Coupled electrochromic compounds with photostable dication oxidation states
First Claim
1. An electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge comprising a covalent bond or an intervening hydrocarbon structure optionally containing one or more heteroatoms, to a second anodic monomeric electrochromic compound, and optionally additional monomeric electrochromic compounds such that electronic communication is exhibited between said anodic monomeric compounds.
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Abstract
Coupling of anodic electrochromic compounds by a covalent bond or a bridge link which provides for electronic communication between the coupled electrochromic compounds results in coupled electrochromic compounds which exhibit greater stability as well as electrochromic activity that differs from the monomeric electrochromic compounds. Extension of the absorption spectrum into the near-infrared region of the spectrum is frequently observed. The coupled electrochromic compounds are highly suitable for use in electrochromic media used to produce electrochromic devices.
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Citations
20 Claims
- 1. An electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge comprising a covalent bond or an intervening hydrocarbon structure optionally containing one or more heteroatoms, to a second anodic monomeric electrochromic compound, and optionally additional monomeric electrochromic compounds such that electronic communication is exhibited between said anodic monomeric compounds.
- 5. An electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge comprising a covalent bond or an intervening hydrocarbon structure optionally containing one or more heteroatoms to a second anodic monomeric electrochromic compound, and optionally additional anodic monomeric compounds such that the absorption spectrum of said coupled electrochromic compound is different from the sum of the absorption spectrum of a mixture of the individual anodic monomeric compounds on an identical mole basis.
- 9. An electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge comprising a covalent bond or an intervening hydrocarbon structure optionally containing one or more heteroatoms to a second anodic monomeric electrochromic compound such, and optionally additional anodic monomeric electrochromic compounds that the voltammogram of said coupled electrochromic compound is measurably different from said anodic monmeric compounds when run in the same solvent.
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15. An electrochromic device comprising:
- a first transparent substrate, a second substrate, a sealing member disposed between said first and second substrates to define a chamber;
an electrochromic medium disposed in said chamber, said electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge to a second anodic monomeric electrochromic compound, such that electronic communication is exhibited between said first anodic compound and said second anodic compound.
- a first transparent substrate, a second substrate, a sealing member disposed between said first and second substrates to define a chamber;
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16. An electrochromic device comprising:
- a first transparent substrate, a second substrate, a sealing member disposed between said first and second substrates to define a chamber;
an electrochromic medium disposed in said chamber, said electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge to a second anodic monomeric electrochromic compound, such that the absorption spectrum of said coupled electrochromic compound is different from the sum of the absorption spectrum of a mixture of the individual first and second anodic electrochromic compound on an identical mole basis.
- a first transparent substrate, a second substrate, a sealing member disposed between said first and second substrates to define a chamber;
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17. An electrochromic device comprising:
- a first transparent substrate, a second substrate, a sealing member disposed between said first and second substrates to define a chamber;
an electrochromic medium disposed in said chamber, said electrochromic medium comprising two or more electroactive compounds, at least one of said electroactive compounds being a coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge to a second anodic monomeric electrochromic compound, such that the voltammogram of said coupled electrochromic compound is measurably different from said first and second monomeric electrochromic compounds when run in the same solvent.
- a first transparent substrate, a second substrate, a sealing member disposed between said first and second substrates to define a chamber;
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18. A coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge to a second anodic monomeric electrochromic compound such that the absorption spectrum of said coupled electrochromic compound at the same relative electron density change as the monomeric compounds has at least one absorption band that is absent in the monomeric electrochromic compounds.
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19. A coupled electrochromic compound comprising a first anodic monomeric electrochromic compound coupled by a bridge comprising a covalent bond or an intervening hydrocarbon structure optionally containing one or more heteroatoms to a second anodic monomeric electrochromic compound such that the absorption spectrum of said coupled electrochromic compound at the same relative electron density change as the monomeric compounds exhibits electrochromic activity at least one wavelength different from the monomeric compounds.
Specification