Direct methanol fuel cell including integrated flow field and method of fabrication

• US 20020076598A1
• Filed: 12/15/2000
• Published: 06/20/2002
• Est. Priority Date: 12/15/2000
• Status: Active Grant

• Current Assignee: Google Technology Holdings LLC (Alphabet Inc.)
• Original Assignee: Motorola, Inc. (Motorola Solutions, Inc.)
• Inventors: Neutzler, Jay K., Bostaph, Joseph W., Koripella, Chowdary R., Fisher, Allison M.
• Granted Patent: US 6,497,975 B2
• Time in Patent Office: Days
• US Class Current: 429/38
• CPC Class Codes: H01M 2300/0082 Organic polymers
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: H01M 8/04186 of liquid-charged or electrolyte-charged reactants
• CPC Class Codes: H01M 8/1009 with one of the reactants being liquid, solid or liquid-charged H01M8/12 takes precedence
• CPC Class Codes: H01M 8/2404 Processes or apparatus for grouping fuel cells
• CPC Class Codes: H01M 8/2418 Grouping by arranging unit cells in a plane H01M8/2425, H01M8/244 take precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A fuel cell device and method of forming the fuel cell device including a base portion, formed of a singular body, and having a major surface. At least one fuel cell membrane electrode assembly formed on the major surface of the base portion. A fluid supply channel including a mixing chamber is defined in the base portion and communicating with the fuel cell membrane electrode assembly for supplying a fuel-bearing fluid to the membrane electrode assembly. An exhaust channel is defined in the base portion and communicating with the membrane electrode. A multi-dimensional fuel flow field is defined in the multi-layer base portion and in communication with the fluid supply channel, the membrane electrode assembly and the exhaust channel. The membrane electrode assembly and the cooperating fluid supply channel, multi-dimensional fuel flow field, and cooperating exhaust channel forming a single fuel cell assembly.

Claims

1. A fuel cell device comprising:

a base portion, formed of a singular body, and having a major surface;

at least one fuel cell membrane electrode assembly formed on the major surface of the base portion;

a fluid supply channel defined in the base portion and communicating with the at least one fuel cell membrane electrode assembly, the fluid supply channel including a mixing chamber and at least one fuel-bearing fluid inlet;

an exhaust channel defined in the base portion and communicating with the at least one fuel cell membrane electrode assembly, the exhaust channel including a water recovery and recirculation channel in communication with the plurality of hydrophilic threads, the exhaust channel spaced apart from the fluid supply channel for exhausting fluid from the at least one fuel cell membrane electrode assembly, the at least one fuel cell membrane electrode assembly and the cooperating fluid supply channel and cooperating exhaust channel forming a single fuel cell assembly;

a multi-dimensional fuel flow field defined in the base portion and communicating with the fluid supply channel, the at least one fuel cell membrane electrode assembly, and the exhaust channel; and

a plurality of electrical components formed in the base portion for electrical integration of the fuel cell assembly.

2. A fuel cell device as claimed in claim 1 wherein the base portion comprises a material selected from the group consisting of ceramic, plastic, glass, graphite, and silicon.

3. A fuel cell device as claimed in claim 2 wherein the at least one fuel cell membrane electrode assembly formed on the major surface of the base portion includes a plurality of fuel cell membrane electrode assemblies formed on the major surface of the base portion.

4. A fuel cell device as claimed in claim 1 wherein the fuel cell membrane electrode assembly further includes a carbon cloth backing positioned on the first electrode on a side opposite the adjacent film, and a carbon cloth backing positioned on the second electrode on a side opposite the adjacent film.

5. A fuel cell device as claimed in claim 1 wherein the multi-dimensional fuel flow field includes a plurality of fuel delivery channels in communication with a plurality of fuel flow returns, thereby providing for the three-dimensional flow of fuel to the membrane electrode assembly.

6. A fuel cell device as claimed in claim 5 wherein the plurality of fuel delivery channels are formed having a separation of less than 1000 mils between adjoining fuel delivery channels.

7. A fuel cell device as claimed in claim 1 wherein the multi-dimensional fuel flow field includes a fuel inlet in fluidic communication with the fluid supply channel and a fuel outlet in fluidic communication with the exhaust channel.

8. A fuel cell device comprising:

a base portion, formed of a singular body, and having a major surface, the base portion formed of a material selected from the group consisting of ceramic, plastic, glass, and silicon;

at least one fuel cell membrane electrode assembly formed on the major surface of the base portion, the at least one fuel cell membrane electrode assembly including a first electrode, a film formed of a protonically conductive electrolyte, and a second electrode;

a fluid supply channel defined in the base portion and communicating with the at least one fuel cell membrane electrode assembly for supplying a fuel-bearing fluid to the at least one fuel cell membrane electrode assembly, the fluid supply channel further including a first fuel-bearing fluid inlet, and a second fuel-bearing fluid inlet, and a mixing chamber;

an exhaust channel defined in the base portion and communicating with the at least one fuel cell membrane electrode assembly, the exhaust channel spaced apart from the fluid supply channel for exhausting fluid from the at least one spaced apart fuel cell membrane electrode assembly, the exhaust channel further including a water recovery and recirculation channel in fluidic communication with the at least one fuel cell membrane electrode assembly;

a multi-dimensional fuel flow field defined in the base portion and communicating with the fluid supply channel, the at least one fuel cell membrane electrode assembly, the exhaust channel, the multi-dimensional fuel flow field, the cooperating fluid supply channel, and the cooperating exhaust channel in combination forming a single fuel cell assembly; and

a top portion including a plurality of electrical components for electrical integration of the plurality of formed fuel cell assemblies.

9. A fuel cell device as claimed in claim 8 further including a plurality of spaced apart fuel cell membrane electrode assemblies formed on the major surface of the base portion, thereby forming a plurality of fuel cell assemblies.

10. A fuel cell device as claimed in claim 9 wherein the plurality of fuel cell membrane electrode assemblies are electrically connected in one of a series electrical interface or a parallel electrical interface.

11. A fuel cell device as claimed in claim 10 wherein the fluid supply channel defined in the base portion and the exhaust channel defined in the base portion are formed to equally and simultaneously communicate with each of the plurality of spaced apart fuel cell membrane electrode assemblies.

12. A fuel cell device as claimed in claim 8 wherein the multi-dimensional fuel flow field includes a plurality of fuel delivery channels in communication with a plurality of fuel flow returns, thereby providing for the three-dimensional flow of fuel to the membrane electrode assembly.

13. A fuel cell device as claimed in claim 12 wherein the plurality of fuel delivery channels are formed having a separation of less than 1000 mils between adjoining fuel delivery channels.

14. A fuel cell device as claimed in claim 8 wherein the multi-dimensional fuel flow field includes a plurality of fuel returns, thereby providing for the three-dimensional flow of fuel within the base portion to the membrane electrode assembly.

15. A fuel cell device as claimed in claim 13 wherein the first and second electrodes comprise a material selected from the group consisting of platinum, palladium, gold, nickel, tungsten, molybdenum, ruthenium, osmium, iridium, copper, cobalt, iron, and alloys of platinum, palladium, gold, nickel, tungsten carbide, molybdenum, osmium, iridium, copper, cobalt, iron, and ruthenium.

17. A method of fabricating a fuel cell device as claimed in claim 16 wherein the step of forming the at least one fuel cell membrane electrode assembly on the major surface of the base portion includes the step of forming a plurality of fuel cell membrane electrode assemblies.

18. A method of fabricating a fuel cell device as claimed in claim 16 wherein the step of electrically interfacing the plurality of fuel cell assemblies includes one of the steps of electrically connecting each of the second electrodes to an adjacent first electrode, thus connecting the plurality of fuel cells in series electrically to increase the output voltage of the structure or electrically connecting each of the first electrodes to an adjacent first electrode and connecting each of the second electrodes to an adjacent second electrode, thus connected in parallel electrically to increase the output current.

19. A method of fabricating a fuel cell device as claimed in claim 16 wherein the step of forming a multi-dimensional fuel flow field includes forming a plurality of fuel delivery channels in communication with a plurality of fuel flow returns in multiple layers of the multi-layer base portion, thereby defining a three-dimensional fuel flow field.

20. A method of fabricating a fuel cell device as claimed in claim 19 wherein the step of forming a plurality of fuel delivery channels includes forming the plurality of fuel delivery channels in the multi-layer base portion having a separation of less than 1000 mils between adjoining fuel delivery channels.

16. A method of fabricating a fuel cell device comprising the steps of:

providing a multi-layer base portion formed of a material selected from the group consisting of ceramic, plastic, glass, graphite, and silicon;

forming a fluid supply channel in the base portion for supplying a fuel-bearing fluid to at least one fuel cell membrane electrode assembly, the fluid supply channel further including a mixing chamber and a methanol concentration sensor;

forming an exhaust channel in the base portion, the exhaust channel spaced apart from the fluid supply channel for exhausting fluid from the at least one spaced apart fuel cell membrane electrode assembly, the exhaust channel further including a water recovery and recirculation channel for the recover and recirculation of a spent fuel-bearing fluid and a reaction water;

forming the at least one fuel cell membrane electrode assembly on the major surface of the base portion, the step of forming the at least one spaced apart fuel cell membrane electrode assembly including the steps of providing for a first electrode on a major surface of the base portion, and providing for a film formed of a protonically conductive electrolyte in contact with the first electrode, providing for a second electrode in contact with the film, the at least one spaced apart fuel cell membrane electrode assembly and the cooperating fluid supply channel and cooperating exhaust channel forming a single fuel cell assembly;

forming a multi-dimensional integrated fuel flow field in communication with the fluid supply channel, the exhaust channel and the at least one fuel cell membrane electrode assembly; and

forming a top portion including a plurality of electrical components for electrical integration of the formed fuel cell assembly.