Lubricating oil composition

• US 20020019320A1
• Filed: 05/30/2001
• Published: 02/14/2002
• Est. Priority Date: 06/02/2000
• Status: Active Grant

• Current Assignee: Chevron Oronite Japan Limited (Chevron Corp.)
• Original Assignee: Chevron Oronite Japan Limited (Chevron Corp.)
• Inventors: Iwamoto, Shigeru, Hirano, Satoshi, Nakazato, Morikuni
• Granted Patent: US 6,569,818 B2
• Time in Patent Office: Days
• US Class Current: 508/159
• CPC Class Codes: C10M 169/045 the additives being a mixture of compounds of unknown or incompletely defined constitution and non-macromolecular compounds
• CPC Class Codes: C10M 169/048 the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
• CPC Class Codes: C10M 2203/1006 used as base material
• CPC Class Codes: C10M 2205/024 Propene
• CPC Class Codes: C10M 2207/026 with tertiary alkyl groups
• CPC Class Codes: C10M 2207/028 Overbased salts thereof
• CPC Class Codes: C10M 2207/144 containing hydroxy groups
• CPC Class Codes: C10M 2207/146 having carboxyl groups bound to carbon atoms of six-membeered aromatic rings having a hydrocarbon substituent of thirty or more carbon atoms
• CPC Class Codes: C10M 2207/262 derived from hydroxy substituted aromatic acids, e.g. salicylates
• CPC Class Codes: C10M 2207/281 of (cyclo)aliphatic monocarboxylic acids
• CPC Class Codes: C10M 2207/289 containing free hydroxy groups
• CPC Class Codes: C10M 2209/084 Acrylate; Methacrylate
• CPC Class Codes: C10M 2215/064 Di- and triaryl amines
• CPC Class Codes: C10M 2215/28 Amides; Imides
• CPC Class Codes: C10M 2223/045 Metal containing thio derivatives
• CPC Class Codes: C10N 2010/04 Groups 2 or 12
• CPC Class Codes: C10N 2030/04 Detergent property or dispersant property
• CPC Class Codes: C10N 2030/42 Phosphor free or low phosphor content compositions
• CPC Class Codes: C10N 2030/43 Sulfur free or low sulfur content compositions
• CPC Class Codes: C10N 2030/45 Ash-less or low ash content
• CPC Class Codes: C10N 2040/252 : Diesel engines

Abstract

A lubricating oil composition having a low P content of 0.01 to 0.1 wt. %, and a sulfated ash of 0.1 to 1 wt. %, which is composed of a) a major amount of mineral base oil having a low S content of at most 0.1 wt. %; b) an ashless alkenyl or alkyl-succinimide dispersant; c) a metal-containing detergent (non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid and/or non-sulfurized alkali metal or alkaline earth metal salt of an alkylphenol derivative having a Mannich base structure); d) Zn-DTP; e) an oxidation inhibitor (phenol compound and/or amine compound) and wherein the sulfur content is 0.01 to 0.3 wt %. The lubricating oil composition shows good high temperature detergency notwithstanding its low S, P, and sulfated ash content, and is favorably employable in diesel engines using fuel of an extremely low sulfur content.

Claims

1. A lubricating oil composition having a sulfur content of 0.01 to 0.3 wt. % and a phosphorus content of 0.01 to 0.1 wt. %, and giving a sulfated ash in the range of 0.1 to 1 wt. %, which comprises

a) a major amount of a mineral base oil having a sulfur content of at most 0.1 wt. %;

b) an ashless dispersant comprising an alkenyl- or alkyl-succinimide or a derivative thereof in an amount of 0.01 to 0.3 wt. % in terms of a nitrogen atom content;

c) a metal-containing detergent containing an organic acid metal salt which is selected from the group consisting of a non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid having a TBN of 10 to 350 mg·

KOH/g and a non-sulfurized alkali metal or alkaline earth metal salt of an alkylphenol derivative having a Mannich base structure, in an amount of 0.1 to 1 wt. % in terms of a sulfated ash content;

d) a zinc dialkyldithiophosphate in an amount of 0.01 to 0.1 wt. % in terms of a phosphorus content; and

e) an oxidation inhibitor selected from the group consisting of a phenol compound and an amine compound in an amount of 0.01 to 5 wt. %.

2. The lubricating oil composition of claim 1, which has a sulfur content of 0.01 to 0.15 wt. %.

3. The lubricating oil composition of claim 1, which has a phosphorus content of 0.01 to 0.06 wt. %.

4. The lubricating oil composition of claim 1, which has a chlorine content of at most 40 ppm.

5. The lubricating oil composition of claim 4, in which the ashless dispersant has a chlorine content of at most 30 ppm.

6. The lubricating oil composition of claim 5, in which the ashless dispersant is a succinimide or a derivative thereof which is obtained by the reaction of a polybutenylsuccinic anhydride and a polyamine, the polybutenylsuccinic anhydride being produced from polybutene and maleic anhydride by a thermal reaction method using neither chlorine or a chlorine atom-containing compound.

7. The lubricating oil composition of claim 1, in which the organic acid metal salt is contained in the oil composition in an amount of 0.2 to 7 wt. %.

8. The lubricating oil composition of claim 1, in which the metal-containing detergent is a non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid having a TBN of 30 to 300 mg·

KOH/g.

9. The lubricating oil composition of claim 8, in which the metal-containing detergent is a non-sulfurized alkali metal or alkaline earth metal salt of an alkylsalicylic acid having a TBN of 30 to 100 mg·

KOH/g.

10. The lubricating oil composition of claim 1, in which the oxidation inhibitor is a hindered phenol compound or a diarylamine compound.

11. The lubricating oil composition of claim 1, in which the oxidation inhibitor is a combination of a hindered phenol compound or a diarylamine compound.

12. The lubricating oil composition of claim 1, which further contains a molybdenum-containing compound in an amount of 0.01 to 5 wt. %.

13. The lubricating oil composition of claim 1, in which the oxidation inhibitor is a combination of a hindered phenol compound and a diarylamine compound, and which further contains a molybdenum-containing compound in an amount of 0.01 to 5 wt. %.

14. The lubricating oil composition of claim 1, which further contains an alkali metal borate hydrate in an amount of 0.01 to 5 wt. %.

15. The lubricating oil composition of claim 1, which further contains a viscosity index improver.

16. The lubricating oil composition of claim 1, in which the mineral base oil is a hydrocracked mineral oil having a sulfur content of at most 0.03 wt. %.

17. The lubricating oil composition of claim 16, in which the mineral base oil has a sulfur content of at most 0.005 wt. %.

18. The lubricating oil composition of claim 17, in which the mineral base oil has an aromatic component content of at most 5 wt. %, a nitrogen content of at most 50 ppm, a sulfur content of at most of 50 ppm, and a viscosity index in the range of 100 to 150.

19. A method of lubricating a diesel engine with a lubricating oil composition of claim 1.

20. A method of lubricating a diesel engine equipped with an exhaust gas after-treatment system comprising a particulate filter and an oxidizing catalyst or a NO_x reducing catalyst composition, using a lubricating oil composition of claim 1.