Matt PU powder coatings
First Claim
Patent Images
1. A matt polyurethane powder coating material, comprising:
- A) 3 to 25% by weight of a polyurea;
B) 35 to 75% by weight of at least one polyester synthesized from polyols and 15-100 mol. % of succinic acid or its anhydride, having an OH number of 20-250 mg KOH/g;
C) 7 to 25% by weight of at least one curing agent of a blocked polyisocyanate, isocyanurate, uretdione or a combination thereof having a functionality of at least 2; and
D) 1 to 50% by weight of auxiliaries and additives;
wherein from 0.6 to 1.2 NCO groups are available per OH group of the resin.
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Abstract
A matt polyurethane powder coating material comprises:
A) 3 to 25% by weight of a polyurea;
B) 35 to 75% by weight of at least one polyester synthesized from polyols and 15-100 mol. % of succinic acid or its anhydride, having an OH number of 20-250 mg KOH/g;
C) 7 to 25% by weight of at least one curing agent of a blocked polyisocyanate, isocyanurate, uretdione or a combination thereof having a functionality of at least 2; and
D) 1 to 50% by weight of auxiliaries and additives; wherein from 0.6 to 1.2 NCO groups are available per OH group of the resin.
28 Citations
15 Claims
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1. A matt polyurethane powder coating material, comprising:
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A) 3 to 25% by weight of a polyurea;
B) 35 to 75% by weight of at least one polyester synthesized from polyols and 15-100 mol. % of succinic acid or its anhydride, having an OH number of 20-250 mg KOH/g;
C) 7 to 25% by weight of at least one curing agent of a blocked polyisocyanate, isocyanurate, uretdione or a combination thereof having a functionality of at least 2; and
D) 1 to 50% by weight of auxiliaries and additives;
wherein from 0.6 to 1.2 NCO groups are available per OH group of the resin.
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2. The matt polyurethane powder coating material as claimed in claim 1, wherein the polyurea A) comprises
at least one at least difunctional isocyanate and at least one at least difunctional amine, the polyurea having a NCO/NH2 ratio of 0.9-1.1: - 1.
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3. The matt polyurethane powder coating material as claimed in claim 1, wherein the polyurea comprises an isocyanate and/or isocyanurate.
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4. The matt polyurethane powder coating material as claimed in claim 3, wherein the isocyanate or isocyanurate is selected from the group consisting of IPDI, HDI and/or HMDI.
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5. The matt polyurethane powder coating material as claimed in claim 1, wherein the polyurea comprises aliphatic, (cyclo)aliphatic, cycloaliphatic, aromatic diamines and/or polyamines having 5-18 carbon atoms.
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6. The matt polyurethane powder coating material as claimed in claim 5, wherein IPDI is present as an amine.
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7. The matt polyurethane powder coating material as claimed in claim 1, wherein the polyester B) is synthesized from at least one polyol selected from the group consisting of ethylene glycol, 1,4-butanediol, 1,6-hexanediol, cyclohexanediol, neopentyl glycol, 1,4-bis(hydroxymethyl) cyclohexane.
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8. The matt polyurethane powder coating material as claimed in claim 1, wherein the polyester B) is synthesized from one the following acids in addition to succinic acid:
- adipic acid, tetrahydrophthalic acid, isophthalic acid, terephthalic acid, trimellitic acid and pyromellitic acid.
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9. The matt polyurethane powder coating material as claimed in claim 1, wherein the polyester B) has a molecular weight of 3,000 to 8,000.
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10. The matt polyurethane powder coating material as claimed in claim 9, wherein the polyester B) has a molecular weight of 4,000 to 5,000.
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11. The matt polyurethane powder coating material as claimed in claim 1, wherein curing agent C) is a blocked polyisocyanate, a blocked isocyanurate and/or a uretdione of the diisocyanates IPDI, HDI and/or HMDI.
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12. The matt polyurethane powder coating material as claimed in claim 11, wherein the curing agent C) is blocked with a blocking agent selected from the group consisting of caprolactam, triazoles, oximes, and pyrazoles.
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13. The matt polyurethane powder coating material as claimed in claim 1, wherein the ratio of OH group-containing polyester to curing agent is such that from 0.6 to 1.2 NCO groups are available per OH group of the polyester.
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14. The matt polyurethane powder coating material as claimed in claim 13, wherein from 0.8 to 1.0 NCO groups are available per OH group of the polyester.
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15. The matt polyurethane powder coating material as claimed in claim 1, wherein said auxiliaries are leveling agents, pigments, fillers and catalysts.
Specification