Flame-retardant and flame-retarding resin composition

• US 20020040083A1
• Filed: 01/24/2001
• Published: 04/04/2002
• Est. Priority Date: 01/26/2000
• Status: Active Grant

• Current Assignee: Idemitsu Kosan Company Limited
• Original Assignee: Idemitsu Petrochemical Co., Ltd. (Idemitsu Kosan Company Limited)
• Inventors: Nakamura, Yasunobu, Muneuchi, Yasuhiro, Kuwaki, Tetsuo
• Granted Patent: US 6,635,697 B2
• Time in Patent Office: Days
• US Class Current: 524/416
• CPC Class Codes: C08K 2003/323 Ammonium polyphosphate
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: C08K 5/3462 Six-membered rings
• CPC Class Codes: C08K 5/5205 Salts of P-acids with N-bases
• CPC Class Codes: C08K 5/523 with hydroxyaryl compounds

Abstract

The present invention provides a flame-retardant which is not only excellent in flame-retarding property but also devoid of lowering moisture-resisting property specially in the course of molding of a resin so that the flame-retardant has little limitation for the molding method, the molding conditions and the intended use thereof. What is characterized is a flame-retardant comprising (a) an aliphatic amine salt of a phosphoric ester with 2-25 carbon atoms in the ester moiety thereof having a melting point of at least 100° C. but not more than a molding temperature of a thermoplastic resin and (b) a salt of phosphoric and/or polyphosphoric acid, the proportion of the component (a) to the component (b), i.e. (a)/(b) being ½-{fraction (5/1)} by weight ratio. In case a polyolefin resin is incorporated with this flame-retardant, the resultant resin composition achieves such an outstanding merits that the composition is not only excellent in flame-retarding property but also devoid of lowering moisture-resisting property especially in the course of molding of the resin composition so that the composition has little limitation for the molding method, the molding conditions and the intended use thereof.

Claims

1. A flame-retardant which comprises (a) an aliphatic amine salt of a phosphoric ester with 2-25 carbon atoms in the ester moiety thereof having a melting point of at least 100°

C. but not more than a molding temperature of a thermoplastic resin to be used and (b) a salt of phosphoric and/or polyphosphoric acid, the proportion of the component (a) to the component (b), i.e. (a)/(b) being ½

-{fraction (5/1)} by weight ratio.

2. A flame-retardant according to claim 1, wherein 10-100 parts by weight of (c) a nitrogen-containing compound having a triazine skeleton is contained per 100 parts by weight of a total amount of the component (a) and the component (b).

3. A flame-retardant according to claims 1-2, wherein the component ( )b) is ammonium polyphosphate.

4. A flame-retardant according to claim 3, wherein the component (a) is an aliphatic amine salt of an aromatic phosphoric monoester.

5. A flame-retardant according to claim 3, wherein the component (a) is an aliphatic secondary polyamine of an aromatic phosphoric monoester.

6. A flame-retardant according to claim 1, wherein the component (a) is piperazine salt of monophenyl phosphate or piperazine salt of monotolyl phosphate.

7. A flame-retarding resin composition which comprises 100 parts by weight of a thermoplastic resin incorporated with 15-150 parts by weight of the flame-retardant according to claim 1.

8. A flame-retarding resin composition which comprises 100 parts by weight of a thermoplastic resin incorporated with 15-100 parts by weight of the flame-retardant according to claim 2.