three-dimensional object, comprising:

forming a layer of filler that includes a particulate material; and

applying a chemical composition to the layer of filler at particular locations to bind the filler at particular locations, the composition comprising an inorganic solute selected from the group consisting of sodium polyphosphate, sodium tetraborate, sodium chloride, ammonium nitrate, potassium sulfate, ammonium chloride, and calcium formate.