Method for rendering surface layer of limited play disk lightfast

• US 20020102499A1
• Filed: 12/10/2001
• Published: 08/01/2002
• Est. Priority Date: 12/11/2000
• Status: Active Grant

• Current Assignee: SpectraDisc Corporation (Flexplay Technologies)
• Original Assignee: SpectraDisc Corporation (Flexplay Technologies)
• Inventors: Krieg-Kowald, Marianne
• Granted Patent: US 6,982,109 B2
• Time in Patent Office: Days
• US Class Current: 430/321
• CPC Class Codes: G11B 23/281 by changing the physical properties of the record carrier
• CPC Class Codes: G11B 7/005 Reproducing G11B7/0065 takes precedence
• CPC Class Codes: G11B 7/244 comprising organic materials only
• CPC Class Codes: G11B 7/252 of layers other than recording layers
• CPC Class Codes: G11B 7/2542 consisting essentially of organic resins
• CPC Class Codes: Y10T 428/21 Circular sheet or circular blank

Abstract

An optically readable media (10) has an information-encoding layer (16) and at least one color-forming layer (12) that embodies an optical readout-limiting mechanism. In a first embodiment the at least one color-forming layer contains an additive that does not interfere with the optical readability of the media for a duration of a readout period. The additive, upon exposure to a source of optical radiation that is suitable for reversing the color-forming layer from an optical readout inhibiting state to an optical readout enabling state, undergoes a transformation that maintains the color-forming layer in the optical readout inhibiting state. More specifically, exposure to the source causes the color-forming layer to photobleach and the additive to oxidize, where the oxidation of the additive permanently inhibits the optical readability of the media. The additive may be a leuco dye. In one embodiment the color-forming layer is comprised of 3-[2,2-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and the additive is comprised of benzoyl leucomethylene blue. In a further embodiment the additive is placed into a protective layer (18) that overlies the color-forming layer.

Claims

1. A method for using a readout-limited optical media comprising:

(a) providing the media with at least one layer that embodies a readout-limiting mechanism, said at least one layer comprising an additive that does not interfere with readability of said media for a duration of a readout period; and

(b) activating said additive upon exposure to a source of optical radiation that is suitable for reversing said layer from an optical readout inhibiting state to an optical readout enabling state such that, when activated, said additive undergoes a transformation that maintains the layer in the optical readout inhibiting state.

2. The method of claim 1, where said additive is comprised of a leuco dye.

3. The method of claim 1, where said layer is comprised of a color former 3-[2,2-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and where said additive is comprised of benzoyl leucomethylene blue.

4. The method of claim 1, wherein when in said readout inhibiting state said layer exhibits an optical wavelength absorption range that includes an optical readout wavelength of said media, thereby inhibiting optical readout of said media.

5. The method of claim 4, where exposure to said source of optical radiation causes said additive to oxidize and to exhibit an optical wavelength absorption range that overlaps with said optical wavelength absorption range of said layer, thereby permanently inhibiting the readability of said media.

6. The method of claim 1, where exposure to said source causes said color-forming layer to photobleach and said additive to oxidize, where the oxidation of said additive permanently inhibits the optical readability of said media.

7. A method for using a readout-limited optical media comprising:

(a) providing the media with at least one color-forming layer that embodies a readout-limiting mechanism;

(b) providing a protective layer that overlies said at least one color-forming layer, said protective layer comprising an additive that does not interfere with readability of said media for a duration of a readout period; and

(c) activating said additive upon exposure to a source of optical radiation that is suitable for reversing said color-forming layer from an optical readout inhibiting state to an optical readout-enabling state such that, when activated, said additive undergoes a transformation from an optical readout enabling state to an optical readout inhibiting state.

8. The method of claim 7, where said additive is comprised of a leuco dye.

9. The method of claim 7, where said color-forming layer is comprised of 3-[2,2-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and where said additive is comprised of benzoyl leucomethylene blue.

10. The method of claim 7, wherein when in said optical readout inhibiting state said color-forming layer exhibits an optical wavelength absorption range that includes an optical readout wavelength of said media, thereby inhibiting optical readout of said media.

11. The method of claim 10, where exposure to said source of optical radiation causes said additive to oxidize and to exhibit an optical wavelength absorption range that overlaps with said optical wavelength absorption range of said color-forming layer, thereby permanently inhibiting the readability of said media.

12. The method of claim 7, where exposure to said source causes said color-forming layer to photobleach and said additive to oxidize, where the oxidation of said additive permanently inhibits the optical readability of said media.

14. The media of claim 13, where said additive is comprised of a leuco dye.

15. The media of claim 13, where said color-forming layer is comprised of 3-[2,2-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and where said additive is comprised of benzoyl leucomethylene blue.

16. The media of claim 13, wherein when in said readout inhibiting state said color-forming layer exhibits an optical wavelength absorption range that includes an optical readout wavelength of said media, thereby inhibiting optical readout of said media.

17. The media of claim 16, where exposure to said source of optical radiation causes said additive to oxidize and to exhibit an optical wavelength absorption range that overlaps with said optical wavelength absorption range of said color-forming layer, thereby permanently inhibiting the readability of said media.

18. The media of claim 16, where exposure to said source causes said color-forming layer to photobleach and said additive to oxidize, where the oxidation of said additive permanently inhibits the optical readability of said media.

20. The media of claim 19, where said additive is comprised of a leuco dye.

21. The media of claim 19, where said color-forming layer is comprised of 3-[2,2-bis(4-diethylaminophenyl)vinyl]-6-dimethylaminophthalide and where said additive is comprised of benzoyl leucomethylene blue.

22. The media of claim 19, wherein when in said optical readout inhibiting state said color-forming layer exhibits an optical wavelength absorption range that includes an optical readout wavelength of said media, thereby inhibiting optical readout of said media.

23. The media of claim 22, where exposure to said source of optical radiation causes said additive to oxidize and to exhibit an optical wavelength absorption range that overlaps with said optical wavelength absorption range of said color-forming layer, thereby permanently inhibiting the readability of said media.

24. The media of claim 19, where exposure to said source causes said color-forming layer to photobleach and said additive to oxidize, where the oxidation of said additive permanently inhibits the optical readability of said media.

13. An optically readable media comprising an information-encoding layer and at least one color-forming layer that embodies an optical readout-limiting mechanism, said at least one color-forming layer comprising an additive that does not interfere with the optical readability of said media for a duration of a readout period, said additive, upon exposure to a source of optical radiation that is suitable for reversing said color-forming layer from an optical readout inhibiting state to an optical readout enabling state, undergoes a transformation that maintains the color-forming layer in the optical readout inhibiting state.

19. An optically readable media comprising an information-encoding layer and at least one color-forming layer that embodies an optical readout-limiting mechanism;

a protective layer that overlies said at least one color-forming layer, said protective layer comprising an additive that does not interfere with readability of said media for a duration of a readout period;

said additive, upon exposure to a source of optical radiation that is suitable for reversing said color-forming layer from an optical readout inhibiting state to an optical readout enabling state, undergoes a transformation from an optical readout enabling state to an optical readout inhibiting state.